Benzhydryl compounds as herbicide antidotes

ABSTRACT

Acids, esters, amides and salts of benzhydryl compounds are antidotes for thiocarbamate and acetamide herbicides. These antidote compounds are especially effective to safen acetamide herbicides used to control grassy weeds and broadleaf weeds in rice, sorghum, corn and wheat.

RELATED APPLICATION

This application is a division of U.S. Ser. No. 06/853,301 filed Apr.17, 1986, U.S. Pat. No. 4,964,893.

FIELD OF THE INVENTION

Herbicide antidotes are well-known crop protection chemicals. Ofparticular interest herein is a class of acids, esters, amides and saltsof benzhydryl compounds found effective as antidotes for protecting cropplants from herbicide injury.

BACKGROUND OF THE INVENTION

Herbicides may injure crop plants at herbicide application ratesnecessary to control weed growth. Accordingly, many herbicides cannot beused for controlling weeds in the presence of certain crops.Uncontrolled weed growth, however, results in lower crop yield andreduced crop quality inasmuch as weeds compete with crops for light,water and soil nutrients. Reduction of herbicidal injury to cropswithout an unacceptable corresponding reduction of herbicidal action onthe weeds can be accomplished by use of crop protectants known asherbicide "antidotes" or "safeners".

Many benzhydryl compounds and derivatives are known for treatment ofhuman central nervous system diseases. For example, U.S. Pat. No.3,544,557 to Nauta describes tenzhydryl ether, acid-addition andquaternary ammonium salt compounds useful as anti-Parkinson diseaseagents. In particular, alkyl benzhydrylacetate compounds are shown asintermediates to obtain the Nauta '557 compounds. U.S. Pat. No.4,003,932 to Gootjes describes diphenylmethoxyethylamine compounds ashaving dopaminergic properties for use in Parkinson-syndrome treatment.The Gootjes '932 compounds are mentioned as prepared from startingmaterials and intermediates selected from unsubstitutedhalo/lower-alkyl-substituted diphenylmethoxyacetamides and lower alkylesters. In particular, the amide starting material is shown as preparedfrom 2-[bis-(p-fluorophenyl)methoxy]acetic acid. U.S. Pat. No. 4,066,686to Lafon describes benzhydrylsulphinyl derivatives useful for treatingcentral nervous systems disturbances. In particular, Lafon '686 showsthe following as intermediate or product compounds: benzhydrylthioaceticacid, ethyl benzhydrylthioacetate, benzhydrylsulphinylacetic acid,methyl benzhydrylsulphinylacetate, andN-[2-(benzhydrylsulphinyl)ethyl]-piperidine hydrochloride. U.S. Pat. No.4,202,896 to Gootjes describesN-benzhydryloxyethyl-N-phenylpropylpiperazine compounds for use inParkinson-syndrome treatment. These compounds are prepared from startingmaterials selected from unsubstituted orhalo/lower-alkyl/lower-alkoxy-substituteddiphenylmethoxyacetic/propanoic acid compounds. In particular, there ismentioned as a starting material the compound methyldiphenylmethoxyacetate.

Benzhydryl compounds and derivatives are known also for otherhuman-related pharmaceutical purposes. For example, U.S. Pat. No.4,205,087 to Waring describes benzhydrylacetic acid derivatives for usein anti-arthritic treatment. In particular, the compound methylbis(4-chlorophenyl)methoxyacetate is shown. U.S. Pat. No. 4,427,590 toAllgeier et al describes triazolobenzodiazepine derivatives and oxidesuseful as tranquilizers and as anticonvulsant agents. An intermediatecompound specifically shown is diphenylmethoxyacetic acid hydrazide.Japanese Kokai No. 74/81,379 of Kono et al showsbenzhydryloxyalkylpenicillin compounds for pharmaceutical uses which areprepared from diphenylmethoxyacetic acid. A monograph by C. Van derStelt et al [Arzneim.-Forsch., 17(11), pp. 1446-1449 (1967)], relatingto guanidine and amidoxime derivatives of diphenylmethyl and tricyclicethers, mentions the compound 2-(diphenylmethoxy)acetamide.

None of the aforementioned publications describes benzhydryl compoundsfor agricultural-related uses, much less for use as herbicide antidotes.

For a herbicide product to be accepted commercially, the herbicideproduct must provide a relatively high level of control of weeds incrops, such as rice, wheat, corn or sorghum, in addition to meetingseveral other criteria. For example, the herbicide must possessrelatively high unit activity so that lower rates of herbicideapplication are feasible. Lower application rates are desirable in orderto minimize exposure of the environment to the herbicide. At the sametime, such herbicide must be selective in herbicidal effect so as not toinjure the crops. Herbicidal selectivity can be enhanced by use of anappropriate antidote in combination with the herbicide. Butidentification of an antidote having high safening activity suitable fora commercially-effective herbicide is a highly complicated task. Whethera compound or class of compounds provides efficacious antidotal orsafening activity is not a theoretical determination but must be doneempirically. Safening activity is determined empirically by observingthe complex interaction of several biological and chemical factors,namely: the type of herbicide compound; the type of weed to becontrolled; the type of crop to be protected from weed competition andherbicidal injury; and the antidote compound itself. Moreover, theherbicide and antidote must each possess chemical and physicalproperties enabling preparation of an efficacious, stable formulationwhich is environmentally safe and easy to apply to the field.

DESCRIPTION OF THE INVENTION

A family of compounds useful as antidotes against herbicide injury tocrop plants is provided by acids, esters, amides and salts ofbenzhydryl-type ether compounds having the general structural formula##STR1## wherein each of X₁, X₂ and X₃ is independently selected fromhydrido, alkyl, cycloalkyl, haloalkyl, phenyl, furanyl, thienyl,thiazolyl, pyridinyl, N-oxidepyridinyl, and phenyl substituted by one ormore radicals, R₄ and R₉ selected from alkyl, alkoxy, halo, haloalkoxy,nitro, haloalkyl and alkyolamino; wherein Z is selected from oxygenatom, sulfur atom, ##STR2## wherein each of R₁ and R₂ is independentlyselected from hydrido and alkyl; wherein A is selected from cyano,oxazolinyl, alkyloxazolinyl, oximinoalkyl, and radicals represented by##STR3## with Y selected from oxygen atom and sulfur atom; wherein eachof R₃, R₄ and R₅ is a substituent independently selected from hydrido,alkyl, alkenyl, alkynyl, haloalkyl, cycloalkyl, oxiranyl, alkoxyalkyl,alkoxycarbonylalkyl, alkylthioalkyl, hydroxyalkyl, phenyl, benzyl,benzodioxolyl, benzodioxolylalkyl, thienyl, thienylalkyl, furanyl,furanylalkyl, hydroxyalkylfuranylalkyl, pyridinyl, pyridinylalkyl,dioxolanyl, alkyldioxolanyl, alkyldioxolanylalkyl, and hydrated andnon-hydrated agriculturally-acceptable alkali metal cations includingsodium and potassium cations, alkaline earth cations including calciumand magnesium cations, onium cations including ammonium, morpholiniumand piperazinium cations and ammonium or morpholinium or piperaziniumcations substituted with one or more groups selected from alkyl,cycloalkyl, hydroxyalkyl, phenylalkyl, diphenylalkyl, triphenylalkyl,aminoalkyl, cyanoalkyl, alkoxyalkyl and hydroxyalkoxyalkyl; wherein anyone of said R₃, R₄ and R₅ substituents having a substitutable positionmay be substituted with one or more radicals selected from alkyl,cycloalkyl, alkoxy, halo, haloalkyl, phenyl, halophenyl, alkoxyphenyl,cyano and nitro; wherein each of R₆ and R₇ is a substituentindependently selected from hydrido, alkyl, alkenyl, amino, hydroxyl,haloalkyl, hydroxyalkyl, alkoxyl and phenyl; wherein R₆ and R₇ may betaken together to form piperazinyl; wherein any of said R₆ and R₇substituents alone, or taken together, and having a substitutableposition, may be substituted with one or more radicals selected fromalkyl, halo, haloalkyl, phenyl, halophenyl, phenylalkoxyalkylcarbonyl,diphenylalkoxyalkylcarbonyl and alkoxyphosphorylalkylisocyano.

Preferred compounds within the class defined by formula I are compoundswherein each of X₁ and X₂ is independently selected from phenyl andphenyl substituted by one or more groups selected from alkyl, alkoxy,halo, nitro, haloalkyl and alkylamino; wherein X₃ is hydrido; wherein Zis oxygen atom; wherein each of R₁ and R₂ is hydrido; wherein A isselected from ##STR4## wherein Y is oxygen atom; wherein each of R₄ andR₅ is independently selected from hydrido, alkyl, alkoxyalkyl,cycloalkoxyalkyl, alkoxycarbonylalkyl, alkylthioalkyl, alkenyl, alkynyl,haloalkyl, phenyl, benzyl, benzodioxolyl, benzodioxolylalkyl, thienyl,thienylalkyl, furanyl, furanylalkyl, hydroxyalkylfuranylalkyl,pyridinyl, pyridinylalkyl, dioxolanyl, alkyldioxolanyl,alkyldioxolanylalkyl, and agriculturally-acceptable cations selectedfrom sodium, ammonium and ammonium substituted with one or more alkylgroups; and wherein any one of said R₄ and R₅ substituents having asubstitutable position may be substituted with one or more radicalsselected from alkyl, cyano, cycloalkyl, haloalkyl, halo, alkoxy, phenyl,halophenyl and haloalkyl.

Particularly preferred compounds within formula I comprise a class ofcompounds of formula II ##STR5## wherein each of R₈ and R₉ independentlyrepresents one or more substituents selected from alkyl, alkoxy,alkylamino, halo, haloalkyl and nitro; wherein A is selected from##STR6## wherein each of R₄ and R₅ is independently selected fromhydrido, alkyl, haloalkyl, cyanoalkyl, alkenyl, alkynyl, phenyl,nitrophenyl, benzyl, halobenzyl, pyridinylalkyl and alkylammonium.

More particularly preferred compounds within formula II are thosewherein each of R₄ and R₅ is independently selected from hydrido,methyl, ethyl, 1-methylethyl, 1,1-dimethylethyl, n-propyl, 2-propenyl,1™methyl-2-propynyl, 1-ethyl-2-propynyl, 2,2,2-trifluoroethyl,1-methyl-2,2,2-trifluoroethyl, 2,2,3,3-tetrafluoropropyl, 2-cyanoethyl,1-cyano-1-methylethyl, phenyl, 3-nitrophenyl, benzyl, 4-chlorobenzyl,3-pyridinylmethyl, and 1,1™dimethylethylammonium, and wherein each of R₈and R₉ represents substituents independently selected from 2-methyl,2,6-dimethyl, 4-chloro, 2-trifluoromethyl, 3-trifluoromethyl and5-trifluoromethyl.

The compounds of the foregoing classes are believed to be novel with theexclusion of certain acids, esters, amides and other groups ofbenzhydryl compounds defined as follows:

when each of X₁ and X₂ is phenyl, X₃ is hydrido, Z is oxygen atom, R₁ ishydrido, R₂ is hydrido, methyl, or ethyl, and R₄ is hydrido, then eachof R₈ and R₉ cannot be hydrido, methyl, fluoro, chloro or bromo;

when each of X₁ and X₂ is phenyl, Z is oxygen atom, each of X₃ and R₁ ishydrido, R₂ is hydrido, methyl or 2-propyl, and R₄ is methyl, ethyl,2-dimethylaminoethyl, 2-ethoxyethyl or diphenylmethyl, then each of R₈and R₉ cannot be hydrido, chloro, fluoro, bromo or trifluoromethyl;

when each of R₆ and R₇ is hydrido, methyl or ethyl, Z is oxygen atom,each of X₁ and X₂ is phenyl, X₃ is hydrido, and each of R₁ and R₂ ishydrido, then each of R₈ and R₉ cannot be hydrido, fluoro, chloro,methyl, tert-butyl, methoxy or amino;

when each of R₈ and R₉ is dimethylamino or diethylamino, Z is oxygenatom, each of X₁ and X₂ is phenyl, and each of X₃, R₁, R₂ and R₆ ishydrido, then R₄ cannot be ethyl, 2-ethoxyethyl or benzyl, and R₇ cannotbe hydrido, methyl, phenyl or chlorophenyl;

when each of X₁ and X₂ is phenyl, each of X₃, R₁ and R₂ is hydrido, andeach of R₈ and R₉ is hydrido or methyl, then A cannot be ##STR7## when Zis either sulfur atom or sulfinyl, each of X₁ and X₂ is phenyl, each ofX₃, R₁, R₂ and R₆ is hydrido, then R₄ cannot be hydrido, methyl orethyl, R₇ cannot be hydroxyl, and A cannot be cyano; and

when Z is oxygen atom, each of X₁ and X₂ is phenyl, each of X₃, R₁ andR₂ is hydrido, and each of R₈ and R₉ is fluoro, then A cannot be cyano.

Where the term "alkyl" is used, either alone or within another term suchas "haloalkyl", the term "alkyl" embraces linear or branched radicalshaving one to ten carbon atoms. The term "cycloalkyl", embraces radicalshaving three to ten carbon atoms, such as cyclopropyl and cyclobutyl.The term "haloalkyl" embraces radicals wherein any one or more of thecarbon atoms is substituted with one or more halo groups, preferablyselected from bromo, chloro and fluoro. Specifically embraced by theterm "haloalkyl" are monohaloalkyl, dihaloalkyl and polyhaloalkylgroups. A monohaloalkyl group, for example, may have either a bromo, achloro, or a fluoro atom within the group. Dihaloalkyl and polyhaloalkylgroups may be substituted with two or more of the same halo groups, ormay have a combination of different halo groups. A dihaloalkyl group,for example, may have two bromo atoms, such as a dibromomethyl group, ortwo chloro atoms, such as a dichloromethyl group, or one bromo atom andone chloro atom, such as a bromochloromethyl group. Examples of apolyhaloalkyl are trifluoromethyl, 2,2,2-trifluoroethyl, perfluoroethyland 2,2,3,3-tetrafluoropropyl groups. The terms "alkylol" and"hydroxyalkyl" embrace linear or branched alkyl groups having one to tencarbon atoms any one of which may be substituted with one or morehydroxyl groups. The term "alkenyl" embraces linear or branched radicalshaving two to ten carbon atoms and containing at least one carbon-carbondouble bond. The term "alkynyl" embraces linear or branched radicalshaving two to ten carbon atoms and containing at least one carbon-carbontriple bond. The term "alkylthioalkyl" embraces radicals containing twolinear or branched alkyl groups, each of one to ten carbon atoms, whichalkyl groups are connected to a divalent sulfur atom. The terms "alkoxy"and "alkoxyalkyl" embrace linear or branched oxy-containing radicalshaving alkyl portions of one to ten carbon atoms, such as a methoxygroup. The "alkoxy" or "alkoxyalkyl" radicals may be further substitutedwith one or more halo atoms, such as fluoro, chloro or bromo, to providehaloalkoxy or haloalkoxyalkyl groups. The term "oxiranyl" embraces athree-membered ring containing an oxygen atom and two carbon atoms. Theterm "alkoxycarbonylalkyl" embraces linear or branched radicalscontaining at least one oxy group and at least one carbonyl moietyseparated by alkyl groups of one to ten carbon atoms. The terms "benzyl"and "phenylmethyl" are interchangeable. The terms"halophenyl","alkylphenyl","alkoxyphenyl" and "nitrophenyl" embracesubstituted phenyl radicals having one or more of the respectivesubstituents, e.g., "halophenyl" embraces monohalo-, dihalo-, trihalo-,tetrahalo- and pentahalo-phenyl. The term "agriculturally-acceptablecations" embraces cations commonly used to form addition salts of thefree acids, examples of such cations being alkali metal cations such assodium and potassium, alkaline earth cations such as magnesium andcalcium, onium cations such as ammonium, substituted ammonium,morpholinium and piperazinium cations and their substituted derivatives.The term "addition salts" includes the salts of acids andquaternary-type salts.

Each of the following radicals is described by a general word term, andthen exemplified by a specific name and structure. It is intended thatsuch specific name and structure are for purposes of exemplification,only, and that many other radicals may be embraced by the general term:

    __________________________________________________________________________    General Term Specific Name Specific Structural                                for Radical  Exemplification                                                                             Exemplification                                    __________________________________________________________________________    dioxolanyl   1,3-dioxolan-4-yl                                                                            ##STR8##                                          alkyldioxolanyl                                                                            2,2-dimethyl-1,3- dixolan-4-yl                                                               ##STR9##                                          alkyldioxolanylalkyl                                                                       (2,2-dimethyl-1,3- dioxolan-4-yl)methyl                                                      ##STR10##                                         benzodioxolyl                                                                              1,3-benzodioxol-5-yl                                                                         ##STR11##                                         benzodioxolylalkyl                                                                         1,3-benzodioxol-5-yl-methyl                                                                  ##STR12##                                         thienyl      2-thienyl                                                                                    ##STR13##                                         thienylalkyl 2-thienylmethyl                                                                              ##STR14##                                         furanyl      3-furanyl                                                                                    ##STR15##                                         furanylalkyl 3-furanylmethyl                                                                              ##STR16##                                         hydroxyalkylfuranylalkyl                                                                   5-(hydroxymethyl)-2- furanylmethyl                                                           ##STR17##                                         thiazolyl    2-thiazolyl                                                                                  ##STR18##                                         oxazolinyl   2-oxazolin-2-yl                                                                              ##STR19##                                         alkyloxazolinyl                                                                            4,4-dimethyl- 2-oxazolin-2-yl                                                                ##STR20##                                         pyridinyl    2-pyridinyl                                                                                  ##STR21##                                         pyridinylalkyl                                                                             3-pyridinylmethyl                                                                            ##STR22##                                         N-oxidepyridinyl                                                                           4-pyridinyl-N-oxide                                                                          ##STR23##                                         oximinoalkyl oximinomethyl CHNOH                                              alkoxyphosphoryl- alkylisocyano                                                            methoxyphosphoryl- ethylisocyano                                                             ##STR24##                                         __________________________________________________________________________

Also included in this invention are the stereo and optical isomers ofcompounds within the class defined by formula I.

The terms "antidote", "safening agent", "safener", "antagonistic agent","interferant", "crop protectant" and "crop protective", are often-usedterms denoting a compound capable of reducing the phytotoxicity of aherbicide to a crop plant or crop seed. The terms "crop protectant" and"crop protective" are sometimes used to denote a herbicide-antidotecombination which provides protection from competitive weed growth byreducing herbicidal injury to a valuable crop plant while at the sametime controlling or suppressing weed growth occurring in the presence ofthe crop plant. An "antidotally-effective amount" of an antidote is thatamount which protects crop plants by interfering with the herbicidalaction of a herbicide on the crop plants, but without interfering withthe herbicidal action on weeds, so as to render the herbicide selectiveto weed plants emerging or growing in the presence of crop plants.

Herbicides which may be used with benefit in combination with anantidote of the described class include a large variety of herbicidessuch as thiocarbamates, triazines, diphenylethers, benzoic acidderivatives, phenylureas, nitroanilines, benzene sulfonamides,sulfonylureas and acetamides. To achieve control of a broad spectrum ofnarrow and broadleaf weeds, it may be desirable to use a combination oftwo or more herbicides along with one or more antidotes. The antidote(s)may act to safen only one of the herbicides of such combination, butsuch combination can be highly useful in providing a trio of advantages,namely, crop safety, herbicide selectivity and broad spectrum weedcontrol. Such combinations can be used to obtain selective weed controlwith low crop injury in several species of monocotyledonous crop plantssuch as corn, grain sorghum (milo), and cereals such as wheat, rice,barley, oats and rye, as well as in several varieties of dicotyledonouscrop plants including oil-seed crops such as soybeans and cotton.

Examples of thiocarbamate herbicides are the following:

cis-/trans-2,3-dichloroallyl-diisopropylthiolcarbamate (common name"diallate");

ethyl dipropylthiocarbamate (common name "EPTC");

2,3,3-trichloroallyl-diisopropylthiolcarbamate (common name"triallate");

S-ethyl diisobutylthiocarbamate (common name "butylate");

S-propyl dipropylthiocarbamate (common name "vernolate");

S-4-chlorobenzyl diethylthiocarbamate (common name "benthiocarb");

S-ethyl hexahydro-1H-azepine-1-carbothioate (common name "molinate");

S-(α,α-dimethylbenzyl)-1-piperazinecarbothioate (common name"dimeperate").

Examples of triazine herbicides are the following:

2-chloro-4,6-bis(ethylamino)-1,3,5-triazine (common name "simazine");

2-chloro-4-ethylamino-6-isopropylamino-sym-triazine (common name"atrazine");

2-chloro-4-(1-cyano)-1-methyl(ethylamino)-6-ethylamino-1,3,5-triazine(common name "cyanazine");

6-chloro-N-(1-methylethyl)-N'-ethyl-N'-(2-methyl-1-propenyl)-1,3,5-triazine

2,4-bis(ethylamino)-6-(methylthio)-sym-triazine (common name"simetryne").

Examples of diphenyl ether herbicides are the following:

2,4-dichlorophenyl-4'-nitrophenyl ether (common name "nitrofen");

2,4,6-trichlorophenyl-4-nitrophenyl ether (common name "CNP");

2-chloro-1-(3'-ethoxy-4'-nitrophenoxy)-4-trifluoromethylbenzene (commonname "oxyfluorfen");

2',4'-dichlorophenyl-3-methoxy-4-nitrophenyl ether (common name"chloromethoxinyl");

methyl 2-[4'-(2",4"-dichlorophenoxy)phenoxy)propionate; methyl5-(2',4'-dichlorophenoxy)-2-nitrobenzoate (common name "bifenox");

N-(2'-methoxyethyl)-2-[5'-(2"-chloro-4"-trifluoromethyl-phenoxy)phenoxy]propionamide;

5-[2-chloro-4-(trifluoromethyl)phenoxy]-N-(methylsulfonyl)-2-nitrobenzamide(common name "fomesafen");

5-(2'-chloro-4'-trifluoromethylphenoxy)-2-nitrobenzoic acid (common name"acifluorfen");

Examples of benzoic acid type herbicides are the following:

3,6-dichloro-o-anisic acid and the sodium or dimethylamine salts thereof(common name "dicamba").

Examples of phenylurea herbicides are the following:

N-(3'-isopropylphenyl)-N',N'-dimethylurea (common name "isoproturon");

1-(3,4-dichlorophenyl)-3,3-dimethylurea (common name "diuron");

N-(3',4'-dimethylbenzyl)-N'-4-tolylurea (common name "dimuron");

N'-(3,4-dichlorophenyl)-N-methoxy-N-methylurea (common name "linuron");

N-(3'-chloro-4'-isopropylphenyl)-N',N'-(3-methylpentamethylen-1,5-yl)urea.

Examples of nitroaniline herbicides are the following:

2,6-dinitro-N,N-dipropyl-4-trifluoromethylaniline (common name"trifluralin");

4-(dipropylamino)-3,5-dinitrobenzenesulfonamide (common name"oryzalin");

N-(1'-ethylpropyl)-2,6-dinitro-3,4-xylidine (common name"pendimethalin").

An example of a benzenesulfonamide herbicide is the following:

2-chloro-N-{[4-methoxy-6-methyl-1,3,5-triazine-2-yl-amino]carbonyl}benzenesulfonamide(common name DPX-4189);

An example of a sulfonylurea herbicide is the following:

methyl2-[{[{[(4,6-dimethoxy-2-pyrimidinyl)amino]-carbonyl}amino]sulfonyl}methyl]benzoate(common name "DPX™5384").

Examples of phenoxyacetic acid type herbicides are the following:

(2,4-dichlorophenoxy)acetic acid (common name "2,4-D");

(4-chloro-2-methylphenoxy)acetic acid (common name "MCPA").

Examples of acetamide herbicides are the following:

2-chloro-N-isopropylacetanilide (common name "propachlor");

2-chloro-N-[2-(1,1-dimethylethyl)-6-methylphenyl]-acetamide;

2-chloro-2'-(1,1-dimethylethyl)-6'-methyl-N-(methoxymethyl)acetanilide;

N-(butoxymethyl)-2-chloro-N-[2-(1,1-dimethylethyl)-6-methylphenyl]acetamide(common name "terbuchlor");

2-chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide (common name"alachlor");

2-chloro-N-(isobutoxymethyl)-2',6'-acetoxylidide;

2-chloro-2',6'-diethyl-N-(butoxymethyl)acetanilide (common name"butachlor");

2-chloro-N-(ethoxymethyl)-6'-ethyl-o-acetotoluidide (common name"acetochlor");

2-chloro-N-(2,6-dimethyl-1-cyclohexen-1-yl)-N-(2-ethoxyethyl)acetamide;

ethyl ester of N-chloroacetyl-N-(2,6-diethylphenyl) glycine (common name"diethatyl ethyl");

2-chloro-N-(2,6-dimethylphenyl)-N-(2-methoxyethyl) acetamide (commonname "dimethachlor");

2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-o-acetotoluidide (commonname "metolachlor");

2-chloro-2',6'-diethyl-N-(2-propoxyethyl)acetanilide (common name"pretilachlor");

2-chloro-2',3'-dimethyl-N-(isopropyl)acetanilide;

2-chloro-2'-methyl-6'-methoxy-N-(propoxymethyl)-acetanilide;

2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl) acetanilide;

2-chloro-2'-methyl-6'-ethoxy-N-(propoxymethyl)-acetanilide;

N-(ethoxymethyl)-N-(2-ethyl-6-methyl-1-cyclohexen-yl)-2-chloroacetamide;

2-chloro-2,6'-dimethyl-N-(1H-pyrazol-1-ylmethyl)-acetanilide (commonname "metazachlor");

2-chloro-N-(2,6-dimethyl-1-cyclohexen-1-yl)-N-(1H-pyrazol-1-ylmethyl)acetamide;

2-chloro-6'-trifluoromethyl-N-(isopropoxymethyl) acetanilide;

2-chloro-2'-methyl-6'-trifluoromethyl-N-(ethoxymethyl) acetanilide;

2-chloro-2'-trifluoromethyl-6-methyl-N-(propoxymethyl)-acetanilide;

2-chloro-2'-methyl-6'-(1-methylethoxy)-N-(ethoxymethyl)acetanilide;

2-chloro-2'-methyl-6'-trifluoromethyl-N-(isopropoxymethyl)acetanilide;

2-chloro-2'-(3-methylbutoxy)-6'-methyl-N-(methyl)-acetanilide;

2-chloro-2'-isobutoxy-6'-methyl-N-(propoxymethyl) acetanilide;

2-chloro-2'-methyl-6'-propoxy-N-(methyl)acetanilide;

2-chloro-2'-butoxy-6'-methyl-N-(methyl)acetanilide;

2-chloro-2'-methyl-6'-propoxy-N-(ethoxymethyl)-acetanilide;

2-chloro-2'-butoxy-6'-ethyl-N-(methyl)acetanilide;

α-chloro-N-(ethoxymethyl)-N-[2-methyl-1-(1-methylethyl)-1-propenyl]acetamide;

2-chloro-2'-methoxy-3',6'-dimethyl-N-[(1-methylethoxy)-methyl]acetanilide;

2-chloro-2'-ethyl-6'-(2-methylpropoxy)-N-(ethoxymethyl)-acetanilide;

2-chloro-2'-methyl-6'-(1-methylbutoxy)-N-(methyl)acetanilide;

2-chloro-2'-ethyl-6'-(1-methylpropyl)-N-(methyl)acetanilide;

2-chloro-2'-(1,3-dimethylbutoxy)-6'-methyl-N-(methyl)acetanilide;

2-chloro-2'-methyl-6'-(1-methylpropyl)-N-(methyl)acetanilide;

2-chloro-2'-ethyl-6'-trifluoromethyl-N-(1-pyrazolyl-1-ylmethyl)acetanilide;

2-chloro-N-[1-(2-chloro-6-fluorophenyl)-2-methyl-1-propen-1-yl]-N-(2-propynyl)acetamide;

2chloro-N-isopropyl-N-(3,5,5-trimethylcyclohexen-1-yl) acetamide (commonname "trimexachlor");

Examples of other miscellaneous herbicides are the following:

2,6-dichlorobenzonitrile (common name "dichlobenil");

3,5-dichloro-4-hydroxybenzonitrile (common name "bromoxynil");

N-(α,α-dimethylbenzyl)-2-bromo-tert-butylamide (common name"bromobutamide");

N-(3,4-dichlorophenyl)propanamide (common name "propanil");

3-[2,4-dichloro-5-(1-methylethoxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2-(3H)-one(common name "oxadiazon");

4-(2,4-dichlorobenzoyl)-1,3-dimethyl-5-pyrazolyl-p-toluenesulfonate(common name "pyrazolate");

2-(2,4-dichloro-3-methylphenoxy)propionamide (common name "MY-15");

4-(2,4-dichloro-3-methylbenzoyl)-1,3-dimethyl-5-methylphenacyloxypyrazole(common name "MY-71");

α-(2-naphthoxy)propionanilide (common name "naproanilide");

1,3-dimethyl-4-(2,4-dichlorobenzoyl)-5-phenacyloxypyrazole (common name"SL-49").

Several of the mentioned herbicides are known in the art. Diallate andtriallate herbicides are described in U.S. Pat. Nos. 3,330,643 and No.3,330,821. Atrazine herbicide is described in U.K. Patent No. 814,947.Alachlor, butachlor and acetochlor herbicides are described in U.S. Pat.Nos. 3,442,945 and No. 3,547,620. Propachlor herbicide is described inU.S. Pat. No. 2,863,752 and Reissue Patent No. 26,961. Metolachlorherbicide is described in U.S. Pat. No. 3,937,730. Pretilachlor isdescribed in U.S. Pat. No. 4,168,965. Metazachlor herbicide is describedin U.S. Pat. No. 4,249,935. Trimexachlor herbicide is described in U.S.Pat. No. 4,319,918.

U.S Pat. No. 4,351,667 describes the herbicidesN-(ethoxymethyl)-N-(2-ethyl-6-methyl-1-cyclohexen-1-yl)-2-chloroacetamideandN-(ethoxymethyl)-N-(2,5-dimethyl-1-cyclopenten-1-yl)-2-chloroacetamide.U.K. Patent No. 2,072,175 describes the herbicide2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl)acetanilide. U.K.Patent No. 2,072,181 describes the herbicide2-chloro-2'-methyl-6'trifluoromethyl-N-(ethoxymethyl)acetanilide.

Combinations may be made of any one or more of the described antidotecompounds with any one or more of the herbicide compounds mentionedherein.

Antidote compounds of the described class are effective to reduceherbicidal injury to grain sorghum (milo), wheat, rice, soybean andcorn, especially where herbicide injury is associated with pre-emergentapplication of the herbicides. Antidote compounds of the invention havebeen found particularly effective to reduce injury to rice caused bybutachlor herbicide. Also, the antidote compounds have been foundparticularly effective to reduce injury to sorghum and wheat caused byalachlor herbicide. Also, the antidote compounds are particularlyeffective to reduce injury to corn caused by the acetamide herbicidesacetochlor and2-chloro-2'-methyl-6'-methoxy-N-(isopropoxymethyl)acetanilide, both ofwhich are highly active acetanilide herbicides.

Antidote compounds of the invention are effective to reduce injury todirect-seeded upland rice, puddle-seeded rice, rice grown in seedbedsfor subsequent transplanting and to transplant rice. Tank-mixcombinations of butachlor and antidote applied preemergent topuddle-seeded rice and seedbeds for transplant rice are particularlyeffective. Antidote compounds of the invention generally do not reducethe performance of the herbicide on weeds.

Antidote Compound Preparation

Table I shows 284 benzhydryl-type antidote compounds by name andstructure which were synthesized. Also indicated are methods ofpreparation and physical-chemical analysis for each antidote compound.The methods of preparation, designated "A" through "DD",are describedbelow in schematic form. Raw materials utilized in the methods wereobtained from commercial sources such as Aldrich Chemical Co.Preparation of non-commercially-available starting materials are shownin methods following Method "DD". Abbreviations of reagents or radicalsspecified in the methods are as follows:

Abbreviation Key

TsOH=toluenesulfonic acid

THF=tetrahydrofuran

DMF=dimethylformamide

Me=methyl

Et=ethyl

OAc=acetate

DCC=dicyclohexylcarbodiimide

DMAP=4-dimethylaminopyridine

MCPBA=m-chloroperbenzoic acid

Bu₄ NBr=tetrabutyl ammonium bromide

n-BuLi=n-butyl lithium

t-BuOK=potassium tert-butoxide

φ=phenyl ##STR25##

The following Examples 1-36 are detailed descriptions of the methods ofpreparation of those antidote compounds which were found in biologicalevaluation to show the most significant safening utility of the 284specific antidote compounds disclosed herein. These detailedpreparations fall within the scope of, and serve to exemplify, the moregenerally described Methods "A" through "DD". These Examples 1-36 arepresented for illustrative purposes only and are not intended as arestriction on the scope of the invention. All parts are by weightunless otherwise indicated. Most of the commercially-available startingmaterials were obtained from Aldrich Chemical Co., Milwaukee, Wis. TableI sets forth analytical data for specific compounds prepared inaccordance with the procedures of Example 1-36.

EXAMPLE 1

A reaction vessel was charged with 200 ml of benzene and 4.5 g (50 mmol)of methyl glycolate. This solution was concentrated under reducedpressure to remove water. Then, 100 ml of dimethylformamide containing10.1 g (50 mmol) of benzhydryl chloride was added to the reaction vesseland the resulting solution was heated to 120° C. After 81/2 hours ofheating at 120° C., 9.0 g (100 mmol) of methyl glycolate was added tothe reaction mixture. After heating the reaction mixture at 120° C. fora total of 16 hours, the reaction appeared complete. The reactionproduct was poured into a vessel containing 200 ml of water and 200 mlof ethyl ether. After separation of the mixture into layers, the ethylether layer was washed with 200 ml of water, then dried with sodiumsulfate and concentrated under reduced pressure. The concentratedmaterial was triturated with cyclohexane, and then distilled (122-124°C.@0.5 mm) to provide 7.9 g of product identified in Table I.

EXAMPLE 2

A reaction vessel was charged with 100 ml of methylene chloride, 9.2 g(50 mmol) of benzhydrol, 9.7 g (50 mmol) of t-butyl bromoacetate, 8 g ofbenzyl triethylammonium chloride and 50 ml of 10% sodium hydroxide. Thisreaction mixture was stirred at room temperature for about 15 hours. Themixture was filtered, then washed successively with 5% hydrochloricacid, 5% sodium bicarbonate and brine. The organic material was driedwith sodium sulfate and then concentrated under reduced pressure. Thesolid residue was recrystallized from ethanol to provide 8.5 g ofproduct identified in Table I.

EXAMPLE 3

A reaction vessel was charged with 300 ml of dimethylformamide, 300 mlof benzene and 191.8 g (1.8 mol) of ethyl glycolate. This mixture wasazeotroped for 4 hours with a Dean-Stark trap to remove water. With thereaction mixture at 130° C., 291.9 g (1.44 mol) chlorodiphenylmethanewas added in one batch. The reaction mixture was heated at 145° C.overnight. Some of the dimethylformamide was removed under reducedpressure and the residue was poured into ice water and then extractedwith methylene chloride. The methylene chloride portion of the mixturewas washed with 700 ml water, dried over sodium sulfate, concentratedunder reduced pressure, and then subjected to Kugelrohr distillation toremove dimethylformamide. About 10 g of the crude product was purifiedby HPLC using 1% ethylacetate-in-toluene eluent to provide productidentified in Table I.

EXAMPLE 4

A dry reaction vessel was charged with 100 ml of tetrahydrofuran and10.3 g (92 mmol) of potassium tert-butoxide. The vessel and contentswere cooled to about 0° C. and then a mixture of 200 ml of drytetrahydrofuran and 22.7 g (90 mmol) of meta-trifluoromethylbenzhydrolwas added dropwise to the vessel contents. The reaction mixture wasstirred for 2 hours without further cooling. Then 14.9 g (7.7 ml) ofmethyl bromoacetate was added dropwise to the reaction mixture and themixture was refluxed for one hour. The mixture was cooled to roomtemperature and then 200 ml of water and 200 ml of methylene chloridewere added. The methylene chloride layer was dried over sodium sulfateand then concentrated under reduced pressure to provide 27.6 g of alight amber oil. This oil was purified by HPLC using a 1% ethylacetate-in-hexane eluent to provide 6.1 g of product identified in TableI.

EXAMPLE 5

A dry reaction vessel was charged with 300 ml of tetrahydrofuran and 160g (143 mmol) of potassium tert-butoxide. The vessel and contents werecooled to about 0 ° C. and then a mixture of 200 ml of ethyl ethercontaining 30 g (119 mmol) of ortho-trifluoromethyl benzhydrol was addeddropwise to the vessel contents. The reaction mixture was stirred fortwo hours at 0° C. Then, 12.0 ml (143 mmol) of methyl bromoacetate wasadded dropwise to the reaction mixture at 0° C. The mixture was stirredfor one hour, cooling was discontinued, and the mixture was stirred onemore hour. Then, 200 ml of water and 200 ml of ethyl ether were added.The ether layer was dried over magnesium sulfate, then solvent wasremoved under reduced pressure to provide 33.9 g of a light-yellow oil.This oil was purified by HPLC using a 5% ethyl acetate-in-hexane eluentto provide product identified in Table I.

EXAMPLE 6

A reaction vessel was charged with 100 ml of methylene chloride, 10 mlof triethylamine and 13 g (50 mmol) of benzyl alcohol. Then, a mixtureof 100 ml of benzene containing 13 g (50 mmol) benzhydryloxyacetic acidchloride was added dropside to the vessel contents with vigorousstirring. The reaction mixture became cloudy with precipitate. Themixture was stirred 4 hours and then washed twice with 300 ml of water.The benzene layer was dried over magnesium sulfate and then concentratedunder reduced pressure to provide a light yellow oil. This oil wastriturated in 100 ml of pentane, then recrystallized in 100 ml of hexaneto provide 8.9 g of product identified in Table I.

EXAMPLE 7

A reaction vessel was charged with 100 ml of methylene chloride, 2.5 mlof n-propanol and 6 ml (43 mmol) of triethylamine. Then, a mixture of 20ml of methylene chloride containing 10 g (38.4 mmol) ofbenzhydryloxyacetic acid chloride was added dropwise to the vesselcontents. The reaction mixture was stirred for 72 hours, then washedtwice with 200 ml of water, dried over magnesium sulfate andconcentrated under reduced pressure to provide 10.3 g of a light amberoil. This oil was purified by HPLC using 2% ethyl acetate-in-hexaneeluent to provide 8 g of product identified in Table I.

EXAMPLE 8

By the procedure of Example 7, a reaction of 25 ml of isopropanol, 10 g(38.4 mmol) of benzhydryloxyacetic acid chloride and 6 ml oftriethylamine yielded an oil which was purified by HPLC using 2% ethylacetate-in-hexane eluent to provide 7.6 g of product identified in TableI.

EXAMPLE 9

By the procedure of Example 7, a reaction of 3.1 ml (40 mmol) of2,2,2-trifluoroethyl alcohol, 10 g (38.4 mmol) of benzhydryloxyaceticacid chloride and 6 ml triethylamine yielded an oil which was purifiedby HPLC using 2% ethyl acetate-in-hexane eluent to provide 10.1 g ofproduct identified in Table I.

EXAMPLE 10

To a reaction vessel containing 6.2 g (260 mmol) of sodium hydridepowder, there was added dropwise a mixture of 300 ml tetrahydrofurancontaining 52 g (240 mmol) of 4-chlorobenzhydrol with vigorous stirring.Immediate gas evolution and a temperature rise to 32° C. were observed.The reaction mixture was stirred for 5 hours. The reaction mixtureappeared as a clear solution in contact with a small amount of sodiumhydride. Then, over a period of 1/2 hour, a mixture of 100 mltetrahydrofuran containing 43.4 g (260 mmol) ethyl bromoacetate wasadded to the vessel contents. A solid material formed immediately. Themixture was stirred for hours and then refluxed one hour. Then, 300 mlof methylene chloride and 400 ml of water were added to the mixturewhich was stirred vigorously. Methylene chloride was concentrated underreduced pressure to provide 80.5 g of an amber oil which was purified byHPLC using 2% ethyl acetate-in-hexane eluent to provide productidentified in Table I.

EXAMPLE 11

A reaction vessel was charged with 20 ml of ethyl ether, 2 g (6.4 mmol)of 3-trifluoromethyl benzhydryloxyacetic acid and 0.7 ml of tert-butylamine. The reaction mixture was stirred overnight at room temperature.No precipitate was observed. The solvent was allowed to evaporate. Thesolid material left was triturated with pentane to provide 2.1 g of awhite solid product identified in Table I.

EXAMPLE 12

A reaction vessel was charged with 200 ml of methylene chloride, 4 ml(64 mmol) of 2-propanethiol and 5.6 ml (40 mmol) triethylamine. Then, amixture of 75 ml methylene chloride containing 9.7 g (36 mmol) ofbenzhydryloxyacetic acid chloride was added dropwise to the vesselcontents under stirring. The reaction mixture was stirred for 2 hours,washed twice with 600 ml water, dried over magnesium sulfate, andconcentrated under reduced pressure to yield 9.4 g of a yellow solidmaterial. This material was recrystallized from 7.5 ml cyclohexane toprovide 3.4 g light-yellow crystal product identified in Table I.

EXAMPLE 13

A reaction vessel was charged with 7.5 ml of methylene chloride, 7.5 g(31 mmol) of benzylhydryloxyacetic acid chloride, 3.1 g (32.5 mmol) ofphenol and 0.3 g of dimethylaminopyridine. The reaction vessel andcontents were cooled to 0° C. and then a mixture of 50 ml of methylenechloride containing 6.7 g (32.5 mmol) of dicyclohexylcarbodiimide wasadded dropwise. The reaction mixture was stirred overnight and allowedto reach room temperature. The solid material was removed by filtration.The filtrate was concentrated under reduced pressure to provide a whitesolid material. This material was triturated with ethyl ether, thenfiltered, and the ether removed under reduced pressure to provide 8.6 gof a white solid material. This material was recrystallized from 50 mlof cyclohexane to provide white crystals identified in Table I.

EXAMPLE 14

A reaction vessel was charged with 100 ml of methylene chloride, 10 g(41 mmol) of benzhydryloxyacetic acid, 4.7 g (43 mmol) of thiophenol and0.3 g of 4-dimethylaminopyridine. The reaction vessel and contents werecooled to -30° C. and then a mixture of 50 ml of methylene chloridecontaining 8.9 g (43 mmol) of dicyclohexylcarbodiimide was addeddropwise with vigorous stirring of the reaction vessel contents. Withthe temperature of the reaction mixture at 0° C., a white solidprecipitate formed. The mixture was stirred overnight and then filtered.The filtrate was concentrated under reduced pressure to provide a whitesolid material. This material was triturated with ethyl ether andfiltered to remove 3.4 g of white solid material. The ether filtrate wasconcentrated under reduced pressure to provide 9.6 g of white solidmaterial. The combined solid materials were recrystallized from 150 mlcyclohexane, filtered and then dried under reduced pressure to provideproduct identified in Table I.

EXAMPLE 15

A reaction vessel was charged with 100 ml of benzene, 5.2 g (20.5 mmol)of 4,4'-dichlorobenzhydrol, 2.8 g (30.8 mmol) of methyl glycolate and0.3 g of para-toluenesulfonic acid. The reaction mixture was refluxedfor 2 hours with a Dean-Stark trap after which time 0.5 ml water wascollected. The reaction mixture was cooled to room temperature, washedwith 200 ml water, dried over magnesium sulfate, and concentrated underreduced pressure to provide a light-yellow oil. This oil was purified byHPLC using a 2% ethyl acetate-in-hexane eluent to provide productidentified in Table I.

EXAMPLE 16

A reaction vessel was charged with 100 ml of methylene chloride, 3 ml ofethyl mercaptan and 5.6 ml of triethylamine. Then, a mixture of 50 mlmethylene chloride containing 10 g (38.4 mmol) of benzhydryloxyaceticacid chloride was added dropwise to the reaction vessel contents. Themixture was stirred in a closed vessel overnight, then washed twice with200 ml of water, dried over magnesium sulfate, and then concentratedunder reduced pressure to provide a yellow oil. This oil was trituratedwith pentane to provide a solid material which was then recrystallizedfrom cyclohexane to give 7.0 g of yellow crystal product identified inTable I.

EXAMPLE 17

By the procedure of Example 6, a reaction of 7 g (27 mmol) ofbenzhydryloxyacetic acid chloride, 3.7 g (28 mmol) of1H,1H,3H-tetrafluoropropanol and 4 ml of triethylamine yielded 6.3 g ofclear colorless oil product identified in Table I.

EXAMPLE 18

A dry reaction vessel was charged with 200 ml of dimethylformamide and17.2 g (60 mmol) of 2-chloro-5-trifluoromethylbenzhydrol. The vessel andcontents were cooled to -30° C. and the contents placed under a nitrogenblanket. Then, 2.2 g (90 mmol) of sodium hydride was added in one batch.The mixture warmed to 0° C. and slow gas evolution was observed. Themixture, under a nitrogen blanket, was stirred overnight at roomtemperature. The vessel and contents were cooled to -30° C. and 8.5 ml(90 mmol) of methyl bromoacetate was added dropwise. The reactionmixture was allowed to reach room temperature during a two-hour stirringperiod. Then, 200 ml of ethyl ether and 100 ml of water were added. Theether portion of the mixture was washed with an additional 500 ml ofwater, dried over magnesium sulfate, and then concentrated under reducedpressure to provide 22.1 g of light-yellow oil which was purified byHPLC using a 3.7% ethyl acetate-in-hexane eluent to provide productidentified in Table I.

EXAMPLE 19

A reaction vessel was charged with 100 ml of methylene chloride, 3.3 ml(35 mmol) of isopropyl mercaptan, and 4.9 ml (35 mmol) of triethylamine.Then, a mixture of 50 ml of methylene chloride containing 9.8 g (30mmol) of benzhydryloxyacetic acid chloride was added dropwise to thevessel contents. The reaction mixture was stirred overnight in a closedvessel, then washed with water, dried over magnesium sulfate, andconcentrated under reduced pressure leaving an oil which was purified byHPLC using a 2% ethyl acetate-in-hexane eluent to provide 8.9 g of ayellow oil product identified in Table I.

EXAMPLE 20

A reaction vessel was charged with 200 ml methylene chloride, 4.6 g (40mmol) of 1,1,1-trifluoro-2-propanol and 6 ml of triethylamine. Then, amixture of 100 ml of methylene chloride containing 12 g (36.5 mmol) of3-trifluoromethylbenzhydrylacetic acid chloride was added dropwise tothe vessel contents. The reaction mixture was stirred in a closed vesselfor 72 hours. The mixture was washed with 500 ml of water, dried overmagnesium sulfate, and then concentrated under reduced pressure toprovide 14.4 g of oil purified by HPLC using 1% ethyl acetate-in-hexaneto give product identified in Table I.

EXAMPLE 21

A reaction vessel was charged with 100 ml of methylene chloride, 4.0 g(28 mmol) of para-chlorobenzyl alcohol and 2.83 g of triethylamine.Then, a mixture of 75 ml of methylene chloride containing 7.0 g (27mmol) of benzhydryloxyacetic acid chloride was dropwise to the vesselcontents with stirring continuing overnight. The reaction mixture waswashed with water, dried over magnesium sulfate, and concentrated underreduced pressure to provide an off-white and oily solid which wasrecrystallized from hexane to provide white crystal product identifiedin Table I.

EXAMPLE 22

A reaction vessel was charged with 150 ml of toluene, 20.0 g (83 mmol)of 2,6,2'6'-tetramethylbenzhydrol, 17.3 g (166 mmol) of ethyl glycolateand 0.6 g (3 mmol) of para-toluenesulfonic acid. The reaction mixturewas heated to reflux and held at reflux for 3 hours, after which time2.8 ml of water was collected (Dean-Stark trap). The mixture wasconcentrated under reduced pressure to provide 19 g of a brown oil. Thisoil was dissolved in methanol, cooled to 0° C. and then 6 g of potassiumhydroxide was added in one batch to the methanol-oil mixture. Thismixture was stirred at 0° C. for one hour and then stirred at roomtemperature for two hours. Methanol was concentrated under reducedpressure to provide a light brown oil. This oil was partitioned betweenwater and ethyl ether. The aqueous layer was acidified with 10%hydrochloric acid and a cloudy oil rose to the top of the aqueous layer.The aqueous layer was extracted with ethyl ether, the ether layer wasdried with magnesium sulfate, and concentrated under reduced pressure toprovide 11.8 g of a white solid which was recrystallized frommethylcyclohexane to give product identified in Table I.

EXAMPLE 23

By the procedure of Example 13, a reaction of 8.50 g (35 mmol) ofbenzhydryloxyacetic acid, 4.87 g (35 mmol) of 3-nitrophenol, 7.24 g (35mmol) of dicyclohexylcarbodiimide and 0.61 g (5 mmol) of 4-dimethylaminopyridine yielded 7.97 g of white solid which was recrystallized frommethylcyclohexane/toluene (20:1) to give product identified in Table I.

EXAMPLE 24

A reaction vessel was charged with 250 ml of toluene, 8.0 g (33 mmol) of2,2',6,6'-tetramethylbenzhydrol, 4.16 g (40 mmol) of ethyl glycolate and1.9 g (10 mmol) of para-toluenesulfonic acid. The reaction mixture washeated to reflux under a nitrogen blanket and a Dean-Stark trap was usedto collect water of reaction. After a four-hour reflux period, thereaction mixture was washed with aqueous sodium bicarbonate. Then, theorganic layer was separated, dried with magnesium sulfate, andconcentrated under reduced pressure to provide an oil. This oil waspurified by HPLC using a 20:1 hexane:ethyl acetate eluent to provide asolid material, which when recrystallized from hexane-ether, yielded awhite solid product identified in Table I.

EXAMPLE 25

By the procedure of Example 13, a reaction of 40.0 g of (170 mmol) ofbenzhydryloxyacetic acid, 21.8 g (200 mmol) of 3-pyridinylcarbinol, 41.2g (200 mmol) of dicyclohexylcarbodiimide and 2.44 g (20 mmol) of4-dimethylaminopyridine yielded 32.6 g of crystal product identified inTable I.

EXAMPLE 26

By the procedure of Example 13, a reaction of 8.1 g (32 mmol) of2-methylbenzhydryloxyacetic acid, 2.94 g (47 mmol) of ethanethiol, 6.6 g(32 mmol) of dicyclohexylcarbodiimide and 0.8 g (6 mmol) of4-dimethylaminopyridine yielded 7.7 g of a clear oil product identifiedin Table I.

EXAMPLE 27

By the procedure of Example 13, a reaction of 7.0 g (30 mmol) ofbenzhydryloxyacetic acid, 2.55 g (30 mmol) of acetone cyanohydrin, 6.18g (30 mmol) of dicyclohexylcarbodiimide and 0.12 g (1 mmol) of-dimethylaminopyridine yielded 2.3 g of white crystal product identifiedin Table I.

EXAMPLE 28

By the procedure of Example 13, a reaction of 6.0 g (20 mmol) of2,2'6,6'-tetramethylbenzhydryloxyacetic acid, 1.25 g (20 mmol) ofethanethiol, 4.2 g (20 mmol) of dicyclohexylcarbodiimide and 0.5 g (4mmol) of para-dimethylaminopyridine yielded 3.95 g of white crystalproduct identified in Table I.

EXAMPLE 29

By the procedure of Example 13, a reaction of 7 g (29 mmol) ofbenzhydryloxyacetic acid, 2.2 g (31 mmol) of 3-hydroxypropionitrile, 6.4g (31 mmol) of dicyclohexylcarbodiimide and 0.5 g (4 mmol) of4-dimethylaminopyridine yielded 3.0 g of a yellow oil product identifiedin Table I.

EXAMPLE 30

By the procedure of Example 13, a reaction of 10 g (30 mmol) of2,2',6,6$0 -tetramethylbenzhydryloxyacetic acid, 3.0 g (35 mmol) ofacetone cyanohydrin, 7.2 g (35 mmol) of dicyclohexylcarbodiimide and0.37 g (3 mmol) of 4-dimethylaminopyridine yielded 5.4 g of a whitecrystal product identified in Table I.

EXAMPLE 31

By the procedure of Example 13, a reaction of 12 g (40 mmol) of2,2',6,6'-tetramethylbenzhydryloxyacetic acid, 2.66 g (35 mmol) of2-propanethiol, 8.25 g (40 mmol) of dicyclohexylcarbodiimide and 0.49 g(4 mmol) of 4-dimethylaminopyridine yielded 6.17 g of white crystalproduct identified in Table I.

EXAMPLE 32

By the procedure of Example 13, a reaction of 10.4 g (40 mmol) ofbenzhydryloxyacetic acid, 3.15 g (45 mmol) of 3-butyn-2-ol, 10.3 g (50mmol) of dicyclohexylcarbodiimide and 0.49 g (4 mmol) of4-dimethylaminopyridine yielded 8.34 of a clear, colorless oil productidentified in Table I.

EXAMPLE 33

By the procedure of Example 13, a reaction of 7.0 g (25 mmol) of4-chlorobenzhydryloxyacetic acid, 3.5 g (25 mmol) of meta-nitrophenol,5.6 g (27 mmol) of dicyclohexylcarbodiimide and 0.37 g (3 mmol) of4-dimethylaminopyridine yielded 3.4 g of a yellow, viscous oil productidentified in Table I.

EXAMPLE 34

By the procedure of Example 13, a reaction of 7.0 g (25 mmol) of4-chlorobenzylhydryloxyacetic acid, 2.13 g (25 mmol) of acetonecyanohydrin, 5.6 g (27 mmol) of dicyclohexylcarbodiimide and 0.37 g (3mmol) of 4-dimethylaminopyridine yielded 5.0 g of a clear, colorless oilproduct identified in Table I.

EXAMPLE 35

By the procedure of Example 13, a reaction of 6.5 g (27 mmol) ofbenzhydryloxyacetic acid, 2.3 g (27 mmol) of ethyl ethynylcarbinol, 5.7g (28 mmol) of dicyclohexylcarbodiimide and 0.4 g (3 mmol) of4-dimethylaminopyridine yielded 7.1 g of a clear, colorless oil productidentified in Table I.

EXAMPLE 36

A reaction vessel was charged with 400 ml of methylene chloride, 10.0 g(36 mmol) of 4-chlorobenzhydryloxyacetic acid, 2.1 g (35 mmol) of allylalcohol and 0.47 g (4 mmol) of 4-dimethylaminopyridine. While thismixture was being stirred, 7.6 g (37 mmol) of dicyclohexylcarbodiimidewas added slowly to the reaction vessel. After stirring overnight, themixture was filtered. The filtrate was concentrated under reducedpressure and the residue was purified by HPLC using a 25:1 hexane:ethylacetate eluent to provide 9.0 g of a clear light-yellow oil identifiedin Table I. ##STR26##

BIOLOGICAL EVALUATION

Effective weed control coupled with low crop injury is a result oftreatment of a plant locus with a combination of herbicide compound andantidote compound. By application to the "plant locus" is meantapplication to the plant growing medium, such as to soil, as well as tothe seeds, emerging seedlings, roots, stems, leaves, or other plantparts.

The phrase "combination of herbicide compound and antidote compound"embraces various methods of treatment. For example, the soil of a plantlocus may be treated with a "tank-mix" composition containing a mixtureof the herbicide and the antidote which is "in combination". Or, thesoil may be treated with the herbicide and antidote compounds separatelyso that the "combination" is made on, or in, the soil. After suchtreatments of the soil, with a mixture of herbicide and antidote, or byseparate or sequential application of the herbicide and antidote to thesoil, the herbicide and antidote may be mixed into or incorporated intothe soil either by mechanical mixing of the soil with implements or by"watering in" by rainfall or irrigation. The soil of a plant locus mayalso be treated with antidote by application of the antidote in adispersible-concentrate form such as a granule. The granule may beapplied to a furrow which is prepared for receipt of the crop seed andthe herbicide may be applied to the plant locus either before or afterin-furrow placement of the antidote-containing granule so that theherbicide and antidote form a "combination". Crop seed may be treated orcoated with the antidote compound either while the crop seed isin-furrow just after seeding or, more commonly, the crop seed may betreated or coated with antidote prior to seeding into a furrow. Theherbicide may be applied to the soil plant locus before or after seedingand a "combination" is made when both herbicide and antidote-coated seedare in the soil. Also contemplated as a "combination" is acommercially-convenient association or presentation of herbicide andantidote. For example, the herbicide and antidote components inconcentrated form may be contained in separate containers, but suchcontainers may be presented for sale or sold together as a"combination". Or, the herbicide and antidote components in concentratedform may be in a mixture in a single container as a "combination".Either such "combination" may be diluted or mixed with adjuvantssuitable for soil applications. Another example of acommercially-presented combination is a container of antidote-coatedcrop seed sold, or presented for sale, along with a container ofherbicide material. These containers may, or may not, be physicallyattached to each other, but nonetheless constitute a "combination ofherbicide and antidote" when intended for use ultimately in the sameplant locus.

The amount of antidote employed in the methods and compositions of theinvention will vary depending upon the particular herbicide with whichthe antidote is employed, the rate of application of the herbicide, theparticular crop to be protected, and the manner of application to theplant locus. In each instance the amount of antidote employed is a"safening-effective amount", that is, an amount which reduces, orprotects against, crop injury that otherwise would result from thepresence of the herbicide. The amount of antidote employed will be lessthan an amount that will substantially injure the crop plant.

The antidote can be applied to the crop plant locus in a mixture withthe selected herbicide. For example, where the crop seed is firstplanted, a suitable mixture of antidote and herbicide, whether in ahomogeneous liquid, emulsion, suspension or solid form, can be appliedto the surface of, or incorporated in, the soil in which the seed hasbeen planted. Or, the herbicide-antidote mixture may be applied to thesoil, and then the seed thereafter "drilled" into or below the soillayer containing the herbicide-antidote mixture. The herbicide willreduce or eliminate the presence of undesirable weed plants. Where theherbicide would by itself injure the crop seedlings, the presence of theantidote will reduce or eliminate the injury to the crop seed caused bythe herbicide. It is not essential that the application of herbicide andthe antidote to the plant locus be made using the selected herbicide andantidote in the form of a mixture or composition. The herbicide and theantidote may be applied to the plant locus in a sequential manner. Forexample, the antidote may be first applied to the plant locus andthereafter the herbicide is applied. Or, the herbicide may be firstapplied to the plant locus and thereafter the antidote is applied.

The ratio of herbicide to antidote may vary depending upon the crop tobe protected, weed to be inhibited, herbicide and antidote used, etc.,but normally a herbicide-to-antidote ratio ranging from 1:25-to-50:1(preferably 1:5-to-30:1) parts by weight may be employed. As indicatedabove, the antidote may be applied to the plant locus in a mixture,i.e., a mixture of a herbicidally-effective amount of herbicide and asafening-effective amount of an antidote, or applied sequentially, i.e.,the plant locus may be treated with an effective amount of the herbicidefollowed by a treatment with the antidote or vice versa. In general,effective herbicidal amounts are in the range of about 0.1 to about 12kilograms/hectare. The preferred range of rate of application is fromabout 0.4 to about 10 Kg/ha. Preferably, antidote application ratesrange from about 0.5 Kg/ha down to about 0.05 Kg/ha. It will beappreciated that at times, amounts either below or above these rangeswill be necessary to obtain the best results. The selection of theherbicide to inhibit the emergence and growth of weeds depends upon thespecies of weeds to be controlled and the crop to be protected.

The application of the antidote can be made directly to the seed beforeplanting. In this practice, a quantity of crop seed is first coated withthe antidote. The coated seed is thereafter planted. The herbicide maybe applied to the soil before or after the coated seed is planted.

Evaluations of safening activity of the antidote compounds of thisinvention were carried out using the specific procedures of Examples286-290 in greenhouse testing. Measurements of biological response asreported in Tables II-VII were made in the following manner. A visualcomparison was made between a crop plant treated with herbicide aloneand crop plant having no herbicide or antidote treatment an ("untreatedcontrol"). A number was assigned to this visual comparison indicatingthe percent injury or inhibition to the herbicide-alone treated cropplant (column "WO" in Tables II-VII indicating herbicide "without"antidote). Also, a visual comparison was made between the crop planttreated with herbicide+ antidote combination and the crop plant havingno herbicide or antidote treatment (the untreated control). A number wasassigned to this visual comparison indicating the percent injury orinhibition to the herbicide+antidote treated crop plant (column "W" inTables II-VII indicating herbicide "with" antidote). Where treatmentsinvolved weed plant species, observations of response to herbicide orherbicide+antidote were similarly recorded. The degree of reduction ofherbicide injury provided by an antidote compound is indicated by themagnitude that the plant inhibition number of column "WO" exceeds thecorresponding number of column "W". Also reported in Tables II-VII aredata showing "safening effect" for the herbicide+antidote combinationscalculated from the plant inhibition numbers, the formula forcalculation of which is shown below.

Summarized below is key information for interpreting data reported inTables II-VII:

    ______________________________________                                        Herbicide                                                                     No.     Name                                                                  ______________________________________                                        1       ethyl dipropylthiocarbamate (EPTC);                                   2       2,3,3-trichloroallyl-diisopropylthiolcarbamate                                (triallate);                                                          3       2-chloro-4-ethylamino-6-isopropylamino-sym-                                   triazine (atrazine);                                                  4       2-chloro-2'-(1,1-dimethylethyl)-6'-methyl-N-                                  (methoxymethyl)acetanilide;                                           5       1-(3,4-dichlorophenyl)-3,3-dimethylurea;                              6       2-chloro-2',6'-diethyl-N-(methoxymethyl)-                                     acetanilide (alachlor);                                               7       dimethylamine salt of 2-methoxy-3,6-                                          dichlorobenzoic acid;                                                 8       α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-                 toluidine (trifluralin);                                              9       2-chloro-N-(isobutoxymethyl)-2',6'-acetoxy-                                   lidide;                                                               10      2-chloro-2',6'-diethyl-N-(butoxymethyl)-                                      acetanilide (butachlor);                                              11      2-chloro-N-(ethoxymethyl)-6'-ethyl- -o-aceto-                                 toluidide (acetochlor);                                               12      2-chloro-N-(2,6-dimethyl-1-cyclohexen-1-yl)-N-                                (2-ethoxyethyl)acetamide;                                             13      2-chloro-4-(isopropylamino)-6-[N-ethyl-N-                                     (2-methylpropenyl)amino]sym-triazine;                                 14      2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-                                 -o-acetotoluidide (metolachlor);                                     15      2-chloro-2'-methyl-6'-methoxy-N-(isopropoxy                                   methyl)acetanilide;                                                   16      2-chloro-N-(2,6-dimethyl-1-cyclohexen-1-yl)-N-                                (1H-pyrazol-1-ylmethyl)acetamide;                                     17      2-chloro-6'-trifluoromethyl-N-(isopropoxy                                     methyl)acetanilide;                                                   18      2-chloro-2'-methyl-6'-trifluoromethyl-N-                                      (ethoxymethyl)acetanilide;                                            19      2-chloro-2'-trifluoromethyl-6-methyl-N-                                       (propoxymethyl)acetanilide;                                           20      2-chloro-2'-methyl-6'-trifluoromethyl-N-                                      (isopropoxymethyl)acetanilide;                                        21      2-chloro-2'-(3-methylbutoxy)-6'-methyl-N-                                     (methyl)acetanilide;                                                  22      2-chloro-2'-isobutoxy-6'-methyl-N-(propoxy-                                   methyl)acetanilide;                                                   23      2-chloro-2'-methyl-6'-propoxy-N-(methyl)                                      acetanilide;                                                          24      2-chloro-2'-butoxy-6'-methyl-N-(methyl)                                       acetanilide;                                                          25      2-chloro-2'-propoxy-6'-methyl-N-(ethoxy-                                      methyl)acetanilide;                                                   26      2-chloro-2'-butoxy-6'-ethyl-N-(methyl)                                        acetanilide;                                                          27      α-chloro-N-(ethoxymethyl)-N-[2-methyl-1-                                (1-methylethyl)-1-propenyl]acetamide;                                 28      2-chloro-2',6'-dimethyl-N-(1-pyrazolyl-                                       methyl)acetanilide;                                                   29      2-chloro-2'-methoxy-3',6'-dimethyl-N-                                         (1-methylethoxymethyl)acetanilide;                                    30      2-chloro-2'-ethyl-6'-(2-methylpropoxy)-N-                                     (ethoxymethyl)acetanilide;                                            31      2-chloro-2'-methyl-6'-(1-methylbutoxy)-N-                                     (methyl)acetanilide;                                                  32      2-chloro-2'-ethyl-6'-(1-methylpropyl)-N-                                      (methyl)acetanilide;                                                  33      2-chloro-N-{[4-methoxy-6-methyl-1,3,5-triazin-                                2-yl)amino]carbonyl}benzenesulfonamide;                               34      2-chloro-N-[1-(2-chloro-6-fluorophenyl)-                                      2-methyl-1-propen-1-yl]-N-(2-propenyl)-                                       acetamide;                                                            35      2-chloro-1-(3'-ethoxy-4'-nitrophenoxy)-4-                                     trifluoromethylbenzene (oxyfluorofen);                                36      S-4-chlorobenzyl diethylthiocarbamate                                         (benthiocarb);                                                        37      2-chloro-2',6'-diethyl-N-(2-propoxyethyl)-                                    acetanilide (pretilachlor);                                           38      methyl 2-[{[{[(4,6-dimethoxy-2-pyrimidinyl)-                                  amino]carbonyl}amino]sulfonyl}methyl]benzoate                                 (DPX-5384).                                                           ______________________________________                                        Antidote No. = Compound in corresponding Example No.                          Rate = Kilograms/hectare (Kg/ha).                                             W = % Plant Inhibition caused by combination of                               herbicide and antidote.                                                       WO = % Plant Inhibition caused by herbicide alone.                             ##STR27##                                                                

The following procedure shows interaction between herbicide and antidotewhen both are incorporated in a soil cover layer before emergence ofcrop and weed species Containers were filled and compacted with afumigated silt loam top soil to a depth of about 1.3 cm from the top ofthe container. A first container was designated as an untreated control,a second container was designated as a herbicide control, and a thirdcontainer was designated as a herbicide+antidote test container. Each ofthe containers was seeded with a crop species. A measured amount ofherbicide dispersed or dissolved in acetone was applied to a measuredquantity of soil. To this same quantity of soil treated with herbicide,there was added a measured amount of antidote dispersed or dissolved inacetone. The quantity of soil treated with the herbicide and antidotewas thoroughly mixed to incorporate the herbicide and antidote in thesoil uniformly. The seed bed in the third container of soil was coveredwith the soil treated with the herbicide and antidote and the containerwas leveled. For each test series, the seed beds of the first and secondcontainers were likewise covered by soil layers. The cover layer of thefirst container was not treated with herbicide or antidote. The coverlayer of the second container had a measured quantity of herbicide aloneincorporated therein. The containers were then placed on a bench in agreenhouse and sub-irrigated as required for the duration of the test.Plant response was observed about three weeks after initial treatment.Results are reported in Table II.

    TABLE II      % PLANT INHIBITION AND % SAFENING EFFECT ()    SORGHUM     HEMP VELVET     HERBICIDE ANTIDOTE RICE GRAIN WHEAT CORN COTTON SOYBEAN SESBANIA LEAF     NO. RATE NO. RATE W  WO W  WO W  WO W  WO W  WO W  WO W  WO W  WO       27 0.14 1 8.96 0  25 10  60 20  40 0  25                  (100)   (83)       (50)   (100) 27 0.56 1 8.96 75  90 70  95 45  85 15  50      (16)     (26)   (47)   (70) 27 2.24 1 8.96 100  98 99  99 90  99 35  80      (0)      (0)   (9)   (56) 3 0.56 1 8.96 30  40    40  50    50  10 50  30     (25)      (20)      (0)   (0) 3 2.24 1 8.96 70  80    98  95    20  90     90  90      (12)      (0)      (77)   (0) 3 8.96 1 8.96 98  98    100     99    85  98 99  99      (0)      (0)      (13)   (0) 4 0.14 1 8.96 0     30 0  25 10  25 0  15      (100)   (100)   ( 60)   (100) 4 0.56 1 8.96     75  70 65  85 45  65 30  55      (0)   (23)   (30)   (45) 4 2.24 1 8.96     80  99 80  98 75  98 30  85      (19)   (18)   (23)   (64) 12 0.14 1     8.96 0  20 15  50 10  25 10  20      (100)   (70)   (60)   (50) 12 0.56     1 8.96 70  50 60  85 60  70 25  70      (0)   (29)   (14)   (64) 12 2.24     1 8.96 95  90 98  100 85  80 75  80      (0)   (2)   (0)   (6) 13 0.56 1     8.96 10  30    30  20    10  0    20  40      (66)      (0)      (0)      (50) 13 2.24 1 8.96 15  40    40  45    10  20    65  75      (62)     (11)      (50)      (13) 13 8.96 1 8.96 65  55    80  98    15  45     100  98      (0)      (18)      (66)      (0) 16 0.14 1 8.96 0  60 25     75 0  70 0  70      (100)   (66)   (100)   (100) 16 0.56 1 8.96 75  95     98  99 70  99 50  85      (21)   (1)   (29)   (41) 16 2.24 1 8.96 100     100 98  100 80  100 75  98      (0)   (2)   (20)   (23) 17 0.28 1 8.96     50  80 0  65 0  15 0  0      (37)   (100)   (100)   (0) 17 1.12 1 8.96     65  99 15  98 35  55 0  0      (34)   (84)   (36)   (0) 17 4.48 1 8.96     98  100 60  100 80  98 10  15      (2)   (40)   (18)   (33) 18 0.28 1     8.96 65  95 30  95 55  70 10  0      (31)   (68)   (21)   (0) 18 1.12 1     8.96 100  100 55  98 70  98 0  10      (0)   (43)   (28)   (100) 18 4.48     1 8.96 100  100 90  99 85  99 0  30      (0)   (9)   (14)   (100) 19     0.28 1 8.96 50  85 20  90 30  40 20  20      (41)   (77)   (25)   (0) 19     1.12 1 8.96 85  95 75  99 75  70 25  40      (10)   (24)   (0)   (37) 19     4.48 1 8.96 100  100 97  99 85  95 25  60      (0)   (2)   (10)   (58)     20 0.28 1 8.96 80  90 95  100 60  85 40  80      (11)   (5)   (29)     (50) 20 1.12 1 8.96 96  98 85  100 75  90 75  95      (2)   (15)   (16)      (21) 20 4.48 1 8.96 100  100 100  100 85  99 95  99      (0)   (0)     (14)   (4) 21 0.28 1 8.96 70  80 60  90 50  85 0  40      (12)   (33)     (41)   (100) 21 1.12 1 8.96 80  85 90  95 100  90 35  85      (5)   (5)      (0)   (58) 21 4.48 1 8.96 98  100 100  100 90  92 85  98      (2)   (0)       (2)   (13) 22 0.28 1 8.96 55  70 15  90 40  70 0  45      (21)   (83)      (42)   (100) 22 1.12 1 8.96 80  90 60  95 80  90 25  75      (11)     (36)   (11)   (66) 22 4.48 1 8.96 100  100 75  100 98  98 75  98     (0)   (25)   (0)   (23) 23 0.28 1 8.96 45  60 70  90 50  45 0  20     (25)   (22)   (0)   (100) 23 1.12 1 8.96 80  80 95  95 80  70 20  75      (0)   (0)   (0)   (73) 23 4.48 1 8.96 95  100 100  100 100  98 75  95        (5)   (0)   (0)   (21) 24 0.14 1 8.96 60  70 95  99 10  65 20  25      (14)   (4)   (84)   (20) 24 0.14 1 8.96 0  45 95  95 40  65 10  50     (100)   (0)   (38)   (80) 24 0.56 1 8.96 30  75 100  98 80  90 50  90       (60)   (0)   (11)   (44) 24 0.56 1 8.96 70  90 100  100 75  85 40  90         (22)   (0)   (11)   (55) 24 2.24 1 8.96 95  98 100  100 95  95 90     99      (3)   (0)   (0)   (9) 24 2.24 1 8.96 70  85 100  100 90  98 90     98      (17)   (0)   (8)   (8) 25 0.28 1 8.96 80  80 15  98 30  45 20     70      (0)   (84)   (33)   (71) 25 1.12 1 8.96 85  98 40  98 60  70 45     85      (13)   (59)   (14)   (47) 25 4.48 1 8.96 100  100 98  100 85     100 75  98      (0)   (2)   (15)   (23) 26 0.28 1 8.96 70  90 70  98 60     80 0  20      (22)   (28)   (25)   (100) 26 1.12 1 8.96 75  95 75  100     65  95 0  80      (21)   (25)   (31)   (100) 26 4.48 1 8.96 85  99 90     100 100  100 65  90      (14)   (10)   (0)   (27) 29 0.28 1 8.96 65  55     0  20 35  40 0  0      (0)   (100)   (12)   (0) 29 1.12 1 8.96 70  85 20      60 35  60 0  15      (17)   (66)   (41)   (100) 29 4.48 1 8.96 85  95     25  85 60  75 10  30      (10)   (70)   (20)   (66) 30 0.28 1 8.96 30     80 10  90 35  90 0  60      (62)   (88)   (61)   (100) 30 1.12 1 8.96 90      97 35  97 80  97 40  95      (7)   (63)   (17)   (57) 30 4.48 1 8.96     100  100 90  99 100  100 80  99      (0)   (9)   (0)   (19) 31 0.14 1     8.96 20  10 40  90 10  60 0  25      (0)   (55)   (83)   (100) 31 0.56 1     8.96 90  70 100  100 75  85 50  60      (0)   (0)   (11)   (16) 31 2.24     1 8.96 98  97 100  100 90  90 98  95      (0)   (0)   (0)   (0) 32 0.14     1 8.96 0  0 20  70 0  30 0  20      (0)   (71)   (100)   (100) 32 0.56 1     8.96 30  50 98  100 50  30 0  40      (40)   (2)   (0)   (100) 32 2.24 1     8.96 90  90 100  100 50  70 90  50      (0)   (0)   (28)   (0) 2 0.56 1     8.96       75  95            (21) 2 0.56 1 8.96 90  90 50  90 90  98      (0)   (44)   (8) 2 0.56 2 8.96 99  98 50  98 98  95      (0)   (48)     (0) 2 0.56 3 8.96       95  95            (0) 2 0.56 4 8.96       80     100            (20) 2 0.56 5 8.96       75  100            (25) 2 0.56 6     8.96       95  95            (0) 2 0.56 7 8.96       90  100     (10) 2 0.56 8 8.96       90  100            (10) 2 0.56 9 8.96       95     100            (5) 2 0.56 10 8.96       80  95            (15) 2 0.56 11     8.96       45  98            (54) 2 0.56 12 8.96       80  100      (20) 2 0.56 13 8.96       100  95            (0) 2 0.56 14 8.96     95  95            (0) 2 0.56 15 8.96       90  100            (10) 2     0.56 16 8.96       100  100            (0) 2 0.56 17 8.96       80  95              (15) 2 0.56 18 8.96       80  95            (15) 2 0.56 19 8.96           80  90            (11) 2 0.56 20 8.96       65  90            (27)     2 0.56 21 8.96       100  100            (0) 2 0.56 22 8.96       100     90            (0) 2 0.56 23 8.96       60  90            (33) 3 6.72 1     8.96 45  45             85  80      (0)               (0) 3 4.48 3 8.96     85  80             55  90      (0)               (38) 3 4.48 4 8.96 90     80             75  75      (0)               (0) 3 4.48 5 8.96 80  80              85  75      (0)               (0) 3 4.48 6 8.96 100  85         100  90      (0)               (0) 3 4.48 7 8.96 100  90     95  85      (0)               (0) 3 4.48 8 8.96 100  90             90     85      (0)               (0) 3 4.48 9 8.96 90  90             80  85       (0)               (5) 3 4.48 10 8.96 95  80             95  85     (0)               (0) 3 4.48 11 8.96 40  80             60  85      (50)                   (29) 3 4.48 12 8.96 100  85             98  75      (0)                (0) 3 4.48 13 8.96 35  80             40  80      (56)            (50) 3 4.48 14 8.96 55  80             90  80      (31)         (0) 3 4.48 15 8.96 95  90             40  60      (0)     (33) 3 4.48 16 8.96 95  95             95  95      (0)               (0)     3 4.48 17 8.96 85  80             80  85      (0)               (5) 3     4.48 18 8.96 90  90             90  95      (0)               (5) 3 4.48     19 8.96 85  95             80  90      (10)               (11) 3 4.48 20     8.96 100  95             100  90      (0)               (0) 3 4.48 21     8.96 45  90             90  90      (50)               (0) 3 4.48 22     8.96 100  100             90  100      (0)               (10) 3 4.48 23     8.96 100  100             100  100      (0)               (0) 6 2.24 1     8.96    55  90 75  98         (38)   (23) 6 2.24 1 8.96 85  100 70  98     55  80      (15)   (28)   ( 31) 6 2.24 2 8.96 98  99 98  98 70  85     (1)   (0)   (17) 6 2.24 3 8.96    10  80 90  90         (87)   (0) 6     2.24 4 8.96    40  65 25  75         (38)   (66) 6 2.24 5 8.96    45  65     65  75         (30)   (13) 6 2.24 6 8.96    25  95 30  80         (73)     (62) 6 2.24 7 8.96    40  100 35  95         (60)   (63) 6 2.24 8 8.96      30  100 70  95         (70)   (26) 6 2.24 9 8.96    15  100 85  95        (85)   (10) 6 2.24 10 8.96    50  75 40  80         (33)   (50) 6     2.24 11 8.96    30  80 90  85         (62)   (0) 6 2.24 12 8.96    70     99 50  99         (29)   (49) 6 2.24 13 8.96    20  85 80  90     (76)   (11) 6 2.24 14 8.96    10  85 90  90         (88)   (0) 6 2.24 15     8.96    25  95 70  85         (73)   (17) 6 2.24 16 8.96    15  95 90     90         (84)   (0) 6 2.24 17 8.96    25  85 60  90         (70)     (33) 6 2.24 18 8.96    80  85 65  90         (5)   (27) 6 2.24 19 8.96      35  70 55  80         (50)   (31) 6 2.24 20 8.96    35  70 35  80       (50)   (56) 6 2.24 21 8.96    55  75 55  90         (26)   (38) 6 2.24     22 8.96    40  90 100  85         (55)   (0) 6 2.24 23 8.96    45  95 95      100         (52)   (5) 10 6.72 1 8.96 60  80      (25) 10 6.72 1 8.96     40  85 60  75 45  80      (52)   (20)   (43) 10 6.72 2 8.96 45  85 80     80 50  80      (47)   (0)   (37) 10 4.48 3 8.96 75  60      (0) 10 4.48     4 8.96 65  75      (13) 10 4.48 5 8.96 65  75      (13) 10 4.48 6 8.96     30  80      (62) 10 4.48 7 8.96 45  95      (52) 10 4.48 8 8.96 60  95        (36) 10 4.48 9 8.96 50  95      (47) 10 4.48 10 8.96 60  90      (33)     10 4.48 11 8.96 35  90      (61) 10 4.48 12 8.96 10  99      (89) 10     4.48 13 8.96 40  90      (55) 10 4.48 14 8.96 40  90      (55) 10 4.48     15 8.96 80  95      (15) 10 4.48 16 8.96 40  85      (52) 10 4.48 17     8.96 90  95      (5) 10 4.48 18 8.96 60  95      (36) 10 4.48 19 8.96     100  90      (0) 10 4.48 20 8.96 70  90      (22) 10 4.48 21 8.96 50  90          (44) 10 4.48 22 8.96 55  95      (42) 10 4.48 23 8.96 70  95     (26) 15 1.12 1 8.96          30  85               (64) 15 2.24 3 8.96           60  80               (25) 15 2.24 4 8.96          55  75         (26) 15 2.24 5 8.96          40  75               (46) 15 2.24 6     8.96          60  80               (25) 15 2.24 7 8.96          90  90                 (0) 15 2.24 8 8.96          40  90               (55) 15     2.24 9 8.96          15  90               (83) 15 2.24 10 8.96     30  90               (66) 15 2.24 11 8.96          40  95     (57) 15 2.24 12 8.96          10  90               (88) 15 2.24 13 8.96             80  80               (0) 15 2.24 14 8.96          30  80           (62) 15 2.24 15 8.96          20  85               (76) 15 2.24 16     8.96          20  90               (77) 15 2.24 17 8.96          20  90                  (77) 15 2.24 18 8.96          90  90               (0) 15     2.24 19 8.96          65  90               (27) 15 2.24 20 8.96     70  90               ( 22) 15 2.24 21 8.96          85  90     (5) 15 2.24 22 8.96          90  95               (5) 15 2.24 23 8.96           40  100               (60) 3 4.48 44 8.96 98  96    80  97    100     100 100  100      (0)      (17)      (0)   (0)  3 4.48 46 8.96 80  96     90  97    100  100 97  100      (16)      (7)      (0)   (3)  3 4.48 47     8.96 60  40             85  90      (0)               (5)  3 2.24 48     8.96 30  20             85  80 95  90 100  90      (0)               (0)       (0)   (0) 3 4.48 48 8.96 50  40             97  85 98  95 100  95     (0)               (0)   (0)   (0)  3 4.48 48 8.96 10  40             50     90      (75)               (44) 3 6.72 48 8.96 50  70             90  95     95  95 100  98      (28)               (5)   (0)   (0) 3 8.96 48 8.96 60      80             98  98 100  99 95  99      (25)               (0)   (0)      (4) 6 0.56 50 8.96       60  60          20  60 99  98            (0)              (66)   (0) 6 1.12 50 8.96       50  80          60  60 100  98               (37)            (0)   (0) 6 2.24 50 8.96       80  90     50  90 100  97            (11)            (44)   (0) 6 4.48 50 8.96      95  90          70  90 90  100            (0)            (22)   (10) 2     0.56 37 8.96 90  98 50  98 90  90      (8)   (48)   (0) 2 0.56 38 8.96     90  90 50  90 80  98      (0)   (44)   (18) 2 0.56 39 8.96 100  98 50     98 98  95      (0)   (48)   (0) 2 0.56 40 8.96 75  95 80  85 97  97     (21)   (5)   (0) 2 0.56 41 8.96 90  98 20  97 100  100      (8)   (79)     (0) 2 0.56 42 8.96 70  96 10  85 98  99      (27)   (88)   (1) 2 0.56 43     8.96 75  97 10  80 99  100      (22)   (87)   (1) 2 0.56 44 8.96 97  97     40  97 98  100      (0)   (58)   (2) 2 0.56 45 8.96       98  90        (0) 2 0.56 46 8.96 99  97 60  97 98  100      (0)   (38)   (2) 2 0.56     47 8.96 100  97 90  85 100  90      (0)   (0)   (0) 2 0.56 48 8.96 85     85 60  90 80  99      (0)   (33)   (19) 2 0.56 49 8.96       95  95           (0) 2 0.56 50 8.96       98  95            (0) 2 0.56 51 8.96      98  90            (0) 2 0.56 52 8.96       85  90            (5) 2 0.56     53 8.96       97  90            (0) 2 0.56 54 8.96       40  95       (57) 2 0.56 55 8.96       90  90            (0) 2 0.56 56 8.96     95  100            (5) 2 0.56 57 8.96       98  95            (0) 2 0.56     58 8.96       98  95            (0) 2 0.56 59 8.96       70  95       (26) 2 0.56 60 8.96       55  95            (42) 2 0.56 61 8.96     75  95            (21) 2 0.56 62 8.96       90  95            (5) 2 0.56     63 8.96       90  80            (0) 2 0.56 64 8.96       85  90       (5) 2 0.56 65 8.96       90  90            (0) 2 0.56 66 8.96       75      90            (16) 2 0.56 67 8.96       75  90            (16) 2 0.56     68 8.96       90  95            (5) 2 0.56 69 8.96       80  95       (15) 2 0.56 70 8.96       95  95            (0) 2 0.56 71 8.96     100  100            (0) 2 0.56 72 8.96       80  100            (20) 2     0.56 73 8.96       90  95            (5) 2 0.56 74 8.96       75  95            (21) 2 0.56 75 8.96       100  95            (0) 2 0.56 76 8.96         100  95            (0) 2 0.56 77 8.96       90  95            (5) 2     0.56 78 8.96       95  100            (5) 2 0.56 79 8.96       100  100               (0) 2 0.56 80 8.96       95  100            (5) 2 0.56 81 8.96           100  100            (0) 2 0.56 82 8.96       100  100     (0) 2 0.56 83 8.96       100  100            (0) 2 0.56 84 8.96       95      100            (5) 2 0.56 85 8.96       90  100            (10) 2 0.56     86 8.96       90  95            (5) 2 0.56 87 8.96       95  100        (5) 2 0.56 88 8.96       90  100            (10) 2 0.56 89 8.96     95  100            (5) 2 0.56 90 8.96       75  100            (25) 2     0.56 91 8.96       100  100            (0) 2 0.56 92 8.96       95  100               (5) 2 0.56 93 8.96       90  100            (10) 2 0.56 94     8.96       90  95            (5) 2 0.56 95 8.96       100  95     (0) 2 0.56 96 8.96       90  100            (10) 2 0.56 97 8.96       85      100            (15) 2 0.56 98 8.96       90  95            (5) 2 0.56     99 8.96       85  95            (10) 2 0.56 100 8.96       90  95         (5) 2 0.56 101 8.96       90  95            (5) 2 0.56 102 8.96      85  95            (10) 2 0.56 103 8.96       90  95            (5) 2     0.56 104 8.96       95  95            (0) 2 0.56 105 8.96       95  95              (0) 2 0.56 106 8.96       80  95            (15) 2 0.56 107     8.96       90  95            (5) 2 0.56 108 8.96       65  95     (31) 2 0.56 109 8.96       85  95            (10) 2 0.56 110 8.96     90  95            (5) 2 0.56 111 8.96       85  95            (10) 2     0.56 112 8.96       90  80            (0) 2 0.56 113 8.96       75  80              (6) 2 0.56 114 8.96       75  80            (6) 2 0.56 115 8.96           70  80            (12) 2 0.56 116 8.96       75  80            (6)     2 0.56 117 8.96       100  95            (0) 2 0.56 118 8.96       80     95            (15) 2 0.56 119 8.96       95  95            (0) 2 0.56     120 8.96       70  90            (22) 2 0.56 121 8.96       90  90          (0) 2 0.56 122 8.96       45  90            (50) 2 0.56 123 8.96        80  90            (11) 2 0.56 124 8.96       80  90            (11) 2     0.56 125 8.96       90  90            (0) 2 0.56 126 8.96       90  95              (5) 2 0.56 127 8.96       85  95            (10) 2 0.56 128     8.96       75  95            (21) 2 0.56 129 8.96       75  95      (21) 2 0.56 130 8.96       95  95            (0) 2 0.56 131 8.96     90  95            (5) 2 0.56 132 8.96       85  95            (10) 2     0.56 133 8.96       90  95            (5) 2 0.56 134 8.96       35  90              (61) 2 0.56 135 8.96       90  90            (0) 2 0.56 136     8.96       95  90            (0) 2 0.56 137 8.96       90  90     (0) 2 0.56 138 8.96       70  90            (22) 2 0.56 139 8.96     80  85            (5) 2 0.56 140 8.96       90  85            (0) 2 0.56     141 8.96       75  95            (21) 2 0.56 142 8.96       70  95          (26) 2 0.56 143 8.96       90  95            (5) 2 0.56 144 8.96        40  85            (52) 2 0.56 145 8.96       40  85            (52) 2     0.56 146 8.96       45  85            (47) 2 0.56 147 8.96       85  85               (0) 2 0.56 148 8.96       65  85            (23) 2 0.56 149     8.96       40  80            (50) 2 0.56 150 8.96       100  90       (0) 2 0.56 151 8.96       90  95            (5) 2 0.56 152 8.96     90  95            (5) 2 0.56 153 8.96       85  95            (10) 2     0.56 154 8.96       100  95            (0) 2 0.56 155 8.96       85  95               (10) 2 0.56 156 8.96       85  95            (10) 2 0.56 157     8.96       65  95            (31) 2 0.56 158 8.96       95  90      (0) 2 0.56 159 8.96       80  90            (11) 2 0.56 160 8.96     80  90            (11) 2 0.56 161 8.96       80  90            (11) 2 0     56 162 8.96       70  90            (22) 2 0.56 163 8.96       80  90             (11) 2 0.56 164 8.96       80  85            (5) 2 0.56 165 8.96           75  85            (11) 2 0.56 166 8.96       90  90            (0)     2 0.56 167 8.96       90  95            (5) 2 0.56 168 8.96       90  95                (5) 2 0.56 169 8.96       85  90            (5) 2 0.56 170     8.96       100  90            (0) 2 0.56 171 8.96       100  90       (0) 2 0.56 172 8.96       90  95            (5) 2 0.56 173 8.96     40  95            (57) 2 0.56 174 8.96       80  95            (15) 2     0.56 175 8.96       80  90            (11) 2 0.56 176 8.96       100  95                (0) 2 0.56 177 8.96       85  90            (5) 2 0.56 178     8.96       80  90            (11) 2 0.56 179 8.96       95  90      (0) 2 0.56 180 8.96       75  90            (16) 2 0.56 181 8.96     95  90            (0) 2 0.56 182 8.96       85  100            (15) 2     0.56 183 8.96       90  100            (10) 2 0.56 184 8.96       100     100            (0) 2 0.56 185 8.96       100  95            (0) 2 0.56     186 8.96       100  95            (0) 2 0.56 187 8.96       80  90          (11) 2 0.56 188 8.96       80  90            (11) 2 0.56 189 8.96         65  90            (27) 2 0.56 190 8.96       95  95            (0) 2     0.56 191 8.96       70  95            (26) 2 0.56 192 8.96       75  95               (21) 2 0.56 193 8.96       70  100            (30) 2 0.56 194     8.96       95  100            (5) 2 0.56 195 8.96       90  100       (10) 2 0.56 196 8.96       85  100            (15) 2 0.56 197 8.96       95  95            (0) 2 0.56 198 8.96       80  95            (15) 2     0.56 199 8.96       100  75            (0) 2 0.56 200 8.96       80  95               (15) 2 0.56 201 8.96       75  70            (0) 2 0.56 202     0.28       85  90            (5) 3 6.72 45 8.96 85  70             95     85      (0)               (0) 3 4.48 49 8.96 45  30             80  65        (0)               (0) 3 4.48 50 8.96 40  30             60  65     (0)               (7) 3 6.72 51 8.96 60  50             95  95      (0)                  (0) 3 6.72 52 8.96 75  50             99  95      (0)             (0) 3 6.72 53 8.96 10  50             97  95      (80)         (0) 3 6.72 54 8.96 90  80             95  90      (0)     (0) 3 6.72 55 8.96 90  85             98  90      (0)               (0)     3 6.72 56 8.96 100  100             100  100      (0)               (0)     3 4.48 57 8.96 100  100             100  100      (0)               (0)     3 4.48 58 8.96 90  100             100  100      (10)               (0)     3 4.48 59 8.96 100  100             100  100      (0)               (0)     3 4.48 60 8.96 100  100             95  100      (0)               (5) 3     4.48 61 8.96 95  100             90  100      (5)               (10) 3     4.48 62 8.96 100  100             100  100      (0)              (0) 3     4.48 63 8.96 95  98             90  98      (3)               (8) 3 4.48     64 8.96 100  90             100  90      (0)              (0) 3 4.48 65     8.96 95  90             90  90      (0)              (0) 3 4.48 66 8.96     95  90             80  90      (0)               (11) 3 4.48 67 8.96 80     90             90  90      (11)               (0) 3 4.48 68 8.96 70  60                80  70      (0)              (0) 3 4.48 69 8.96 80  60          75  70      (0)               (0) 3 4.48 70 8.96 80  60     90  70      (0)               (0) 3 4.48 71 8.96 90  80             90     75      (0)               (0) 3 4.48 72 8.96 75  90             75  80        (16)               (6) 3 4.48 73 8.96 95  75             100  70     (0)               (0) 3 4.48 74 8.96 85  85             90  90      (0)                  (0) 3 4.48 75 8.96 90  85             90  90      (0)             (0) 3 4.48 76 8.96 100  85             100  90      (0)          (0) 3 4.48 77 8.96 100  85             100  90      (0)       (0) 3 4.48 78 8.96 95  90             95  85      (0)     (0) 3 4.48 79 8.96 95  90             95  85      (0)               (0)     3 4.48 80 8.96 100  90             95  85      (0)               (0) 3     4.48 81 8.96 90  90             25  85      (0)               (70) 3     4.48 82 8.96 80  90             30  85      (11)               (64) 3     4.48 83 8.96 60  90             60  85      (33)               (29) 3     4.48 84 8.96 70  90             60  85      (22)               (29) 3     4.48 85 8.96 90  90             40  85      (0)               (52) 3     4.48 86 8.96 95  80             100  85      (0)               (0) 3     4.48 87 8.96 100  90             75  60      (0)               (0) 3     4.48 88 8.96 85  70             30  60      (0)               (50) 3     4.48 89 8.96 95  70             35  60      (0)               (41) 3     4.48 90 8.96 95  95             100  95      (0)               (0) 3     4.48 91 8.96 80  95             85  95      (15)               (10) 3     4.48 92 8.96 95  95             90  95      (0)               (5) 3 4.48     93 8.96 80  80             100  85      (0)               (0) 3 4.48 94     8.96 85  80             90  90      (0)               (0) 3 4.48 95 8.96     90  80             90  90      (0)               (0) 3 4.48 96 8.96 95     90             95  90      (0)               (0) 3 4.48 97 8.96 100  90                90  90      (0)               (0) 3 4.48 98 8.96 95  90           100  90      (0)               (0) 3 4.48 99 8.96 85  80       85  85      (0)               (0) 3 4.48 100 8.96 85  80     90  85      (0)               (0) 3 4.48 101 8.96 95  80             90     85      (0)               (0) 3 4.48 102 8.96 90  80             95  85         (0)               (0) 3 4.48 103 8.96 95  80             85  85     (0)               (0) 3 4.48 104 8.96 90  80             95  85      (0)                   (0) 3 4.48 105 8.96 90  80             85  85      (0)               (0) 3 4.48 106 8.96 90  80             95  90      (0)           (0) 3 4.48 107 8.96 95  80             90  90      (0)       (0) 3 4.48 108 8.96 90  90             70  100      (0)     (30) 3 4.48 109 8.96 90  80             100  95      (0)     (0) 3 4.48 110 8.96 95  80             80  95      (0)     (15) 3 4.48 111 8.96 90  90             65  100      (0)     (35) 3 4.48 112 8.96 75  80             45  85      (6)     (47) 3 4.48 113 8.96 80  80             75  85      (0)     (11) 3 4.48 114 8.96 90  80             65  85      (0)     (23) 3 4.48 115 8.96 95  80             95  85      (0)     (0) 3 4.48 116 8.96 90  80             85  85      (0)               (0)     3 4.48 117 8.96 90  80             95  80      (0)               (0) 3     4.48 118 8.96 90  80             100  80      (0)               (0) 3     4.48 119 8.96 80  80             90  85      (0)               (0) 3     4.48 120 8.96 95  90             65  80      (0)               (18) 3     4.48 121 8.96 80  90             85  80      (11)               (0) 3     4.48 122 8.96 100  90             100  80      (0)               (0) 3     4.48 123 8.96 95  90             80  80      (0)               (0) 3     4.48 124 8.96 85  90             85  80      (5)               (0) 3     4.48 125 8.96 95  80             90  85      (0)               (0) 3     4.48 126 8.96 80  90             80  90      (11)               (11) 3     4.48 127 8.96 95  90             100  90      (0)               (0) 3     4.48 128 8.96 90  90             95  90      (0)               (0) 3     4.48 129 8.96 90  90             85  90      (0)               (5) 3     4.48 130 8.96 90  90             95  90      (0)               (0) 3     4.48 131 8.96 95  90             90  90      (0)               (0) 3     4.48 132 8.96 95  90             80  90      (0)               (11) 3     4.48 133 8.96 95  90             90  90      (0)               (0) 3     4.48 134 8.96 80  90             90  80      (11)               (0) 3     4.48 135 8.96 90  90             100  80      (0)               (0) 3     4.48 136 8.96 90  80             45  85      (0)               (47) 3     4.48 137 8.96 75  80             90  85      (6)               (0) 3     4.48 138 8.96 90  80             80  85      (0)               (5) 3     4.48 139 8.96 90  85             80  75      (0)               (0) 3     4.48 140 8.96 90  85             60  75      (0)               (20) 3     4.48 141 8.96 95  90             90  90      (0)               (0) 3     4.48 142 8.96 85  90             100  90      (5)               (0) 3     4.48 143 8.96 95  90             100  90      (0)               (0) 3     4.48 144 8.96 90  85             95  80      (0)               (0) 3     4.48 145 8.96 80  85             85  80      (5)               (0) 3     4.48 146 8.96 95  85             100  80      (0)               (0) 3     4.48 147 8.96 95  85             95  80      (0)               (0) 3     4.48 148 8.96 70  85             90  80      (17)               (0) 3     4.48 149 8.96 90  80             85  85      (0)               (0) 3     4.48 150 8.96 95  90             90  85      (0)               (0) 3     4.48 151 8.96 95  90             95  95      (0)               (0) 3     4.48 152 8.96 95  90             100  95      (0)               (0) 3     4.48 153 8.96 95  90             100  95      (0)               (0) 3     4.48 154 8.96 90  90             80  90      (0)               (11) 3     4.48 155 8.96 95  90             95  95      (0)               (0) 3     4.48 156 8.96 90  90             100  95      (0)               (0) 3     4.48 157 8.96 95  90             95  95      (0)               (0) 3     4.48 158 8.96 90  95             95  90      (5)               (0) 3     4.48 159 8.96 95  95             90  90      (0)               (0) 3     4.48 160 8.96 95  95             95  90      (0)               (0) 3     4.48 161 8.96 100  95             95  90      (0)               (0) 3     4.48 162 8.96 95  95             100  90      (0)               (0) 3     4.48 163 8.96 90  95             85  90      (5)               (5) 3     4.48 164 8.96 65  90             85  90      (27)               (5) 3     4.48 165 8.96 95  85             95  95      (0)               (0) 3     4.48 166 8.96 95  90             100  90      (0)               (0) 3     4.48 167 8.96 100  90             100  90      (0)               (0) 3     4.48 168 8.96 100  90             95  90      (0)               (0) 3     4.48 169 8.96 75  90             85  90      (16)               (5) 3     4.48 170 8.96 75  90             70  90      (16)               (22) 3     4.48 171 8.96 80  90             80  90      (11)               (11) 3     4.48 172 8.96 35  85             100  75      (58)               (0) 3     4.48 173 8.96 95  85             85  95      (0)               (10) 3     4.48 174 8.96 90  85             95  95      (0)               (0) 3     4.48 175 8.96 85  90             80  90      (5)               (11) 3     4.48 176 8.96 90  85             100  95      (0)               (0) 3     4.48 177 8.96 95  90             100  90      (0)               (0) 3     4.48 178 8.96 90  90             95  90      (0)               (0) 3     4.48 179 8.96 90  90             85  90      (0)               (5) 3     4.48 180 8.96 85  90             85  90      (5)               (5) 3     4.48 181 8.96 95  90             100  90      (0)               (0) 3     4.48 182 8.96 90  85             95  90      (0)               (0) 3     4.48 183 8.96 65  85             90  90      (23)               (0) 3     4.48 184 8.96 90  90             85  75      (0)               (0) 3     4.48 185 8.96 70  85             60  80      (17)               (25) 3     4.48 186 8.96 100  100             95  90      (0)               (0) 3     4.48 187 8.96 100  100             100  100      (0)               (0) 3     4.48 188 8.96 100  100             100  100      (0)               (0) 3     4.48 189 8.96 100  100             100  100      (0)               (0) 3     4.48 190 8.96 100  100             100  100      (0)               (0) 3     4.48 191 8.96 95  100             95  100      (5)               (5) 3     4.48 192 8.96 100  100             100  100      (0)               (0) 3     4.48 193 8.96 100  95             100  95      (0)               (0) 3     4.48 194 8.96 100  95             100  95      (0)               (0) 3     4.48 195 8.96 100  95             100  95      (0)               (0) 3     4.48 196 8.96 100  100             95  95      (0)               (0) 3     4.48 197 8.96 100  100             95  95      (0)               (0) 3     4.48 198 8.96 100  95             100  95      (0)               (0) 3     4.48 199 8.96 95  60             95  80      (0)               (0) 3     6.72 200 8.96 80  80             80  95      (0)               (15) 3     4.48 201 8.96 60  65             80  75      (7)               (0) 3     6.72 202 0.28 50  95             55  90      (47)               (38) 6     2.24 37 8.96 85  90 70  95 70  80      (5)   (26)   (12) 6 2.24 38 8.96     90  100 75  98 90  80      (10)   (23)   (0) 6 2.24 39 8.96 100  99 99     98 90  85      (0)   (0)   (0) 6 2.24 40 8.96 95  97 97  95 80  75     (2)   (0)   (0) 6 2.24 41 8.96 90  96 65  99 80  90      (6)   (34)     (11) 6 2.24 42 8.96 100  100 30  99 70  80      (0)   (69)   (12) 6 2.24     43 8.96 98  98 35  98 60  85      (0)   (64)   (29) 6 2.24 44 8.96 90     99 70  97 85  99      (9)   (27)   (14) 6 2.24 45 8.96    50  90 60  90            (44)   (33) 6 2.24 46 8.96 100  99 80  97 95  99      (0)   (17)      (4) 6 2.24 47 8.96 100  99 95  99 100  98      (0)   (4)   (0) 6 2.24     48 8.96 99  99 70  96 75  90      (0)   (27)   (16) 6 2.24 49 8.96    99      99 55  80         (0)   (31) 6 2.24 50 8.96    98  99 70  80     (1)   (12) 6 2.24 51 8.96    60  98 80  90         (38)   (11) 6 2.24 52     8.96    70  98 90  90         (28)   (0) 6 2.24 53 8.96    90  98 80  90             (8)   (11) 6 2.24 54 8.96    50  60 40  65         (16)   (38) 6     2.24 55 8.96    80  75 60  80         (0)   (25) 6 2.24 56 8.96    30     100 80  80         (70)   (0) 6 2.24 57 8.96    40  95 80  85     (57)   (5) 6 2.24 58 8.96    98  95 90  85         (0)   (0) 6 2.24 59     8.96    30  95 25  85         (68)   (70) 6 2.24 60 8.96    20  95 30     85         (78)   (64) 6 2.24 61 8.96    25  95 35  85         (73)     (58) 6 2.24 62 8.96    0  95 35  85         (100)   (58) 6 2.24 63 8.96       45  90 60  75         (50)   (20) 6 2.24 64 8.96    75  80 50  75        (6)   (33) 6 2.24 65 8.96    98  80 80  75         (0)   (0) 6 2.24     66 8.96    20  80 30  75         (75)   (60) 6 2.24 67 8.96    35  80 55      75         (56)   (26) 6 2.24 68 8.96    45  95 90  75         (52)     (0) 6 2.24 69 8.96    70  95 50  75         (26)   (33) 6 2.24 70 8.96      80  95 75  75         (15)   (0) 6 2.24 71 8.96    35  65 45  75      (46)   (40) 6 2.24 72 8.96    20  85 55  75         (76)   (26) 6 2.24     73 8.96    30  75 35  85         (60)   (58) 6 2.24 74 8.96    30  95 60      80         (68)   (25) 6 2.24 75 8.96    20  95 60  80         (78)     (25) 6 2.24 76 8.96    35  95 65  80         (63)   (18) 6 2.24 77 8.96       80  95 70  80         (15)   (12) 6 2.24 78 8.96    20  90 60  85        (77)   (29) 6 2.24 79 8.96    95  90 90  85         (0)   (0) 6 2.24     80 8.96    30  100 90  95         (70)   (5) 6 2.24 81 8.96    20  100     85  95         (80)   (10) 6 2.24 82 8.96    15  100 40  95         (85)       (57) 6 2.24 83 8.96    35  100 80  95         (65)   (15) 6 2.24 84     8.96    35  100 60  95         (65)   (36) 6 2.24 85 8.96    45  100 90     95         (55)   (5) 6 2.24 86 8.96    10  75 55  80         (86)     (31) 6 2.24 87 8.96    70  95 80  85         (26)   (5) 6 2.24 88 8.96      30  95 60  90         (68)   (33) 6 2.24 89 8.96    40  95 95  90       (57)   (0) 6 2.24 90 8.96    25  95 75  90         (73)   (16) 6 2.24     91 8.96    70  95 90  90         (26)   (0) 6 2.24 92 8.96    20  95 75     90         (78)   (16) 6 2.24 93 8.96    35  100 70  90         (65)     (22) 6 2.24 94 8.96    95  100 70  75         (5)   (6) 6 2.24 95 8.96      80  100 95  75         (20)   (0) 6 2.24 96 8.96    45  95 55  80       (52)   (31) 6 2.24 97 8.96    60  95 70  80         (36)   (12) 6 2.24     98 8.96    20  80 75  70         (75)   (0) 6 2.24 99 8.96    30  85 90     90         (64)   (0) 6 2.24 100 8.96    30  85 95  90         (64)     (0) 6 2.24 101 8.96    35  85 95  90         (58)   (0) 6 2.24 102 8.96       30  85 80  90         (64)   (11) 6 2.24 103 8.96    20  85 95  90         (76)   (0) 6 2.24 104 8.96    30  85 90  90         (64)   (0) 6     2.24 105 8.96    100  85 90  90         (0)   (0) 6 2.24 106 8.96    40     95 35  80         (57)   (56) 6 2.24 107 8.96    40  95 100  80     (57)   (0) 6 2.24 108 8.96    30  65 70  60         (53)   (0) 6 2.24     109 8.96    25  95 90  85         (73)   (0) 6 2.24 110 8.96    95  95     75  85         (0)   (11) 6 2.24 111 8.96    55  65 30  60         (15)      (50) 6 2.24 112 8.96    55  90 45  75         (38)   (40) 6 2.24 113     8.96    80  90 55  75         (11)   ( 26) 6 2.24 114 8.96    70  90 70     75         (22)   (6) 6 2.24 115 8.96    30  90 60  75         (66)     (20) 6 2.24 116 8.96    35  90 45  75         (61)   (40) 6 2.24 117     8.96    50  80 80  75         (37)   (0) 6 2.24 118 8.96    95  80 80     75         (0)   (0) 6 2.24 119 8.96    100  90 90  85         (0)   (0)     6 2.24 120 8.96    55  90 85  90         (38)   (5) 6 2.24 121 8.96     80  90 85  90         (11)   (5) 6 2.24 122 8.96    30  90 80  90      (66)   (11) 6 2.24 123 8.96    55  90 40  90         (38)   (55) 6 2.24     124 8.96    55  90 70  90         (38)   (22) 6 2.24 125 8.96    35  90     80  100         (61)   (20) 6 2.24 126 8.96    50  95 90  85     (47)   (0) 6 2.24 127 8.96    60  95 95  85         (36)   (0) 6 2.24     128 8.96    40  95 70  85         (57)   (17) 6 2.24 129 8.96    50  95     80  85         (47)   (5) 6 2.24 130 8.96    80  95 65  85         (15)      (23) 6 2.24 131 8.96    35  95 80  85         (63)   (5) 6 2.24 132     8.96    30  95 75  85         (68)   (11) 6 2.24 133 8.96    95  95 100     85         (0)   (0) 6 2.24 134 8.96    55  90 95  85         (38)   (0)     6 2.24 135 8.96    55  90 95  85         (38)   (0) 6 2.24 136 8.96     40  95 90  95         (57)   (5) 6 2.24 137 8.96    95  95 90  95      (0)   (5) 6 2.24 138 8.96    90  95 70  95         (5)   (26) 6 2.24     139 8.96    70  85 70  75         (17)   (6) 6 2.24 140 8.96    65  85     80  75         (23)   (0) 6 2.24 141 8.96    70  80 95  80         (12)      (0) 6 2.24 142 8.96    80  80 70  80         (0)   (12) 6 2.24 143 8.96        80  80 60  80         (0)   (25) 6 2.24 144 8.96    60  80 30  80         (25)   (62) 6 2.24 145 8.96    20  80 70  80         (75)   (12) 6     2.24 146 8.96    70  80 50  80         (12)   (37) 6 2.24 147 8.96    90      80 80  80         (0)   (0) 6 2.24 148 8.96    95  80 65  80     (0)   (18) 6 2.24 149 8.96    50  90 85  90         (44)   (5) 6 2.24     150 8.96    45  90 90  90         (50)   (0) 6 2.24 151 8.96    75  85     90  90         (11)   (0) 6 2.24 152 8.96    80  85 90  90         (5)     (0) 6 2.24 153 8.96    75  85 80  90         (11)   (11) 6 2.24 154 8.96        10  90 60  85         (88)   (29) 6 2.24 155 8.96    75  85 75  90          (11)   (16) 6 2.24 156 8.96    80  85 95  90         (5)   (0) 6     2.24 157 8.96    50  85 75  90         (41)   (16) 6 2.24 158 8.96    85      70 80  80         (0)   (0) 6 2.24 159 8.96    30  70 70  80     (57)   (12) 6 2.24 160 8.96    0  70 70  80        (57)   (12) 6 2.24     161 8.96    40  70 45  80        (42)   (43) 6 2.24 162 8.96    45  70     40  80        (35)   (50) 6 2.24 163 8.96    45  70 70  80        (35)     (12) 6 2.24 164 8.96    80  90 65  70        (11)   (7) 6 2.24 165 8.96       35  95 25  85        (63)   (70) 6 2.24 166 8.96    35  90 70  90       (61)   (22) 6 2.24 167 8.96    95  90 100  85        (0)   (0) 6 2.24     168 8.96    10  90 80  85        (88)   (5) 6 2.24 169 8.96    35  90 55      90        (61)   (38) 6 2.24 170 8.96    50  90 65  90        (44)     (27) 6 2.24 171 8.96    35  90 100  90        (61)   (0) 6 2.24 172 8.96        20  90 50  80        (77)   (37) 6 2.24 173 8.96    35  80 20  85        (56)   (76) 6 2.24 174 8.96    30  80 30  85        (62)   (64) 6     2.24 175 8.96    35  75 40  45        (53)   (11) 6 2.24 176 8.96    45     80 40  85        (43)   (52) 6 2.24 177 8.96    35  75 50  45     (53)   (0) 6 2.24 178 8.96    35  75 35  45        (53)   (22) 6 2.24     179 8.96    35  75 65  45        (53)   (0) 6 2.24 180 8.96    35  75 65      45        (53)   (0) 6 2.24 181 8.96    0  75 80  45        (100)   (0)     6 2.24 182 8.96    25  80 100  100        (68)   (0) 6 2.24 183 8.96     40  80 100  100        (50)   (0) 6 2.24 184 8.96    60  65 95  75      (7)   (0) 6 2.24 185 8.96    55  90 90  75        (38)   (0) 6 2.24 186     8.96    40  65 85  90        (38)   (5) 6 2.24 187 8.96    30  90 85  85            (66)   (0) 6 2.24 188 8.96    70  95 90  100        (26)   (10) 6     2.24 189 8.96    50  95 75  100        (47)   (25) 6 2.24 190 8.96    35      95 55  75        (63)   (26) 6 2.24 191 8.96    30  95 90  75     (68)   (0) 6 2.24 192 8.96    40  95 65  75        (57)   (13) 6 2.24     193 8.96    45  100 100  90        (55)   (0) 6 2.24 194 8.96    45  100     90  90        (55)   (0) 6 2.24 195 8.96    50  100 85  90        (50)     (5) 6 2.24 196 8.96    35  95 70  95        (63)   (26) 6 2.24 197 8.96       60  95 70  90        (36)   (22) 6 2.24 198 8.96    35  95 95  95       (63)   (0) 6 2.24 199 8.96    80  100 70  65        (20)   (0) 6 2.24     200 8.96    75  75 50  75        (0)   (33) 6 2.24 201 8.96    40  90 0     65        (55)   (100) 6 2.24 202 0.28    0  85 15  85        (100)     (82) 10 6.72 37 8.96 50  90 70  90 70  80      (44)   (22)   (12) 10     6.72 38 8.96 45  85 60  75 80  80      (47)   (20)   (0) 10 6.72 39 8.96     90  85 70  80 90  80      (0)   (12)   (0) 10 6.72 40 8.96 50  90 85  80     95  95      (44)   (0)   (0) 10 6.72 41 8.96 90  90 60  95 80  85     (0)   (36)   (5) 10 6.72 42 8.96 90  90 40  80 50  75      (0)   (50)     (33) 10 6.72 43 8.96 97  95 60  75 80  80      (0)   (20)   (0) 10 6.72     44 8.96 10  95 50  95 60  97      (89)   (47)   (38) 10 6.72 45 8.96 55     65      (15) 10 6.72 46 8.96 90  95 60  95 75  97      (5)   (36)   (22)     10 6.72 47 8.96 90  90 85  90 95  95      (0)   (5)   (0) 10 6.72 48     8.96 65  95 65  97 50  85      (31)   (32)   (41) 10 6.72 49 8.96 90  95          (5) 10 6.72 50 8.96 95  95      (0) 10 6.72 51 8.96 75  80      (6)     10 6.72 52 8.96 70  80      (12) 10 6.72 53 8.96 70  80      (12) 10     6.72 54 8.96 75  80      (6) 10 6.72 55 8.96 20  80      (75) 10 6.72 56     8.96 50  98      (48) 10 4.48 57 8.96 65  95      (31) 10 4.48 58 8.96     98  95      (0) 10 4.48 59 8.96 65  95      (31) 10 4.48 60 8.96 70  95         (26) 10 4.48 61 8.96 55  95      (42) 10 4.48 62 8.96 60  95     (36) 10 4.48 63 8.96 45  90      (50) 10 4.48 64 8.96 60  90      (33)     10 4.48 65 8.96 90  90      (0) 10 4.48 66 8.96 50  90      (44) 10 4.48     67 8.96 45  90      (50) 10 4.48 68 8.96 100  90      (0) 10 4.48 69     8.96 50  90      (44) 10 4.48 70 8.96 60  90      (33) 10 4.48 71 8.96     55  75      (26) 10 4.48 72 8.96 80  90      (11) 10 4.48 73 8.96 55  80          (31) 10 4.48 74 8.96 60  80      (25) 10 4.48 75 8.96 40  80     (50) 10 4.48 76 8.96 75  80      (6) 10 4.48 77 8.96 60  80      (25) 10     4.48 78 8.96 95  90      (0) 10 4.48 79 8.96 95  90      (0) 10 4.48 80     8.96 35  95      (63) 10 4.48 81 8.96 80  95      (15) 10 4.48 82 8.96     70  95      (26) 10 4.48 83 8.96 80  95      (15) 10 4.48 84 8.96 95  95          (0) 10 4.48 85 8.96 85  95      (10) 10 4.48 96985 8.96 80  90     (11) 10 4.48 96994 8.96 95  95      (0) 10 4.48 96997 8.96 90  90     (0) 10 4.48 89 8.96 85  90      (5) 10 4.48 90 8.96 85  85      (0) 10     4.48 91 8.96 85  85      (0) 10 4.48 92 8.96 90  85      (0) 10 4.48 93     8.96 45  90      (50) 10 4.48 94 8.96 95  85      (0) 10 4.48 95 8.96 90      85      (0) 10 4.48 96 8.96 80  90      (11) 10 4.48 97 8.96 90  90      (0) 10 4.48 98 8.96 90  80      (0) 10 4.48 99 8.96 90  95      (5) 10     4.48 100 8.96 50  95      (47) 10 4.48 101 8.96 75  95      (21) 10 4.48     102 8.96 80  95      (15) 10 4.48 103 8.96 75  95      (21) 10 4.48 104     8.96 60  95      (36) 10 4.48 105 8.96 100  95      (0) 10 4.48 106 8.96     50  80      (37) 10 4.48 107 8.96 75  80      (6) 10 4.48 108 8.96 70     80      (12) 10 4.48 109 8.96 100  90      (0) 10 4.48 110 8.96 85  90        (5) 10 4.48 111 8.96 65  80      (18) 10 4.48 112 8.96 85  90     (5) 10 4.48 113 8.96 60  90      (33) 10 4.48 114 8.96 60  90      (33)     10 4.48 115 8.96 70  90      (22) 10 4.48 116 8.96 85  90      (5) 10     4.48 117 8.96 90  80      (0) 10 4.48 118 8.96 95  80      (0) 10 4.48     119 8.96 90  80      (0) 10 4.48 120 8.96 80  95      (15) 10 4.48 121     8.96 80  95      (15) 10 4.48 122 8.96 85  95      (10) 10 4.48 123 8.96     90  95      (5) 10 4.48 124 8.96 90  95      (5) 10 4.48 125 8.96 85  95          (10) 10 4.48 126 8.96 75  90      (16) 10 4.48 127 8.96 90  90     (0) 10 4.48 128 8.96 85  90      (5) 10 4.48 129 8.96 85  90      (5) 10     4.48 130 8.96 90  90      (0) 10 4.48 131 8.96 80  90      (11) 10 4.48     132 8.96 65  90      (27) 10 4.48 133 8.96 90  90      (0) 10 4.48 134     8.96 60  90      (33) 10 4.48 135 8.96 90  90      (0) 10 4.48 136 8.96     90  90      (0) 10 4.48 137 8.96 55  90      (38) 10 4.48 138 8.96 80     90      (11) 10 4.48 139 8.96 90  80      (0) 10 4.48 140 8.96 90  80       (0) 10 4.48 141 8.96 90  85      (0) 10 4.48 142 8.96 45  85      (47)     10 4.48 143 8.96 65  85      (23) 10 4.48 144 8.96 85  90      (5) 10     4.48 145 8.96 60  90      (33) 10 4.48 146 8.96 80  90      (11) 10 4.48     147 8.96 95  90      (0) 10 4.48 148 8.96 95  90      (0) 10 4.48 149     8.96 65  90      (27) 10 4.48 150 8.96 90  85      (0) 10 4.48 151 8.96     65  95      (31) 10 4.48 152 8.96 95  95      (0) 10 4.48 153 8.96 90     95      (5) 10 4.48 154 8.96 70  90      (22) 10 4.48 155 8.96 75  95       (21) 10 4.48 156 8.96 80  95      (15) 10 4.48 157 8.96 90  95     (5) 10 4.48 158 8.96 100  90      (0) 10 4.48 159 8.96 80  90      (11)     10 4.48 160 8.96 80  90      (11) 10 4.48 161 8.96 80  90      (11) 10     4.48 162 8.96 95  90      (0) 10 4.48 163 8.96 90  90      (0) 10 4.48     164 8.96 95  85      (0) 10 4.48 165 8.96 90  90      (0) 10 4.48 166     8.96 75  90      (16) 10 4.48 167 8.96 95  90      (0) 10 4.48 168 8.96     90  90      (0) 10 4.48 169 8.96 90  90      (0) 10 4.48 170 8.96 70  90          (22) 10 4.48 171 8.96 85  90      (5) 10 4.48 172 8.96 90  90     (0) 10 4.48 173 8.96 90  80      (0) 10 4.48 174 8.96 75  80      (6) 10     4.48 175 8.96 75  90      (16) 10 4.48 176 8.96 90  80      (0) 10 4.48     177 8.96 75  90      (16) 10 4.48 178 8.96 65  90      (27) 10 4.48 179     8.96 80  90      (11) 10 4.48 180 8.96 80  90      (11) 10 4.48 181 8.96     85  90      (5) 10 4.48 182 8.96 80  90      (11) 10 4.48 183 8.96 75     90      (16) 10 4.48 184 8.96 90  90      (0) 10 4.48 185 8.96 45  80       (43) 10 4.48 186 8.96 90  75      (0) 10 4.48 187 8.96 75  95     (21) 10 4.48 188 8.96 75  95      (21) 10 4.48 189 8.96 80  95      (15)     10 4.48 190 8.96 90  95      (5) 10 4.48 191 8.96 95  95      (0) 10     4.48 192 8.96 80  95      (15) 10 4.48 193 8.96 80  95      (15) 10 4.48     194 8.96 90  95      (5) 10 4.48 195 8.96 80  95      (15) 10 4.48 196     8.96 70  100      (30) 10 4.48 197 8.96 80  100      (20) 10 4.48 198     8.96 90  100      (10) 10 4.48 199 8.96 95  70      (0) 10 4.48 200 8.96     90  90      (0) 10 4.48 201 8.96 75  80      (6) 10 4.48 202 0.28 0  90         (100) 15 1.12 45 8.96          60  75               (20) 15 1.12 49     8.96          80  85               (5) 15 1.12 50 8.96          85  85                 (0) 15 1.12 51 8.96          75  70               (0) 15     1.12 52 8.96          80  70               (0) 15 1.12 53 8.96     50  70               (28) 15 1.12 54 8.96          85  85     (0) 15 1.12 55 8.96          30  90               (66) 15 1.12 56 8.96            30  90               (66) 15 1.12 57 8.96          80  90           (11) 15 1.12 58 8.96          95  90               (0) 15 1.12 59     8.96          20  90               (77) 15 1.12 60 8.96          65  90                  (27) 15 1.12 61 8.96          75  90               (16) 15     1.12 62 8.96          30  90               (66) 15 2.24 63 8.96     30  90               (66) 15 2.24 64 8.96          95  90     (0) 15 2.24 65 8.96          95  90               (0) 15 2.24 66 8.96           50  90               (44) 15 2.24 67 8.96          50  90          (44) 15 2.24 68 8.96          40  85               (52) 15 2.24 69     8.96          45  85               (47) 15 2.24 70 8.96          35  85                  (58) 15 2.24 71 8.96          25  75               (66) 15     2.24 72 8.96          65  75               (13) 15 2.24 73 8.96     35  75               (53) 15 2.24 74 8.96          80  80     (0) 15 2.24 75 8.96          75  80               (6) 15 2.24 76 8.96           25  80               (68) 15 2.24 77 8.96          70  80          (12) 15 2.24 78 8.96          65  90               (27) 15 2.24 79     8.96          90  90               (0) 15 2.24 80 8.96          40  90                 (55) 15 2.24 81 8.96          20  90               (77) 15     2.24 82 8.96          75  90               (16) 15 2.24 83 8.96     10  90               (88) 15 2.24 84 8.96          45  90     (50) 15 2.24 85 8.96          40  90               (55) 15 2.24 86 8.96             90  90               (0) 15 2.24 87 8.96          80  85           (5) 15 2.24 88 8.96          65  90               (27) 15 2.24 89     8.96          70  90               (22) 15 2.24 90 8.96          60  90                  (33) 15 2.24 91 8.96          95  90               (0) 15     2.24 92 8.96          90  90               (0) 15 2.24 93 8.96     45  90               (50) 15 2.24 94 8.96          80  90     (11) 15 2.24 95 8.96          45  90               (50) 15 2.24 96 8.96             60  75               (20) 15 2.24 97 8.96          90  75            (0) 15 2.24 98 8.96          70  80               (12) 15 2.24 99     8.96          20  90               (77) 15 2.24 100 8.96          50  90                   (44) 15 2.24 101 8.96          45  90               (50)     15 2.24 102 8.96          85  90               (5) 15 2.24 103 8.96         15  90               (83) 15 2.24 104 8.96          50  90         (44) 15 2.24 105 8.96          90  90               (0) 15 2.24 106     8.96          80  90               (11) 15 2.24 107 8.96          85  90                   (5) 15 2.24 108 8.96          50  80               (37) 15     2.24 109 8.96          65  95               (31) 15 2.24 110 8.96       85  95               (10) 15 2.24 111 8.96          70  80       (12) 15 2.24 112 8.96          35  90               (61) 15 2.24 113     8.96          65  90               (27) 15 2.24 114 8.96          50  90                   (44) 15 2.24 115 8.96          50  90               (44)     15 2.24 116 8.96          85  90               (5) 15 2.24 117 8.96         90  90               (0) 15 2.24 118 8.96          90  90        (0) 15 2.24 119 8.96          70  90               (22) 15 2.24 120     8.96          60  95               (36) 15 2.24 121 8.96          90  95                   (5) 15 2.24 122 8.96          90  95               (5) 15     2.24 123 8.96          55  95               (42) 15 2.24 124 8.96       85  95               (10) 15 2.24 125 8.96          40  90       (55) 15 2.24 126 8.96          45  90               (50) 15 2.24 127     8.96          75  90               (16) 15 2.24 128 8.96          65  90                   (27) 15 2.24 129 8.96          30  90               (66)     15 2.24 130 8.96          85  90               (5) 15 2.24 131 8.96         80  90               (11) 15 2.24 132 8.96          40  90         (55) 15 2.24 133 8.96          95  90               (0) 15 2.24 134     8.96          70  90               (22) 15 2.24 135 8.96          90  90                   (0) 15 2.24 136 8.96          65  90               (27) 15     2.24 137 8.96          90  90               (0) 15 2.24 138 8.96      80  90               (11) 15 2.24 139 8.96          90  80      (0) 15 2.24 140 8.96          80  80               (0) 15 2.24 141 8.96              80  80               (0) 15 2.24 142 8.96          60  80             (25) 15 2.24 143 8.96          25  80               (68) 15 2.24     144 8.96          50  90               (44) 15 2.24 145 8.96          70      90               (22) 15 2.24 146 8.96          30  90     (66) 15 2.24 147 8.96          80  90               (11) 15 2.24 148     8.96          95  90               (0) 15 2.24 149 8.96          65  95                  (31) 15 2.24 150 8.96          45  90               (50) 15     2.24 151 8.96          30  90               (66) 15 2.24 152 8.96       80  90               (11) 15 2.24 153 8.96          75  90       (16) 15 2.24 154 8.96          60  95               (36) 15 2.24 155     8.96          40  90               (55) 15 2.24 156 8.96          80  90                   (11) 15 2.24 157 8.96          75  90               (16)     15 2.24 158 8.96          90  90               (0) 15 2.24 159 8.96         50  90               (44) 15 2.24 160 8.96          30  90         (66) 15 2.24 161 8.96          65  90               (27) 15 2.24 162     8.96          75  90               (16) 15 2.24 163 8.96          65  90                   (27) 15 2.24 164 8.96          80  90               (11)     15 2.24 165 8.96          50  90               (44) 15 2.24 166 8.96          65  85               (23) 15 2.24 167 8.96          90  95          (5) 15 2.24 168 8.96          75  95               (21) 15 2.24 169     8.96          45  85               (47) 15 2.24 170 8.96          60  85                   (29) 15 2.24 171 8.96          95  85               (0) 15     2.24 172 8.96          35  80               (56) 15 2.24 173 8.96       45  80               (43) 15 2.24 174 8.96          20  80       (75) 15 2.24 175 8.96          25  80               (68) 15 2.24 176     8.96          40  80               (50) 15 2.24 177 8.96          45  80                   (43) 15 2.24 178 8.96          35  80               (56)     15 2.24 179 8.96          45  80               (43) 15 2.24 180 8.96          25  80               (68) 15 2.24 181 8.96          65  80          (18) 15 2.24 182 8.96          35  80               ( 56) 15 2.24     183 8.96          50  80               (37) 15 2.24 184 8.96          60      85               (29) 15 2.24 185 8.96          65  85     (23) 15 2.24 186 8.96          60  95               (36) 15 2.24 187     8.96          50  95               (47) 15 2.24 188 8.96          75     100               (25) 15 2.24 189 8.96          60  100     (40) 15 2.24 190 8.96          80  95               (15) 15 2.24 191     8.96          70  95               (26) 15 2.24 192 8.96          60  95                   (36) 15 2.24 193 8.96          70  95               (26)     15 2.24 194 8.96          50  95               (47) 15 2.24 195 8.96          45  95               (52) 15 2.24 197 8.96          50  100           (50) 15 2.24 198 8.96          0  95               (100) 15 2.24     199 8.96          90  95               (5) 15 2.24 200 8.96          50     95               (47) 15 2.24 201 8.96          80  90     (11) 15 2.24 202 0.28          30  95               (68)

EXAMPLE 286

The following procedure shows interaction between a herbicide andantidote when the antidote is applied in a soil furrow containing cropseed and the herbicide is incorporated in a soil cover layer. Containerswere filled and compacted with fumigated silt loam soil to a depth ofabout 1.3 cm from the top of the container. A first container wasdesignated as an untreated control, a second container was designated asa herbicide control, and a third container was designated as aherbicide + antidote test container. Each container was seeded with cropseed in marked furrows. Antidote compound, dissolved in acetone, wasapplied directly to the seeded furrows of the third container. Antidoteapplication rate was 0.55 mg active compound per inch of furrow (0.22mg/cm). This rate was comparable to a plot application rate of 0.28kilogram per hectare (kg/ha), based on 76 cm (30") spaced-apart furrows.Then, each of the second and third containers was filled and leveledwith a cover layer of soil having incorporated therein the selectedherbicide at a pre-determined concentration. The first container wasfilled and leveled with soil containing no herbicide. The containerswere then placed on a bench in a greenhouse and sub-irrigated asrequired for the duration of the test. Plant response was observed aboutthree weeks after initial treatment. Results are reported in Table III.

                                      TABLE III                                   __________________________________________________________________________    % PLANT INHIBITION AND % SAFENING EFFECT ( )                                                  SORGHUM                                                       HERBICIDE                                                                             ANTIDOTE                                                                              GRAIN    WHEAT     RICE     SOYBEAN   CORN                    NO. RATE                                                                              NO. RATE                                                                              W     WO W      WO W     WO W      WO W     WO                __________________________________________________________________________    2   0.56                                                                               1  0.28         70     95                                                                         (26)                                             2   0.56                                                                               24 0.28         90     100                                                                        (10)                                             2   0.56                                                                               25 0.28         95     95                                                                         (0)                                              2   0.56                                                                               26 0.28         95     95                                                                         (0)                                              2   0.56                                                                               27 0.28         85     95                                                                         (10)                                             2   0.56                                                                               28 0.28         90     95                                                                         (5)                                              2   0.56                                                                               29 0.28         95     95                                                                         (0)                                              2   0.56                                                                               30 0.28         100    100                                                                        (0)                                              2   0.56                                                                               31 0.28         95     100                                                                        (5)                                              2   0.56                                                                               32 0.28         85     95                                                                         (10)                                             2   0.56                                                                               33 0.28         80     95                                                                         (15)                                             2   0.56                                                                               34 0.28         90     100                                                                        (10)                                             2   0.56                                                                               35 0.28         85     95                                                                         (10)                                             2   0.56                                                                               36 0.28         85     100                                                                        (15)                                             3   6.72                                                                               1  0.28                   95    100                                                                              100    95                                                               (5)       (0)                           3   6.72                                                                               24 0.28                   100   100                                                                              100    100                                                              (0)       (0)                           3   6.72                                                                               25 0.28                   100   100                                                                              100    100                                                              (0)       (0)                           3   4.48                                                                               26 0.28                   90    90 70     75                                                               (0)       (6)                           3   4.48                                                                               27 0.28                   100   95                                                                         (0)                                     3   4.48                                                                               27 0.28                            85     95                                                                         (10)                          3   4.48                                                                               28 0.28                   60    65 95     90                                                               (7)       (0)                           3   4.48                                                                                29                                                                              0.28                   90    80 95     95                                                               (0)       (0)                           3   6.72                                                                               30 0.28                   60    70 40     85                                                               (14)      (52)                          3   6.72                                                                               31 0.28                   70    85 70     90                                                               (17)      (22)                          3   6.72                                                                               32 0.28                            40     85                                                                         (52)                          3   6.72                                                                               33 0.28                            85     85                                                                         (0)                           3   6.72                                                                               34 0.28                            85     85                                                                         (0)                           3   6.72                                                                               35 0.28                            60     80                                                                         (25)                          3   4.48                                                                               36 0.28                            40     90                                                                         (55)                          6   2.24                                                                               1  0.28                                                                              20    95 20     80                                                               (78)      (75)                                             6   2.24                                                                               24 0.28                                                                              45    95 90     95                                                               (52)      (5)                                              6   2.24                                                                               25 0.28                                                                              0     95 45     85                                                               (100)     (47)                                             6   2.24                                                                               26 0.28                                                                              65    95 70     75                                                               (31)      (6)                                              6   2.24                                                                               27 0.28                                                                              10    100                                                                              40     70                                                               (90)      (42)                                             6   2.24                                                                               28 0.28                                                                              100   100                                                                              85     95                                                               (0)       (10)                                             6   2.24                                                                               29 0.28                                                                              40    100                                                                              80     100                                                              (60)      (20)                                             6   2.24                                                                               30 0.28                                                                              95    100                                                                              30     70                                                               (5)       (57)                                             6   2.24                                                                               31 0.28                                                                              100   100                                                                              60     80                                                               (0)       (25)                                             6   2.24                                                                               32 0.28                                                                              30    100                                                                              95     100                                                              (70)      (5)                                              6   2.24                                                                               33 0.28                                                                              10    95 20     75                                                               (89)      (73)                                             6   2.24                                                                               34 0.28                                                                              50    100                                                                              70     95                                                               (50)      (26)                                             6   2.24                                                                               35 0.28                                                                              15    95 35     75                                                               (84)      (53)                                             6   2.24                                                                               36 0.28                                                                              70    100                                                                              90     100                                                              (30)      (10)                                             10  4.48                                                                               1  0.28                   0     95                                                                         (100)                                   10  4.48                                                                               24 0.28                   50    95                                                                         (47)                                    10  4.48                                                                               25 0.28                   40    100                                                                        (60)                                    10  4.48                                                                               26 0.28                   5     95                                                                         (94)                                    10  4.48                                                                               27 0.28                   10    85                                                                         (88)                                    10  4.48                                                                               28 0.28                   35    100                                                                        (65)                                    10  4.48                                                                               29 0.28                   35    95                                                                         (63)                                    10  4.48                                                                               30 0.28                   40    95                                                                         (57)                                    10  4.48                                                                               31 0.28                   70    90                                                                         (22)                                    10  4.48                                                                               32 0.28                   40    80                                                                         (50)                                    10  4.48                                                                               33 0.28                   20    60                                                                         (66)                                    10  4.48                                                                               34 0.28                   10    90                                                                         (88)                                    10  4.48                                                                               35 0.28                   25    95                                                                         (73)                                    10  4.48                                                                               36 0.28                   55    95                                                                         (42)                                    15  2.24                                                                               1  0.28                            80     55 20    95                                                                (0)      (78)                 15  2.24                                                                               24 0.28                                      85    100                                                                        (15)                 15  2.24                                                                               25 0.28                                      80    95                                                                         (15)                 15  2.24                                                                               26 0.28                            40     45 70    95                                                                (11)     (26)                 15  2.24                                                                               27 0.28                            70     40 30    95                                                                (0)      (68)                 15  2.24                                                                               28 0.28                            55     50 95    95                                                                (0)      (0)                  15  2.24                                                                               29 0.28                            30     70 10    95                                                                (57)     (89)                 15  2.24                                                                               30 0.28                            90     85 95    95                                                                (0)      (0)                  15  2.24                                                                               31 0.28                            70     65 95    95                                                                (0)      (0)                  15  2.24                                                                               32 0.28                            20     75 20    95                                                                (73)     (78)                 15  2.24                                                                               33 0.28                            90     80 50    95                                                                (0)      (47)                 15  2.24                                                                               34 0.28                            30     70 10    90                                                                (57)     (88)                 15  2.24                                                                               35 0.28                            20     55 5     100                                                               (63)     (95)                 15  2.24                                                                               36 0.28                            40     85 30    95                                                                (52)     (68)                 2   0.56                                                                              203 0.28         95     95                                                                         (0)                                              2   0.56                                                                              204 0.28         95     100                                                                        (5)                                              2   0.56                                                                              205 0.28         90     100                                                                        (10)                                             2   0.56                                                                              206 0.28         80     95                                                                         (15)                                             2   0.56                                                                              207 0.28         95     95                                                                         (0)                                              2   0.56                                                                              208 0.28         85     95                                                                         (10)                                             2   0.56                                                                              209 0.28         90     95                                                                         (5)                                              2   0.56                                                                              210 0.28         45     100                                                                        (55)                                             2   0.56                                                                              211 0.28         10     100                                                                        (90)                                             2   0.56                                                                              212 0.28         75     95                                                                         (21)                                             2   0.56                                                                              213 0.28         60     95                                                                         (36)                                             2   0.56                                                                              214 0.28         95     100                                                                        (5)                                              2   0.56                                                                              215 0.28         100    100                                                                        (0)                                              2   0.56                                                                              216 0.28         95     100                                                                        (5)                                              2   0.56                                                                              217 0.28         95     100                                                                        (5)                                              2   0.56                                                                              218 0.28         95     100                                                                        (5)                                              2   0.56                                                                              219 0.28         95     100                                                                        (5)                                              2   0.56                                                                              220 0.28         100    95                                                                         (0)                                              2   0.56                                                                              221 0.28         80     100                                                                        (20)                                             2   0.56                                                                              222 0.28         100    100                                                                        (0)                                              2   0.56                                                                              223 0.28         95     95                                                                         (0)                                              2   0.56                                                                              224 0.28         95     95                                                                         (0)                                              2   0.56                                                                              225 0.28         95     100                                                                        (5)                                              2   0.56                                                                              226 0.28         95     100                                                                        (5)                                              2   0.56                                                                              227 0.28         95     100                                                                        (5)                                              2   0.56                                                                              228 0.28         95     100                                                                        (5)                                              2   0.56                                                                              229 0.28         85     100                                                                        (15)                                             2   0.56                                                                              230 0.28         80     95                                                                         (15)                                             2   0.56                                                                              231 0.28         90     95                                                                         (5)                                              2   0.56                                                                              232 0.28         95     95                                                                         (0)                                              2   0.56                                                                              233 0.28         80     90                                                                         (11)                                             2   0.56                                                                              234 0.28         90     90                                                                         (0)                                              2   0.56                                                                              235 0.28         100    100                                                                        (0)                                              2   0.56                                                                              236 0.28         95     100                                                                        (5)                                              2   0.56                                                                              237 0.28         75     100                                                                        (25)                                             2   0.56                                                                              238 0.28         95     100                                                                        (5)                                              2   0.56                                                                              239 0.28         100    95                                                                         (0)                                              2   0.56                                                                              240 0.28         90     95                                                                         (5)                                              2   0.56                                                                              241 0.28         100    95                                                                         (0)                                              2   0.56                                                                              242 0.28         100    95                                                                         (0)                                              2   0.56                                                                              243 0.28         90     95                                                                         (5)                                              2   0.56                                                                              244 0.28         95     95                                                                         (0)                                              2   0.56                                                                              245 0.28         95     100                                                                        (5)                                              2   0.56                                                                              246 0.28         85     100                                                                        (15)                                             2   0.56                                                                              247 0.28         85     100                                                                        (15)                                             2   0.56                                                                              248 0.28         100    95                                                                         (0)                                              2   0.56                                                                              249 0.28         85     95                                                                         (10)                                             2   0.56                                                                              250 0.28         100    95                                                                         (0)                                              2   0.56                                                                              251 0.28         75     95                                                                         (21)                                             2   0.56                                                                              252 0.28         70     100                                                                        (30)                                             2   0.56                                                                              253 0.28         65     100                                                                        (35)                                             2   0.56                                                                              254 0.28         95     95                                                                         (0)                                              2   0.56                                                                              255 0.28         70     95                                                                         (26)                                             2   0.56                                                                              256 0.28         75     95                                                                         (21)                                             2   0.56                                                                              257 0.28         90     95                                                                         (5)                                              2   0.56                                                                              258 0.28         90     100                                                                        (10)                                             2   0.56                                                                              259 0.28         90     95                                                                         (5)                                              2   0.56                                                                              260 0.28         85     90                                                                         (5)                                              2   0.56                                                                              261 0.28         85     95                                                                         (10)                                             2   0.56                                                                              262 0.28         80     95                                                                         (15)                                             2   0.56                                                                              263 0.28         85     100                                                                        (15)                                             2   0.56                                                                              264 0.28         75     100                                                                        (25)                                             2   0.56                                                                              265 0.28         80     100                                                                        (20)                                             2   0.56                                                                              266 0.28         80     100                                                                        (20)                                             2   0.56                                                                              267 0.28         80     100                                                                        (20)                                             2   0.56                                                                              268 0.28         80     100                                                                        (20)                                             2   0.56                                                                              269 0.28         60     100                                                                        (40)                                             2   0.56                                                                              270 0.28         75     95                                                                         (21)                                             2   0.56                                                                              271 0.28         65     95                                                                         (31)                                             2   0.56                                                                              272 0.28         75     95                                                                         (21)                                             2   0.56                                                                              273 0.28         35     95                                                                         (63)                                             2   0.56                                                                              274 0.28         90     95                                                                         (5)                                              2   0.56                                                                              275 0.28         60     95                                                                         (36)                                             2   0.56                                                                              276 0.28         70     95                                                                         (26)                                             2   0.56                                                                              277 0.28         90     95                                                                         (5)                                              2   0.56                                                                              278 0.28         75     95                                                                         (21)                                             2   0.56                                                                              279 0.28         70     95                                                                         (26)                                             2   0.56                                                                              280 0.28         100    95                                                                         (0)                                              2   0.56                                                                              281 0.28         70     95                                                                         (26)                                             2   0.56                                                                              282 0.28         80     100                                                                        (20)                                             2   0.56                                                                              283 0.28         80     100                                                                        (20)                                             3   6.72                                                                              203 0.28                   90    85 95     90                                                               (0)       (0)                           3   6.72                                                                              204 0.28                   65    95 70     95                                                               (31)      (26)                          3   4.48                                                                              205 0.28                   100   100                                                                              60     95                                                               (0)       (36)                          3   4.48                                                                              206 0.28                   70    65 90     90                                                               (0)       (0)                           3   4.48                                                                              207 0.28                   70    80 75     90                                                               (12)      (16)                          3   4.48                                                                              208 0.28                   95    95 95     90                                                               (0)       (0)                           3   4.48                                                                              209 0.28                   65    60 70     95                                                               (0)       (26)                          3   4.48                                                                              210 0.28                   70    75 95     95                                                               (6)       (0)                           3   4.48                                                                              211 0.28                   95    80 100    95                                                               (0)       (0)                           3   6.72                                                                              212 0.28                   40    75 100    80                                                               (46)      (0)                           3   6.72                                                                              213 0.28                   40    70 40     90                                                               (42)      (55)                          3   6.72                                                                              214 0.28                   45    85 45     80                                                               (47)      (43)                          3   6.72                                                                              215 0.28                   45    85 70     80                                                               (47)      (12)                          3   6.72                                                                              216 0.28                   60    85 50     80                                                               (29)      (37)                          3   6.72                                                                              217 0.28                   80    70 50     85                                                               (0)       (41)                          3   6.72                                                                              218 0.28                   50    70 55     85                                                               (28)      (35)                          3   6.72                                                                              219 0.28                   40    70 15     85                                                               (42)      (82)                          3   6.72                                                                              220 0.28                   70    90 75     95                                                               (22)      (21)                          3   6.72                                                                              221 0.28                            90     85                                                                         (0)                           3   6.72                                                                              222 0.28                            95     85                                                                         (0)                           3   6.72                                                                              223 0.28                            95     100                                                                        (5)                           3   6.72                                                                              224 0.28                            60     100                                                                        (40)                          3   6.72                                                                              225 0.28                            85     85                                                                         (0)                           3   6.72                                                                              226 0.28                            100    85                                                                         (0)                           3   6.72                                                                              227 0.28                            30     85                                                                         (64)                          3   6.72                                                                              228 0.28                            95     85                                                                         (0)                           3   6.72                                                                              229 0.28                            75     85                                                                         (11)                          3   6.72                                                                              230 0.28                            45     50                                                                         (10)                          3   6.72                                                                              231 0.28                            85     80                                                                         (0)                           3   6.72                                                                              232 0.28                            85     80                                                                         (0)                           3   6.72                                                                              233 0.28                            10     60                                                                         (83)                          3   6.72                                                                              234 0.28                            50     60                                                                         (16)                          3   6.72                                                                              235 0.28                            80     80                                                                         (0)                           3   6.72                                                                              236 0.28                            75     80                                                                         (6)                           3   6.72                                                                              237 0.28                            75     85                                                                         (11)                          3   6.72                                                                              238 0.28                            85     85                                                                         (0)                           3   6.72                                                                              239 0.28                            90     80                                                                         (0)                           3   6.72                                                                              240 0.28                            75     80                                                                         (6)                           3   6.72                                                                              241 0.28                            70     75                                                                         (7)                           3   6.72                                                                              242 0.28                            20     75                                                                         (73)                          3   6.72                                                                              243 0.28                            95     95                                                                         (0)                           3   6.72                                                                              244 0.28                            100    95                                                                         (0)                           3   6.72                                                                              245 0.28                            70     100                                                                        (30)                          3   6.72                                                                              246 0.28                            75     100                                                                        (25)                          3   6.72                                                                              247 0.28                            100    100                                                                        (0)                           3   6.72                                                                              248 0.28                            100    100                                                                        (0)                           3   4.48                                                                              249 0.28                            20     95                                                                         (78)                          3   4.48                                                                              250 0.28                            100    100                                                                        (0)                           3   4.48                                                                              251 0.28                            100    100                                                                        (0)                           3   4.48                                                                              252 0.28                            100    100                                                                        (0)                           3   4.48                                                                              253 0.28                            100    100                                                                        (0)                           3   4.48                                                                              254 0.28                            75     90                                                                         (16)                          3   4.48                                                                              255 0.28                            100    95                                                                         (0)                           3   4.48                                                                              256 0.28                            95     95                                                                         (0)                           3   4.48                                                                              257 0.28                            95     95                                                                         (0)                           3   4.48                                                                              258 0.28                            100    100                                                                        (0)                           3   4.48                                                                              259 0.28                            95     100                                                                        (5)                           3   4.48                                                                              260 0.28                            95     85                                                                         (0)                           3   4.48                                                                              261 0.28                            20     75                                                                         (73)                          3   4.48                                                                              262 0.28                            70     75                                                                         (6)                           3   4.48                                                                              263 0.28                            70     90                                                                         (22)                          3   4.48                                                                              264 0.28                            15     90                                                                         (83)                          3   4.48                                                                              265 0.28                            25     90                                                                         (72)                          3   4.48                                                                              266 0.28                            30     90                                                                         (66)                          6   2.24                                                                              203 0.28                                                                              30    90 50     85                                                               (66)      (41)                                             6   2.24                                                                              204 0.28                                                                              10    90                                                                         (88)                                                       6   2.24                                                                              204 0.28         30     90                                                                         (66)                                             6   2.24                                                                              205 0.28                                                                              20    85 10     70                                                               (76)      (85)                                             6   2.24                                                                              206 0.28                                                                              10    100                                                                              65     95                                                               (90)      (31)                                             6   2.24                                                                              207 0.28                                                                              100   100                                                                              40     70                                                               (0)       (42)                                             6   2.24                                                                              208 0.28                                                                              95    100                                                                              75     80                                                               (5)       (6)                                              6   2.24                                                                              209 0.28                                                                              0     100                                                                              35     90                                                               (100)     (61)                                             6   2.24                                                                              210 0.28                                                                              85    100                                                                              95     95                                                               (15)      (0)                                              6   2.24                                                                              211 0.28                                                                              100   100                                                                              90     100                                                              (0)       (10)                                             6   2.24                                                                              212 0.28                                                                              65    95 70     95                                                               (31)      (26)                                             6   2.24                                                                              213 0.28                                                                              50    95 95     90                                                               (47)      (0)                                              6   2.24                                                                              214 0.28                                                                              90    100                                                                              50     95                                                               (10)      (47)                                             6   2.24                                                                              215 0.28                                                                              95    100                                                                              70     95                                                               (5)       (26)                                             6   2.24                                                                              216 0.28                                                                              90    100                                                                              70     95                                                               (10)      (26)                                             6   2.24                                                                              217 0.28                                                                              80    100                                                                              60     70                                                               (20)      (14)                                             6   2.24                                                                              218 0.28                                                                              100   100                                                                              60     70                                                               (0)       (14)                                             6   2.24                                                                              219 0.28                                                                              100   100                                                                              50     70                                                               (0)       (28)                                             6   2.24                                                                              220 0.28                                                                              95    100                                                                              50     90                                                               (5)       (44)                                             6   2.24                                                                              221 0.28                                                                              10    100                                                                              50     90                                                               (90)      (44)                                             6   2.24                                                                              222 0.28                                                                              40    100                                                                              65     90                                                               (60)      (27)                                             6   2.24                                                                              223 0.28                                                                              10    100                                                                              40     90                                                               (90)      (55)                                             6   2.24                                                                              224 0.28                                                                              20    100                                                                              30     90                                                               (80)      (66)                                             6   2.24                                                                              225 0.28                                                                              95    100                                                                              85     95                                                               (5)       (10)                                             6   2.24                                                                              226 0.28                                                                              60    100                                                                              80     95                                                               (40)      (15)                                             6   2.24                                                                              227 0.28                                                                              50    100                                                                              80     95                                                               (50)      (15)                                             6   2.24                                                                              228 0.28                                                                              35    100                                                                              70     95                                                               (65)      (26)                                             6   2.24                                                                              229 0.28                                                                              50    100                                                                              60     95                                                               (50)      (36)                                             6   2.24                                                                              230 0.28                                                                              5     100                                                                              0      80                                                               (95)      (100)                                            6   2.24                                                                              231 0.28                                                                              30    95 10     70                                                               (68)      (85)                                             6   2.24                                                                              232 0.28                                                                              20    95 30     70                                                               (78)      (57)                                             6   2.24                                                                              233 0.28                                                                              60    95 75     85                                                               (36)      (11)                                             6   2.24                                                                              234 0.28                                                                              95    95 45     85                                                               (0)       (47)                                             6   2.24                                                                              235 0.28                                                                              65    95 95     85                                                               (31)      (0)                                              6   2.24                                                                              236 0.28                                                                              60    95 45     85                                                               (36)      (47)                                             6   2.24                                                                              237 0.28                                                                              10    100                                                                              40     60                                                               (90)      (33)                                             6   2.24                                                                              238 0.28                                                                              90    100                                                                              25     60                                                               (10)      (58)                                             6   2.24                                                                              239 0.28                                                                              85    95 80     75                                                               (10)      (0)                                              6   2.24                                                                              240 0.28                                                                              25    95 25     75                                                               (73)      (66)                                             6   2.24                                                                              241 0.28                                                                              95    100                                                                        (5)                                                        6   2.24                                                                              241 0.28         85     85                                                                         (0)                                              6   2.24                                                                              242 0.28         70     85                                                                         (17)                                             6   2.24                                                                              242 0.28                                                                              100   100                                                                        (0)                                                        6   2.24                                                                              243 0.28                                                                              5     85 45     65                                                               (94)      (30)                                             6   2.24                                                                              244 0.28                                                                              45    100                                                                              85     95                                                               (55)      (10)                                             6   2.24                                                                              245 0.28                                                                              35    100                                                                              50     95                                                               (65)      (47)                                             6   2.24                                                                              246 0.28                                                                              20    100                                                                              85     95                                                               (80)      (10)                                             6   2.24                                                                              247 0.28                                                                              35    100                                                                              95     90                                                               (65)      (0)                                              6   2.24                                                                              248 0.28                                                                              100   100                                                                              70     60                                                               (0)       (0)                                              6   2.24                                                                              249 0.28                                                                              100   100                                                                              50     70                                                               (0)       (28)                                             6   2.24                                                                              250 0.28                                                                              65    100                                                                              70     90                                                               (35)      (22)                                             6   2.24                                                                              251 0.28                                                                              55    100                                                                              25     90                                                               (45)      (72)                                             6   2.24                                                                              252 0.28                                                                              40    100                                                                              40     95                                                               (60)      (57)                                             6   2.24                                                                              253 0.28                                                                              35    100                                                                              60     95                                                               (65)      (36)                                             6   2.24                                                                              254 0.28                                                                              60    100                                                                              45     85                                                               (40)      (47)                                             6   2.24                                                                              255 0.28                                                                              60    100                                                                              85     95                                                               (40)      (10)                                             6   2.24                                                                              256 0.28                                                                              60    100                                                                              60     95                                                               (40)      (36)                                             6   2.24                                                                              257 0.28                                                                              65    100                                                                              50     95                                                               (35)      (47)                                             6   2.24                                                                              258 0.28                                                                              80    100                                                                              55     95                                                               (20)      (42)                                             6   2.24                                                                              259 0.28                                                                              60    100                                                                              85     95                                                               (40)      (10)                                             6   2.24                                                                              260 0.28                                                                              45    100                                                                              95     95                                                               (55)      (0)                                              6   2.24                                                                              261 0.28                                                                              100   100                                                                              95     100                                                              (0)       (5)                                              6   2.24                                                                              262 0.28                                                                              100   100                                                                              95     100                                                              (0)       (5)                                              6   2.24                                                                              263 0.28                                                                              70    100                                                                              90     100                                                              (30)      (10)                                             6   2.24                                                                              264 0.28                                                                              40    100                                                                              90     100                                                              (60)      (10)                                             6   2.24                                                                              265 0.28                                                                              70    100                                                                              95     100                                                              (30)      (5)                                              6   2.24                                                                              266 0.28                                                                              40    100                                                                              85     100                                                              (60)      (15)                                             6   2.24                                                                              267 0.28                                                                              50    100                                                                              85     100                                                              (50)      (15)                                             6   2.24                                                                              268 0.28                                                                              65    100                                                                              90     100                                                              (35)      (10)                                             6   2.24                                                                              269 0.28                                                                              60    100                                                                              65     100                                                              (40)      (35)                                             6   2.24                                                                              270 0.28                                                                              65    100                                                                              80     100                                                              (35)      (20)                                             6   2.24                                                                              271 0.28                                                                              5     95 35     100                                                              (94)      (65)                                             6   2.24                                                                              272 0.28                                                                              30    95 55     100                                                              (68)      (45)                                             6   2.24                                                                              273 0.28                                                                              60    95 75     100                                                              (36)      (25)                                             6   2.24                                                                              274 0.28                                                                              80    100                                                                              40     95                                                               (20)      (57)                                             6   2.24                                                                              275 0.28                                                                              65    100                                                                              40     95                                                               (35)      (57)                                             6   2.24                                                                              276 0.28                                                                              35    100                                                                              60     95                                                               (65)      (36)                                             6   2.24                                                                              277 0.28                                                                              85    95 65     90                                                               (10)      (27)                                             6   2.24                                                                              278 0.28                                                                              30    100                                                                              65     80                                                               (70)      (18)                                             6   2.24                                                                              279 0.28                                                                              50    90 65     80                                                               (44)      (18)                                             6   2.24                                                                              280 0.28                                                                              95    95                                                                         (0)                                                        6   2.24                                                                              281 0.28                                                                              35    95 20     45                                                               (63)      (55)                                             6   2.24                                                                              282 0.28                                                                              100   95 90     100                                                              (0)       (10)                                             6   2.24                                                                              283 0.28                                                                              95    95 85     70                                                               (0)       (0)                                              6   2.24                                                                              284 0.28                                                                              95    100                                                                        (5)                                                        10  4.48                                                                              203 0.28                   20    95                                                                         (78)                                    10  4.48                                                                              204 0.28                   60    85                                                                         (29)                                    10  4.48                                                                              205 0.28                   45    95                                                                         (52)                                    10  4.48                                                                              206 0.28                   60    100                                                                        (40)                                    10  4.48                                                                              207 0.28                   80    95                                                                         (15)                                    10  4.48                                                                              208 0.28                   60    85                                                                         (29)                                    10  4.48                                                                              209 0.28                   35    95                                                                         (63)                                    10  4.48                                                                              210 0.28                   100   95                                                                         (0)                                     10  4.48                                                                              211 0.28                   100   100                                                                        (0)                                     10  4.48                                                                              212 0.28                   30    80                                                                         (62)                                    10  4.48                                                                              213 0.28                   75    65                                                                         (0)                                     10  4.48                                                                              214 0.28                   45    90                                                                         (50)                                    10  4.48                                                                              215 0.28                   50    90                                                                         (44)                                    10  4.48                                                                              216 0.28                   40    90                                                                         (55)                                    10  4.48                                                                              217 0.28                   40    95                                                                         (57)                                    10  4.48                                                                              218 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              219 0.28                   50    95                                                                         (47)                                    10  4.48                                                                              220 0.28                   75    90                                                                         (16)                                    10  4.48                                                                              221 0.28                   40    90                                                                         (55)                                    10  4.48                                                                              222 0.28                   50    90                                                                         (44)                                    10  4.48                                                                              223 0.28                   40    90                                                                         (55)                                    10  4.48                                                                              224 0.28                   20    90                                                                         (77)                                    10  4.48                                                                              225 0.28                   70    90                                                                         (22)                                    10  4.48                                                                              226 0.28                   20    90                                                                         (77)                                    10  4.48                                                                              227 0.28                   30    90                                                                         (66)                                    10  4.48                                                                              228 0.28                   20    90                                                                         (77)                                    10  4.48                                                                              229 0.28                   40    90                                                                         (55)                                    10  4.48                                                                              230 0.28                   20    85                                                                         (76)                                    10  4.48                                                                              231 0.28                   40    85                                                                         (52)                                    10  4.48                                                                              232 0.28                   20    85                                                                         (76)                                    10  4.48                                                                              233 0.28                   40    80                                                                         (50)                                    10  4.48                                                                              234 0.28                   60    80                                                                         (25)                                    10  4.48                                                                              235 0.28                   50    90                                                                         (44)                                    10  4.48                                                                              236 0.28                   45    90                                                                         (50)                                    10  4.48                                                                              237 0.28                   15    85                                                                         (82)                                    10  4.48                                                                              238 0.28                   15    85                                                                         (82)                                    10  4.48                                                                              239 0.28                   80    95                                                                         (15)                                    10  4.48                                                                              240 0.28                   30    95                                                                         (68)                                    10  4.48                                                                              241 0.28                   75    75                                                                         (0)                                     10  4.48                                                                              242 0.28                   55    75                                                                         (26)                                    10  4.48                                                                              243 0.28                   10    65                                                                         (84)                                    10  4.48                                                                              244 0.28                   45    95                                                                         (52)                                    10  4.48                                                                              245 0.28                   50    90                                                                         (44)                                    10  4.48                                                                              246 0.28                   45    90                                                                         (50)                                    10  4.48                                                                              247 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              248 0.28                   50    65                                                                         (23)                                    10  4.48                                                                              249 0.28                   85    95                                                                         (10)                                    10  4.48                                                                              250 0.28                   95    90                                                                         (0)                                     10  4.48                                                                              251 0.28                   80    90                                                                         (11)                                    10  4.48                                                                              252 0.28                   35    60                                                                         (41)                                    10  4.48                                                                              253 0.28                   15    60                                                                         (75)                                    10  4.48                                                                              254 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              255 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              256 0.28                   75    95                                                                         (21)                                    10  4.48                                                                              257 0.28                   75    95                                                                         (21)                                    10  4.48                                                                              258 0.28                   95    100                                                                        (5)                                     10  4.48                                                                              259 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              260 0.28                   70    95                                                                         (26)                                    10  4.48                                                                              261 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              262 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              263 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              264 0.28                   40    95                                                                         (57)                                    10  4.48                                                                              265 0.28                   50    95                                                                         (47)                                    10  4.48                                                                              266 0.28                   50    95                                                                         (47)                                    10  4.48                                                                              267 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              268 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              269 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              270 0.28                   55    95                                                                         (42)                                    10  4.48                                                                              271 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              272 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              273 0.28                   70    95                                                                         (26)                                    10  4.48                                                                              274 0.28                   65    95                                                                         (31)                                    10  4.48                                                                              275 0.28                   40    95                                                                         (57)                                    10  4.48                                                                              276 0.28                   50    95                                                                         (47)                                    10  4.48                                                                              277 0.28                   50    90                                                                         (44)                                    10  4.48                                                                              278 0.28                   70    100                                                                        (30)                                    10  4.48                                                                              279 0.28                   45    95                                                                         (52)                                    10  4.48                                                                              280 0.28                   50    70                                                                         (28)                                    10  4.48                                                                              281 0.28                   65    85                                                                         (23)                                    10  4.48                                                                              282 0.28                   90    95                                                                         (5)                                     10  4.48                                                                              283 0.28                   95    95                                                                         (0)                                     15  2.24                                                                              203 0.28                                      40    95                                                                         (57)                 15  2.24                                                                              203 0.28                            40     60                                                                         (33)                          15  2.24                                                                              204 0.28                            55     40 85    85                                                                (0)      (0)                  15  2.24                                                                              205 0.28                            15     55 20    90                                                                (72)     (77)                 15  2.24                                                                              206 0.28                            20     50 50    95                                                                (60)     (47)                 15  2.24                                                                              207 0.28                            50     45 80    95                                                                (0)      (15)                 15  2.24                                                                              208 0.28                            30     50 95    95                                                                (40)     (0)                  15  2.24                                                                              209 0.28                            20     50 0     90                                                                (60)     (100)                15  2.24                                                                              210 0.28                            30     70 70    95                                                                (57)     (26)                 15  2.24                                                                              211 0.28                            80     60 60    90                                                                (0)      (33)                 15  2.24                                                                              212 0.28                            60     80 20    80                                                                (25)     (75)                 15  2.24                                                                              213 0.28                            40     80 10    95                                                                (50)     (89)                 15  2.24                                                                              214 0.28                            70     70 95    95                                                                (0)      (0)                  15  2.24                                                                              215 0.28                            70     70 95    95                                                                (0)      (0)                  15  2.24                                                                              216 0.28                            70     70 95    95                                                                (0)      (0)                  15  2.24                                                                              217 0.28                            70     85 75    95                                                                (17)     (21)                 15  2.24                                                                              218 0.28                            85     85 95    95                                                                (0)      (0)                  15  2.24                                                                              219 0.28                            85     85 95    95                                                                (0)      (0)                  15  2.24                                                                              220 0.28                            85     90 95    95                                                                (5)      (0)                  15  2.24                                                                              221 0.28                            80     70 50    95                                                                (0)      (47)                 15  2.24                                                                              222 0.28                            85     70 95    95                                                                (0)      (0)                  15  2.24                                                                              223 0.28                            95     70 85    95                                                                (0)      (10)                 15  2.24                                                                              224 0.28                            90     70 60    95                                                                (0)      (36)                 15  2.24                                                                              225 0.28                            75     70 90    90                                                                (0)      (0)                  15  2.24                                                                              226 0.28                            70     70 60    90                                                                (0)      (33)                 15  2.24                                                                              227 0.28                            30     70 40    90                                                                (57)     (55)                 15  2.24                                                                              228 0.28                            30     70 40    90                                                                (57)     (55)                 15  2.24                                                                              229 0.28                            20     70 10    90                                                                (71)     (88)                 15  2.24                                                                              230 0.28                            20     70 10    85                                                                (71)     (88)                 15  2.24                                                                              231 0.28                            20     65 50    95                                                                (69)     (47)                 15  2.24                                                                              232 0.28                            10     65 30    95                                                                (84)     (68)                 15  2.24                                                                              233 0.28                            15     55 95    95                                                                (72)     (0)                  15  2.24                                                                              234 0.28                            40     55 90    95                                                                (27)     (5)                  15  2.24                                                                              235 0.28                            60     45 55    80                                                                (0)      (31)                 15  2.24                                                                              236 0.28                            70     45 30    80                                                                (0)      (62)                 15  2.24                                                                              237 0.28                                      30    60                                                                         (50)                 15  2.24                                                                              237 0.28                            65     45                                                                         (0)                           15  2.24                                                                              238 0.28                            80     45 100   95                                                                (0)      (0)                  15  2.24                                                                              239 0.28                            15     55 80    100                                                               (72)     (20)                 15  2.24                                                                              240 0.28                            20     55 50    100                                                               (63)     (50)                 15  2.24                                                                              241 0.28                            25     55 60    85                                                                (54)     (29)                 15  2.24                                                                              242 0.28                            45     55 70    85                                                                (18)     (17)                 15  2.24                                                                              243 0.28                                      25    80                                                                         (68)                 15  2.24                                                                              244 0.28                            15     45 65    100                                                               (66)     (35)                 15  2.24                                                                              245 0.28                            0      40 45    80                                                                (100)    (43)                 15  2.24                                                                              246 0.28                            35     40 65    80                                                                (12)     (18)                 15  2.24                                                                              247 0.28                            55     50 45    95                                                                (0)      (52)                 15  2.24                                                                              248 0.28                                      80    100                                                                        (20)                 15  2.24                                                                              248 0.28                            85     45                                                                         (0)                           15  2.24                                                                              249 0.28                            15     45 95    100                                                               (66)     (5)                  15  2.24                                                                              250 0.28                            90     75 15    90                                                                (0)      (83)                 15  2.24                                                                              251 0.28                            65     75 20    90                                                                (13)     (77)                 15  2.24                                                                              252 0.28                            10     50 20    100                                                               (80)     (80)                 15  2.24                                                                              253 0.28                            40     50 15    100                                                               (20)     (85)                 15  2.24                                                                              254 0.28                            35     60 95    95                                                                (41)     (0)                  15  2.24                                                                              255 0.28                            5      45 75    95                                                                (88)     (21)                 15  2.24                                                                              256 0.28                            15     45 90    95                                                                (66)     (5)                  15  2.24                                                                              257 0.28                            90     45 100   95                                                                (0)      (0)                  15  2.24                                                                              258 0.28                            60     65 95    100                                                               (7)      (5)                  15  2.24                                                                              259 0.28                            95     50 90    95                                                                (0)      (5)                  15  2.24                                                                              260 0.28                            55     80 90    95                                                                (31)     (5)                  15  2.24                                                                              261 0.28                            85     75 95    100                                                               (0)      (5)                  15  2.24                                                                              262 0.28                            70     75 100   100                                                               (6)      (0)                  15  2.24                                                                              263 0.28                            55     85 55    95                                                                (35)     (42)                 15  2.24                                                                              264 0.28                            45     85 30    95                                                                (47)     (68)                 15  2.24                                                                              265 0.28                            55     85 55    95                                                                (35)     (42)                 15  2.24                                                                              266 0.28                            90     85 55    95                                                                (0)      (42)                 15  2.24                                                                              267 0.28                            95     90 90    95                                                                (0)      (5)                  15  2.24                                                                              268 0.28                            65     90 95    95                                                                (27)     (0)                  15  2.24                                                                              269 0.28                            80     90 90    95                                                                (11)     (5)                  15  2.24                                                                              270 0.28                            50     90 95    100                                                               (44)     (5)                  15  2.24                                                                              271 0.28                            75     80 40    80                                                                (6)      (50)                 15  2.24                                                                              272 0.28                            40     80 55    80                                                                (50)     (31)                 15  2.24                                                                              273 0.28                            20     80 65    80                                                                (75)     (18)                 15  2.24                                                                              274 0.28                            55     90 30    80                                                                (38)     (62)                 15  2.24                                                                              275 0.28                            50     90 35    80                                                                (44)     (56)                 15  2.24                                                                              276 0.28                            40     90 15    80                                                                (55)     (81)                 15  2.24                                                                              277 0.28                            85     90 75    100                                                               (5)      (25)                 15  2.24                                                                              278 0.28                            75     80 50    95                                                                (6)      (47)                 15  2.24                                                                              279 0.28                            45     85 65    95                                                                (47)     (31)                 15  2.24                                                                              280 0.28                            40     50 85    80                                                                (20)     (0)                  15  2.24                                                                              281 0.28                            45     50 65    95                                                                (10)     (31)                 15  2.24                                                                              282 0.28                            95     80 90    95                                                                (0)      (5)                  15  2.24                                                                              283 0.28                            60     80 95    95                                                                (25)     (0)                  __________________________________________________________________________

EXAMPLE 287

The procedure of Example 285 was followed to determine the interactionbetween herbicide and antidote when both are incorporated in a soilcover layer before emergence of the crop species. In this series oftests, however, all containers were seeded with at least one weedspecies in addition to crop seed. Results are reported in Table IV.

    TABLE IV      % PLANT INHIBITION AND % SAFENING EFFECT ( )     HEMP VELVET SORGHUM     GREEN  BARNYARD RED SHATTER HERBICIDE ANTIDOTE SOYBEAN RICE SESBANIA     LEAF GRAIN WHEAT FOXTAIL CORN GRASS RICE CANE NO. RATE NO. RATE W  WO W     WO W  WO W  WO W  WO W  WO W  WO W  WO W  WO W  WO W      WO                    3 1.12 11 8.96 30   35 10   40 99   99 50   90             (14)  (75)  (0)  (44)   3 2.24 11 8.96 50   60 50   75 99  100     99   99     (16)  (33)  (1)  (0)   3 4.48 11 8.96 95   90 99   80 100     100 100  100     (0)  (0)  (0)  (0)   3 6.72 11 8.96 100   95 100   95     100  100 100  100     (0)  (0)  (0)  (0)   3 1.12 13 8.96 95   50 70     30 100  100 85   40     (0)  (0)  (0)  (0)   3 2.24 13 8.96 99   60 40     30 99   99 30   70     (0)  (0)  (0)  (57)   3 4.48 13 8.96 100   80 75      70 99   99 99  100     (0)  (0)  (0)  (1)   3 6.72 13 8.96 99  100 80     100 99  100 90  100     (1)  (20)  (1)  (10)   3 1.12 21 8.96 90    60     50   45 100   80 85   60     (0)  (0)  (0)  (0)   3 2.24 21 8.96 95   60     30   60 100  100 100   90     (0)  (50)  (0)  (0)   3 4.48 21 8.96 95     70 30   85 100  100 95  100     (0)  (64)  (0)  (5)   3 6.72 21 8.96 90      90 70   75 100  100 100  100     (0)  (6)  (0)  (0)   3 2.24 30 2.24 10       60   90  100     (83)    (10)   3 2.24 30 8.96 10   60   100  100     (83)    (0)   3 6.72 30 2.24 95   90   100  100     (0)    (0)   3 6.72     30 8.96 75    90   100  100     (16)    (0)   3 2.24 32 2.24 70   80     100  100     (12)    (0)   3 2.24 32 8.96 80   80   100  100     (0)     (0)   3 6.72 32 2.24 95   95   100  100     (0)    (0)   3 6.72 32 8.96     90   95   100  100     (5)    (0)   6 0.56 1 2.24     60   58     (0)   6 0.56 1 2.24      5   28          (82)   6 0.56 1 2.24     30     85 15   30 85   90         (64)  (50)  (5)   6 0.56 1 8.96     0   50 30       40 98   98         (100)  (25)  (0)   6 0.56 1 8.96     5   85 20   30     85   90         (94)  (33)  (5)   6 0.56 1 8.96      5   28     (82)   6 0.56 1 8.96     20   58         (65)   6 1.12 1 8.96     10     70 30   50 99   99         (85)  (40)  (0)   6 2.24 1 2.24     75   88           (14)   6 2.24 1 2.24     45   95 35   50 95   95         (52)     (30)  (0)   6 2.24 1 2.24      5   40          (87)   6 2.24 1 8.96     60   88         (31)   6 2.24 1 8.96      15   40          (62)   6 2.24     1 8.96     15   95 30   70 98   99         (84)  (57)  (1)   6 2.24 1     8.96     40   95 45   50 100   95         (57)  (10)  (0)   6 4.48 1     8.96     75   98 70   80 100   99         (23)  (12)  (0)   6 0.56 3     2.24     15   58         (74)   6 0.56 3 2.24      0   28          (100)       6 0.56 3 8.96     0   60 10   60 100  100         (100)  (83)  (0)   6     0.56 3 8.96      0   28          (100)   6 0.56 3 8.96     5   58      (91)   6 1.12 3 8.96     0   90 0   80 100  100         (100)  (100)     (0)   6 2.24 3 0.56     80   95 40   73         (15)  (45)   6 2.24 3     2.24     25   95 40   73         (73)  (45)   6 2.24 3 2.24     80   88            (9)   6 2.24 3 2.24      20   40          (50)   6 2.24 3 4.48      35   95 70   73         (63)  (4)   6 2.24 3 8.96     15   90 35   80     100  100         (83)  (56)  (0)   6 2.24 3 8.96      10   40     (75)   6 2.24 3 8.96     25   88         (71)   6 4.48 3 8.96     10     100 75   90 100  100         (90)  (16)  (0)    6 0.56 4 2.24     5   48             (89)   6 0.56 4 8.96     5   48         (89)   6 0.56 4 8.96     10   65 25   60 99   99         (84)  (58)  (0)   6 1.12 4 8.96     20     90 25   70 100   99         (77)  (64)  (0)   6 2.24 4 2.24     10   83            (87)   6 2.24 4 8.96     5   83         (93)   6 2.24 4 8.96     40   98 50   85 100   99         (59)  (41)  (0)   6 4.48 4 8.96     50      99 70   85 100   99         (49)  (17)  (0)   6 0.56 6 8.96     0   20     30   75 75   50         (100)  (60)  (0)   6 1.12 6 8.96     0   30 40     70 90   80        (100)  (42)  (0)   6 2.24 6 8.96     10   50 40   50     99   95         (80)  (20)  (0)   6 4.48 6 8.96     20   80 60   70 100      95         (75)   (14)   6 0.56 7 2.24      15   28          (46)   6     0.56 7 2.24     35   58         (39)   6 0.56 7 8.96     0   90 80   40     80   50         (100)  (0)  (0)   6 0.56 7 8.96      5   28     (82)   6 0.56 7 8.96     10   58         (82)   6 1.12 7 8.96     0   90     60   60 70   70         (100)  (0)  (0)   6 2.24 7 2.24     85   88        (3)   6 2.24 7 2.24      25   40          (37)   6 2.24 7 8.96     30   40          (25)   6 2.24 7 8.96     5   99 95   85 100   75      (94)  (0)  (0)   6 2.24 7 8.96     35   88         (60)   6 4.48 7 8.96         10   99 90   90 95   99         (89)  (0)  (4)   6 0.56 8 8.96     0       90 80   40 20   50         (100)  (0)  (60)   6 1.12 8 8.96     0   90     90   60 70   70         (100)  (0)  (0)   6 2.24 8 8.96     0   99 90     85 90   75         (100)  (0)  (0)   6 4.48 8 8.96     20   99 85   90     99   99         (79)  (5)  (0)   6 0.56 9 2.24     45   58         (22)      6 0.56 9 2.24      5   28          (82)   6 0.56 9 8.96     25   58         (56)   6 0.56 9 8.96     0   90 50   70 95   50         (100)  (28)     (0)   6 0.56 9 8.96      10   28          (64)   6 1.12 9 8.96     0     95 70   80 80   80         (100)  (12)  (0)   6 2.24 9 2.24     80   88            (9)   6 2.24 9 2.24      30   40          (25)   6 2.24 9 8.96      70   88         (20)   6 2.24 9 8.96     10  100 90   80 100  100       (90)  (0)  (0)   6 2.24 9 8.96      20   40          (50)   6 4.48 9     8.96     30  100 95  100 100   99         (70)  (5)  (0)   6 0.56 10     2.24     35   88         (60)   6 0.56 10  2.24      15   48     (68)   6 0.56 10  8.96     0   90 40   70 90   50         (100)  (42)     (0)   6 0.56 10  8.96      15   48          (68)   6 0.56 10  8.96     5       88         (94)   6 1.12 10  8.96     0   95 60   80 90   80     (100)  (25)  (0)   6 2.24 10  2.24     65   98         (33)   6 2.24 10     2.24      70   75          (6)   6 2.24 10  8.96     25   98     (74)   6 2.24 10  8.96     20  100 60   80 100  100         (80)  (25)     (0)   6 2.24 10  8.96      60   75          (20)   6 4.48 10  8.96     25  100 90  100 100   99         (75)  (10)  (0)   6 0.56 11  8.96     0       35 40   60 40   80         (100)  (33)  (50)   6 1.12 11  8.96     10      85 80   70 90   90         (88)  (0)  (0)   6 2.24 11  8.96     10   90     80   90 100    99         (88)  (11)  (0)   6 4.48 11  8.96     50   99     90   90 100  100         (49)  (0)  (0)   6 0.56 12  2.24      10   28            (64)   6 0.56 12  2.24     30   58        (48)   6 0.56 12  8.96         20   28          (28)   6 0.56 12  8.96     0   58         (100)   6     0.56 12  8.96     10   60 40   50 50   70         (83)  (20)  (28)   6     1.12 12  8.96     20    60 70   50 95   80         (66)  (0)  (0)   6     2.24 12  2.24     55   88         (37)   6 2.24 12  2.24      10   40           (75)   6 2.24 12  8.96      10   40          (75)   6 2.24 12     8.96     25   80 70   85 80   95         (68)  (17)  (15)   6 2.24 12     8.96     25   88         (71)   6 4.48 12  8.96     30   90 90   95 100     100         (66)  (5)  (0)   6 0.56 13  8.96     30   90 30   40 99   90             (66)  (25)  (0)   6 1.12 13  8.96     40   99 40   60 80   90          (59)  (33)  (11)   6 2.24 13  8.96     80   99 70   75 99   95        (19)  (6)  (0)   6 4.48 13  8.96     90   90 85   95 100   95     (0)  (10)  (0)   6 0.56 14  2.24      10   28          (64)   6 0.56 14     2.24     40   58         (31)   6 0.56 14  8.96     0    58     (100)   6 0.56 14  8.96     10   90 50   40 80   90         (88)  (0)     (11)   6 0.56 14  8.96      15   28          (46)   6 1.12 14  8.96     35   99 60   60 95   90         (64)  (0)  (0)   6 2.24 14  2.24    50     88         (43)   6 2.24 14  2.24      20   40          (50)   6 2.24 14      8.96     50   99 90   75 100   95         (49)  (0)  (0)   6 2.24 14     8.96     45   88         (48)  `6 2.24 14  8.96      15   40     (62)   6 4.48 14  8.96     50   90 90   95 99   95         (44)  (5)     (0)   6 0.56 15  8.96     10   95 50   70 80   70         (89)  (28)     (0)   6 1.12 15  8.96    60   95 60   90 100   80         (36)  (33)     (0)   6 2.24 15  8.96    25   95 70   99 100   99         (73)  (29)     (0)   6 4.48 15 8.96     55  100 100   100 100   99         (45)  (0)     (0)   6 0.56 16  2.24      5   28          (82)   6 0.56 16  2.24     10       58         (82)   6 0.56 16  8.96      20   28          (28)   6 0.56     16  8.96     10   58         (82)   6 0.56 16  8.96     10   80 30   50     80   80         (87)  (40)  (0)   6 1.12 16  8.96     30   80 50   70 90       95         (62)  (28)  (5)   6 2.24 16  2.24     60   88         (31)      6 2.24 16  2.24      25   40          (37)   6 2.24 16  8.96     15     88         (82)   6 2.24 16  8.96     40   95 50   80 90   95     (57)  (37)  (5)   6 2.24 16  8.96      5   40          (87)   6 4.48 16     8.96     60  100 90   90 95  100         (40)  (0)  (5)   6 0.56 17     8.96     0   70 10   45 99   95         (100)  (77)  (0)   6 1.12 17     8.96     10   80 30   60 99   95         (87)  (50)  (0)   6 2.24 17     8.96     30   90 40   80 100  100         (66)  (50)  (0)   6 4.48 17     8.96     40   95 80   90 100  100         (57)  (11)  (0)   6 0.56 19     2.24     25   48         (47)   6 0.56 19  8.96     5   48         (89)      6 2.24 19  2.24     30   83         (63)   6 2.24 19  8.96     10   83            (87)   6 0.56 20  2.24     10   48         (79)   6 0.56 20  8.96         50   95 30   50 95   95         (47)  (40)  (0)   6 0.56 20  8.96      10   48         (79)   6 1.12 20  8.96     50  100 40   80 95  100        (50)  (50)  (5)   6 2.24 20  2.24     35   83         (57)   6 2.24     20  8.96     10   83         (87)   6 2.24 20  8.96     50  100 50   90     99  100         (50)  (44)  (1)   6 4.48 20  8.96     85  100 80   95     100  100         (15)  (15)  (0)   6 0.56 22  2.24      5   20     (75)   6 0.56 22  8.96     0   95 55   80 85   35         (100)  (31)     (0)   6 0.56 22  8.96      10   20          (50)   6 1.12 22  8.96     50  100 60   70 80   75         (50)  (14)  (0)   6 2.24 22  0.56     90       93         (3)   6 2.24 22  2.24     95   93         (0)   6 2.24 22     2.24      30   55          (45)   6 2.24 22  8.96     75   95 80  100 95       90         (21)  (20)  (0)   6 2.24 22  8.96      35   55     (36)   6 2.24 22  8.96     65   93         (30)   6 4.48 22  8.96     90      100 100   95 95   95         (10)  (0)  (0)   6 0.56 23  2.24     45     70 0   10 95   95         (35)  (100)  (0)   6 0.56 23  2.24      55     60 100  100         (8)  (0)   6 0.56 23  2.24      50   40 100  100          (0)  (0)   6 0.56 23  2.24      15   45 100  100          (66)  (0)       6 0.56 23  2.24     95   95 20   40 90   95         (0)  (50)  (5)   6     0.56 23  2.24     55   85 5   30 90   90         (35)  (83)  (0)   6     0.56 23  2.24      25   25 100  100          (0)  (0)   6 0.56 23  2.24         35   20 100  100          (0)  (0)   6 0.56 23  2.24     65   90 30      35 95   95         (27)  (14)  (0)   6 0.56 23  2.24      40   40 100     100          (0)  (0)   6 0.56 23  2.24      85   85 100  100     (0)  (0)   6 0.56 23  2.24     25   90 20   35 90   95         (72)     (42)  (5)   6 0.56 23  2.24      60   90 100  100          (33)  (0)   6     0.56 23  2.24     35   75 10   30 95   95         (53)  (66)  (0)   6     0.56 23  2.24      0   10 100  100          (100)  (0)   6 0.56 23  2.24         40   80 20   35 90  100         (50)  (42)  (10)   6 0.56 23  2.24       15   10 0   0 90   95         (0)  (0)  (5)   6 0.56 23  2.24     50     90 10   20 95   95         (44)  (50)  (0)   6 0.56 23  2.24     35   95     5   50 100  100         (63)  (90)  (0)   6 0.56 23  2.24      60    80     100  100          (25)  (0)   6 0.56 23  2.24     5  100 15   40 90  100             (95)  (62)  (10)   6 0.56 23  2.24      40   90 100  100      (55)  (0)   6 0.56 23  2.24      10   35 100  100          (71)  (0)     6 0.56 23  2.24      0   65 100  100          (100)  (0)   6 0.56 23     2.24     75  100 15   65 100  100        (25)  (76)  (0)   6 0.56 23     2.24      0   35 90  100          (100)  (10)   6 0.56 23  2.24     35     100 45   20 95  100         (65)  (0)  (5)   6 0.56 23  2.24      65     80 100  100          (18)  (0)   6 0.56 23  2.24     15  100 45   45 95      95         (85)  (0)  (0)   6 0.56 23  2.24     60  100 85   60 100     100         (40)  (0)  (0)   6 0.56 23  2.24     75   95 10   35 100     100         (21)  (71)  (0)   6 0.56 23  2.24     50   95 100  100        (47)  (0)   6 0.56 23  2.24     60  100 55   40 95   95         (40)     (0)  (0)   6 0.56 23  2.24      5   30 90   95          (83)  (5)   6     0.56 23  2.24     25  100 0   75 100  100         (75)  (100)  (0)   6     0.56 23  2.24      45   80 100  100          (43)  (0)   6 0.56 23  2.24          60   50 100  100          (0)  (0)   6 0.56 23  2.24     10   75 10       35 95   95         (86)  (71)  (0)   6 0.56 23  2.24      20   25 100     100          (20)  (0)   6 0.56 23  2.24      15   75 100  100     (80)  (0)   6 0.56 23  2.24     45  100 15   50 100  100         (55)     (70)  (0)   6 0.56 23  2.24     40   58         (31)   6 0.56 23  2.24        5   28          (82)   6 0.56 23  2.24     25  100 20   60 95  100          (75)  (66)  (5)   6 0.56 23  2.24     35  100 35   80 100   95        (65)  (56)  (0)   6 0.56 23  2.24     40   95 50   70 95  100     (57)  (28)  (5)   6 0.56 23  2.24     30  100 45   75 95  100     (70)  (40)  (5)   6 0.56 23  2.24     35   95 5   6095  100         (63)      (91)  (5)   6 0.56 23  2.24     55  100 50   65 100   95         (45)     (23)  (0)   6 0.56 23  8.96      10   75 95  100          (86)  (5)   6     0.56 23  8.96     0  100 20   50 100  100         (100)  (60)  (0)   6     0.56 23  8.96      30   50 100  100         (40)  (0)   6 0.56 23  8.96         20   25 100  100          (20)  (0)   6 0.56 23  8.96     55   80     100  100          (31)  (0)   6 0.56 23  8.96     25  100 0   75 100     100         (75)  (100)  (0)   6 0.56 23  8.96     5   75 0   35 90   95             (93)  (100)  (5)   6 0.56 23  8.96      40   95 100  100      (57)  (0)   6 0.56 23  8.96     10   80 0   35 95  100         (87)     (100)  (5)   6 0.56 23  8.96     10   95 30   35 100  100         (89)     (14)  (0)   6 0.56 23  8.96      0   65 100  100          (100)  (0)   6     0.56 23  8.96      25   80 100  100          (68)  (0)   6 0.56 23  8.96         15  100 15   20 95  100         (85)  (25)  (5)   6 0.56 23  8.96      15  100 0   60 100   100         (85)  (100)  (0)   6 0.56 23  8.96     10  100 20   45 95   95         (90)  (55)  (0)   6 0.56 23  8.96     15      100 5   40 85   95         (85)  (87)  (10)   6 0.56 23  8.96     0     100 10   65 100  100         (100)  (84)  (0)   6 0.56 23  8.96     10     100   0 95   95         (0)  (0)  (0)   6 0.56 23  8.96      10   35 85     100          (71)  (15)   6 0.56 23  8.96      0    35 95  100     (100)  (5)   6 0.56 23  8.96      15   30 85   95          (50)  (10)     6 0.56 23  8.96     20  100 5   40 90  100         (80)  (87)  (10)   6     0.56 23  8.96      15   80 100  100          (81)  (0)   6 0.56 23  8.96         10   95 25   40 95   95         (89)  (37)  (0)   6 0.56 23  8.96       40   90 100  100          (55)  (0)   6 0.56 23  8.96     60   90 5     20 95    95         (33)  (75)  (0)   6 0.56 23  8.96     10   95 5   50     100  100         (89)  (90)  (0)   6 0.56 23  8.96     30   90 15   35     90   95         (66)  (57)  (5)   6 0.56 23  8.96     30   75 25   30 95       95         (60)  (16)  (0)   6 0.56 23  8.96      55   90 100  100          (38)  (0)   6 0.56 23  8.96      35   40 95  100          (12)  (5)       6 0.56 23  8.96      0    25 100  100          (100)  (0)   6 0.56 23     8.96     55   90 25   75 80   85         (38)  (66)  (5)   6 0.56 23     8.96      70   85 100  100          (17)  (0)   6 0.56 23  8.96      5     40 100  100          (87)  (0)   6 0.56 23  8.96     20   90 0   35 100      95         (77)  (100)  (0)   6 0.56 23  8.96     50   70 0   10 95     95         (28)  (100)  (0)   6 0.56 23  8.96      0    20 100  100         (100)  (0)   6 0.56 23  8.96     0   85 25   30 95   90     (100)  (16)  (0)   6 0.56 23  8.96      15   45 100  100          (66)     (0)   6 0.56 23  8.96      0   10 95  100         (100)  (5)   6 0.56 23      8.96      60   60 80  100          (0)  (20)   6 0.56 23  8.96     15     58         (74)   6 0.56 23  8.96     15  100 35   75 100  100     (85)  (53)  (0)   6 0.56 23  8.96     35   95 10   70 95  100     (63)  (85)  (5)   6 0.56 23  8.96     30  100 35   80 100   95     (70)  (56)  (0)   6 0.56 23  8.96     45   95 25   60 95  100     (52)  (58)  (5)   6 0.56 23  8.96     15  100 45   60 95  100     (85)  (25)  (5)   6 0.56 23  8.96     20  100 30   65 95   95     (80)  (53)  (0)   6 0.56 23  8.96      20   28          (28)   6 1.12 23      8.96     90   90 30   85 100  100         (0)  (64)  (0)   6 2.24 23     2.24     90  100 50   50 90  100         (10)  (0)  (10)   6 2.24 23     2.24      90   80 100  100          (0)  (0)   6 2.24 23  2.24      50     80 100  100          (37)  (0)   6 2.24 23  2.24      45   85 100  100            (47)  (0)   6 2.24 23  2.24      60   75 100  100          (20)     (0)   6 2.24 23  2.24     85   95 30   50 100   95         (10)  (40)     (0)   6 2.24 23  2.24      75   80 100  100          (6)  (0)   6 2.24     23  2.24      5   50 100  100          (90)  (0)   6 2.24 23  2.24     80   95 65   55 95   95         (15)  (0)  (0)   6 2.24 23  2.24     85      90 15   75 100  100         (5)  (80)  (0)   6 2.24 23  2.24      90     95 100  100          (5)  (90)   6 2.24 23  2.24     80  100 35   55 100      100         (20)  (36)  (0)   6 2.24 23  2.24      85   95 100  100          (10)  (0)   6 2.24 23  2.24      70   55 100  100          (0)  (0)       6 2.24 23  2.24     40   80 0   0 95  100         (50)  (0)  (5)   6     2.24 23  2.24     75  100 25   60 100  100         (25)  (58)  (0)   6     2.24 23  2.24     85  100 55   95 100  100         (15)  (42)  (0)   6     2.24 23   2.24     95  100 50   60 95  100         (5)  (16)  (5)   6     2.24 23  2.24      90   95 100  100          (5)  (0)   6 2.24 23  2.24        75   95 60   65 85   95         (21)  (7)  (10)   6 2.24 23  2.24     80  100 80   90 100  100         (20)  (11)  (0)   6 2.24 23  2.24     30   75 100  100         (60)  (0)   6 2.24 23  2.24      100   95 100     100          (0)  (0)   6 2.24 23  2.24     55  100 10   80 100  100         (45)  (87)  (0)   6 2.24 23  2.24     90  100 50   70 100  100       (10)  (28)  (0)   6 2.24 23  2.24      85   95 100  100          (10)     (0)   6 2.24 23  2.24      70   50 100  100          (0)  (0)   6 2.24     23  2.24     60  100 35   65 100  100         (40)  (46)  (0)   6 2.24     23  2.24      85   95 100  100          (10)  (0)   6 2.24 23  2.24     80  100 65   75 100  100         (20)  (13)  (0)   6 2.24 23  2.24     75  100 50   75 100   95         (25)  (33)  (0)   6 2.24 23  2.24     30   65 100  100          (53)  (0)   6 2.24 23  2.24     15   95 65     60 100  100         (84)  (0)  (0)   6 2.24 23  2.24     85  100 80   90     100  100         (15)  (11)  (0)   6 2.24 23  2.24      80   95 100  100              (15)  (0)   6 2.24 23  2.24     100  100 75  100 100  100       (0)  (25)  (0)   6 2.24 23  2.24      75   95 100  100          (21)     (0)   6 2.24 23  2.24      60   60 100  100          (0)  (0)   6 2.24     23  2.24      60   95 100  100          (36)  (0)   6 2.24 23  2.24     50  100 70   90 100  100         (50)  (22)  (0)   6 2.24 23  2.24     75   90 100  100          (16)  (0)   6 2.24 23  2.24     60  100 65     90 100  100         (40)  (27)  (0)   6 2.24 23  2.24      40   40        (0)   6 2.24 23  2.24     70  100 45   90 100  100         (30)  (50)      (0)   6 2.24 23  2.24     80  100 50   80 100  100         (20)  (37)     (0)   6 2.24 23  2.24     85  100 85   90 100  100         (15)  (5)     (0)   6 2.24 23  2.24     70   88         (20)   6 2.24 23  2.24     85     100 65   70 100  100         (15)  (7)  (0)   6 2.24 23  2.24     55     100 50   95 95  100         (45)  (47)  (5)   6 2.24 23  8.96     10     95 10   60 100  100         (89)  (83)  (0)   6 2.24 23  8.96      15     60 100  100          (75)  (0)   6 2.24 23  8.96      95   95 100  100            (0)  (0)   6 2.24 23  8.96      75   90 100  100          (16)     (0)   6 2.24 23  8.96     45  100 50   90 100  100         (55)  (44)     (0)   6 2.24 23  8.96      85   95 100  100          (10)  (0)   6 2.24     23  8.96      70   95 100  100          (26)  (0)   6 2.24 23  8.96     70  100 40   90 100  100         (30)  (55)  (0)   6 2.24 23  8.96     35  100 5   60 100  100         (65)  (91)  (0)   6 2.24 23  8.96     45      100 70  100 100  100         (55)  (30)  (0)   6 2.24 23  8.96     35     100 45   65 100  100         (65)  (30)  (0)   6 2.24 23  8.96      60     95 100  100          (36)  (0)   6 2.24 23  8.96      60   95 100  100            (36)  (0)   6 2.24 23  8.96     35  100 50   75 95   95     (65)  (33)  (0)   6 2.24 23  8.96      35   65 100  100          (46)     (0)   6 2.24 23  8.96     45   80 5   0 95  100         (43)  (0)  (5)     6 2.24 23  8.96     60  100 55   75 100  100         (40)  (26)  (0)   6     2.24 23  8.96     50   100 50   70 100  100         (50)  (28)  (0)   6     2.24 23  8.96     5  100 35   80 100  100         (95)  (56)  (0)   6     2.34 23  8.96     80   95 100  100         (15)  (0)   6 2.24 23  8.96       35  100 45   90 100  100         (65)  (50)  (0)   6 2.24 23  8.96     60   95 50   80 100  100         (36)  (37)  (0)   6 2.24 23  8.96     40   75 100  100         (46)  (0)   6 2.24 23  8.96      60   95 100     100          (36)  (0)   6 2.24 23  8.96      25   50 100  100     (50)  (0)   6 2.24 23  8.96     70  100 70   95 100  100         (30)     (26)  (0)   6 2.24 23  8.96     60  100 55   60 100  100         (40)     (8)  (0)   6 2.24 23  8.96     20  100 35   55 95  100         (80)     (36)  (5)   6 2.24 23  8.96     50  100 35   50 95  100         (50)     (30)  (5)   6 2.24 23  8.96    55   95 50   55 100    95         (42)     (9)  (0)   6 2.24 23  8.96      90   95 100  100          (5)  (0)   6     2.24 23  8.96      35   75 100  100          (53)  (0)   6 2.24 23  8.96         60   95 30   65 100   95         (36)  (53)  (0)   6 2.24 23  8.96        95   95 100  100          (0)  (0)   6 2.24 23  8.96      45   80 100      100          (43)  (0)   62.24 23  8.96     55   50 100  100     (0)  (0)   6 2.24 23  8.96     35   95 45   50 100   95         (63)     (10)  (0)   6 2.24 23  8.96      20   85 100  100          (76)  (0)   6     2.24 23  8.96      60   80 100  100          (25)  (0)   6 2.24 23  8.96          40   80 100  100          (50)  (0)   6 2.24 23  8.96     80   90     20   75 95  100         (11)  (73)  (5)   6 2.24 23  8.96      25   55     100  100          (54)  (0)    6 2.24 23  8.96     45  100 65   80 100     100         (55)  (18)  (0)   6 2.24 23  8.96     25  100 50   90 100     100         (75)  (44)  (0)   6 2.24 23  8.96     30   88         (65)     6 2.24 23  8.96      40   40          (0)   6 2.24 23  8.96     40  100     55   90 100  100         (60)  (38)  (0)   6 2.24 23  8.96     10  100     60   70 100  100         (90)  (14)  (0)   6 2.24 23  8.96     25  100     40   90 100  100         (75)  (55)  (0)   6 2.24 23  8.96     15  100     50   95 100  100         (85)  (47)  (0)   6 4.48 23  8.96     60   95     70  100 100  100         (36)  (30)  (0)   6 0.56 24  2.24      15   30     90   95          (50)  (5)   6 0.56 24  2.24     10   10 25   0 85    95             (0)  (0)  (10)   6 0.56 24  2.24      30   20          (0)   6     0.56 24  8.96      10   30 95    95          (66)  (0)   6 0.56 24  8.96         0   10 10   0 85   95         (100)  (0)  (10)   6 0.56 24  8.96      15   20          (25)   6 2.24 24  0.56     95   93         (0)   6     2.24 24  2.24      30   50 95  100          (40)  (5)   6 2.24 24  2.24        10   80 0   0 95  100         (87)  (0)  (5)   6 2.24 24  2.24     40   55          (27)   6 2.24 24  2.24     70   93         (24)   6     2.24 24  8.96      35   50 95  100          (30)  (5)   6 2.24 24  8.96        15   80 0   0 90  100         (81)  (0)  (10)   6 2.24 24  8.96     15   55          (72)   6 2.24 24  8.96     35   93         (62)   6     0.56 25  2.24     20   80 0   35 100  100         (75)  (100)  (0)   6     0.56 25  8.96     10   80 0   35 100  100         (87)  (100)  (0)   6     2.24 25  2.24     70  100 10   60 100  100         (30)  (83)  (0)   6     2.24 25  8.96     25  100 20   60 100  100         (75)  (66)  (0)   6     0.56 27  2.24     50  100 60   80 100   95         (50)  (25)  (0)   6     0.56 27  8.96     15  100 25   80 100   95         (85)  (68)  (0)   6     2.24 27  2.24     15  100 80   90 100  100         (85)  (11)  (0)   6     2.24 27  8.96     5  100 30   90 100  100         (95)  (66)  (0)   6     0.56 28  2.24      10   20          (50)   6 0.56 28  8.96      15   20             (25)   6 2.24 28  0.56     75   93         (19)   6 2.24 28     2.24     75   93         (19)   6 2.24 28  2.24      30   55     (45)   6 2.24 28  8.96     30   93         (67)   6 2.24 28  8.96     40   55          (27)   6 0.56 29  2.24     60  100 15    75 100  100          (40)  (80)  (0)   6 0.56 29  8.96     35  100 85   75 100  100        (65)  (0)  (0)   6 2.24 29  2.24     70  100 95  100 100  100     (30)  (5)  (0)   6 2.24 29  8.96     80  100 50  100 100  100     (20)  (50)  (0)   6 0.56 30  2.24      15   20          (25)   6 0.56 30      2.24      35   75 100  100          (53)  (0)   6 0.56 30  8.96      30       20          (0)   6 0.56 30  8.96      25   75 100  100          (66)     (0)   6 2.24 30  0.56     85   93         (8)   6 2.24 30  2.24     55     93         (40)   6 2.24 30  2.24      60   90 100  100          (33)     (0)   6 2.24 30  2.24      50   55          (9)   6 2.24 30  8.96     75   90 100  100          (16)  (0)   6 2.24 30  8.96      30   55        (45)   6 2.24 30   8.96     45   93         (51)   6 0.56 31  2.24       20   20          (0)   6 0.56 31  8.96      25   20          (0)   6     2.24 31  0.56     95   93         (0)   6 2.24 31  2.24      45   55          (18)   6 2.24 31  2.24     85   93         (8)   6 2.24 31  8.96      80   93         (13)   6 2.24 31  8.96      25   55          (54)   6     0.56 32   2.24     5   95  90  100         (94)   (10)   6 0.56 32  8.96         5   95  100  100         (94)   (0)   6 2.24 32  2.24      70   80     100  100          (12)  (0)   6 2.24 32  2.24     50   95  100  100        (47)   (0)   6 2.24 32  8.96     20   95  100  100         (78)   (0)       6 2.24 32  8.96      65   80 100  100          (18)  (0)   6 0.56 33     2.24      30   48          (37)   6 0.56 33  2.24     25   90  95  100           (72)   (5)   6 0.56 33  2.24     25   88         (71)   6 0.56 33     8.96      5   48          (89)   6 0.56 33  8.96     20   88     (77)   6 0.56 33  8.96     25   90  90  100         (72)   (10)   6 2.24     33  2.24     35   95  100  100         (63)   (0)   6 2.24 33  2.24     70   75          (6)    6 2.24 33  2.24     50   98         (48)   6     2.24 33  8.96      50   75          (33)   6 2.24 33  8.96     20   95     100  100         (78)   (0)   6 2.24 33  8.96     20   98         (79)     6 0.56 34  2.24     20   90  95  100         (77)   (5)   6 0.56 34     2.24     20   88         (77)   6 0.56 34  2.24      5   48     (89)   6 0.56 34  8.96     0    88         (100)   6 0.56 34  8.96     0       90  90  100         (100)   (10)   6 0.56 34  8.96      35   48       (27)   6 2.24 34  2.24     70   98         (28)   6 2.24 34  2.24     40   75          (46)   6 2.24 34  2.24     40   95  100  100     (57)   (0)   6 2.24 34  8.96     45   95  100  100         (52)   (0)     6 2.24 34  8.96      30   75          (60)   6 2.24 34  8.96     25   98             (74)   6 0.56 35  2.24      5   25 100  100          (80)  (0)     6 0.56 35  2.24     20   85  95  100         (76)   (5)   6 0.56 35     2.24      20   45 100  100          (55)  (0)   6 0.56 35  8.96      5     45 100  100          (88)  (0)   6 0.56 35  8.96     0   85  95  100         (100)   (5)   6 0.56 35  8.96      15   25 100  100          (40)     (0)   6 2.24 35  2.24      75   75 100  100          (0)  (0)   6 2.24     35  2.24     35   95  100  100         (63)   (0)   6 2.24 35  2.24     40   80 100  100         (50)  (0)   6 2.24 35  8.96      30   80 100     100          (62)  (0)   6 2.24 35  8.96     10   95  100  100     (89)   (0)   6 2.24 35  8.96      15   75 100  100          (80)  (0)     9 0.28 1 8.96  20   20   0   50 0   10  0   0      (0)    (100)  (100)     (0)   9 1.12 1 8.96  50   50   30   60 10   40  25   20      (0)    (50)      (75)   (0)   9 4.48 1 8.96  60   70   35   90 50   75  25   60     (14)    (61)  (33)   (58)   9 0.28 9 8.96  10   20   15   50 0   10  10      0      (50)    (70)  (100)   (0)   9 1.12 9 8.96  50   50   50   60 10      40  20   20      (0)    (16)   (75)   (0)   9 4.48 9 8.96  70   70   75       90 80   75  20   60      (0)    (16)  (0)   (66)   9 0.28 11  8.96  40       20   35   50 20   10  10   0      (0)    (30)  (0)   (0)   9 1.12 11     8.96  50   50   25   60 20   40  20   20      (0)    (58)  (50)   (0)     9 4.48 11  8.96  60   70   75   90 80   75  10   60      (14)    (16)     (0)   (83)  10 1.12 1 2.24  10   55       100  100      (81)        (0)     10 1.12 1 2.24  35   50       100  100      (30)        (0)  10 1.12 1     2.24  25   40       95  100      (37)        (5)  10 1.12 1 2.24  85     55       100  100      (0)        (0)  10 1.12 1 2.24  5   65       100     100      (92)        (0)  10 1.12 1 2.24  35   65       100  100     (46)        (0)  10 1.12 1 2.24  85   75       100  100      (0)     (0)  10 1.12 1 2.24  20   45       95  100      (55)        (5)  10 1.12     1 2.24  25   85       95  100      (70)        (5)  10 1.12 1 2.24  25     70       100  100      (64)        (0)  10 1.12 1 2.24  30   43     (30)  10 1.12 1 2.24  20   18      (0)  10 1.12 1 8.96  0   30       75      99      (100)        (24)  10 1.12 1 8.96  15   18      (16)  10 1.12 1     8.96  0   70       75  100      (100)        (25)  10 1.12 1 8.96  35     75       100  100      (53)        (0)  10 1.12 1 8.96  10   85     100  100      (88)        (0)  10 1.12 1 8.96  0   30       70   98     (100)        (28)  10 1.12 1 8.96  30   60       20  100      (50)      (80)  10 1.12 1 8.96  10   65       100  100      (84)        (0)  10     1.12 1 8.96  10   30       100   100      (66)        (0)  10 1.12 1     8.96  10   43      (76)  10 1.12 1 8.96  25   60       100  100     (58)        (0)  10 1.12 18.96  5   50       100  100      (90)     (0)  10 1.12 1 8.96  0   45       85  100      (100)        (15)  10     1.12 1 8.96  20   20       90   95      (0)        (5)  10 1.12 1 8.96     20   70       85  100      (71)        (15)  10 1.12 1 8.96  10   35       99   99      (71)        (0)  10 1.12 1 8.96  20   55       80  100       (63)        (20)  10 1.12 1 8.96  5   40       80  100      (87)      (20)  10 1.12 1 8.96  15   65       100  100      (76)        (0)  10     1.12 1 8.96  5   55       100  100      (90)        (0)  10 2.24 1 8.96     10   50       100  100      (80)        (0)  10 2.24 1 8.96  15   50       99   99      (70)        (0)  10 2.24 1 8.96  40   70       30   95       (42)        (68)  10 2.24 1 8.96  20   50       90   99      (60)       (9)  10 2.24 1 8.96  10   80       80  100      (87)        (20)  10     2.24 1 8.96  0   60       100  100      (100)        (0)  10 2.24 1 8.96      15   45       99   99      (66)        (0)  10 2.24 1 8.96  35   60       100  100      (41)        (0)  10 2.24 1 8.96  20   50       95   98        (60)        (3)  10 2.24 1 8.96  0   70       100  100      (100)        (0)  10 4.48 1 2.24  35   90       100  100      (61)        (0)  10     4.48 1 2.24  40   80       100  100      (50)        (0)  10 4.48 1 2.24      60   85       100  100      (29)        (0)  10 4.48 1 2.24  40   80        100  100      (50)        (0)  10 4.48 1 2.24  55   95       100  100          (42)        (0)  10 4.48 1 2.24  15   80       100  100      (81)          (0)  10 4.48 1 2.24  40   67      (40)  10 4.48 1 2.24  30   58      (48)  10 4.48 1 2.24  35   95       100  100      (63)        (0)  10     4.48 1 2.24  15   85       100  100      (82)        (0)  10 4.48 1 2.24      40   90       100  100      (55)        (0)  10 4.48 1 2.24  95   90        100  100      (0)        (0)  10 4.48 1 8.96  30   85       100  100         (64)        (0)  10 4.48 1 8.96  15   95       100  100      (84)         (0)  10 4.48 1 8.96  10   67      (85)  10 4.48 1 8.96  30   65      99   99      (53)        (0)  10 4.48 1 8.96  5   58      (91)  10 4.48     1 8.96  65   100       35  100      (35)        (65)  10 4.48 1 8.96  20       90       100  100      (77)        (0)  10 4.48 1 8.96  50   75     100  100      (33)        (0)  10 4.48 1 8.96  35   90       100  100       (61)        (0)  10 4.48 1 8.96  15   75       100  100      (80)       (0)  10 4.48 1 8.96  10   85       100  100      (88)        (0)  10     4.48 1 8.96  60   80       100  100      (25)        (0)  10 4.48 1 8.96      20   80       100  100      (75)        (0)  10 4.48 1 8.96  15   70        99  100      (78)        (1)  10 4.48 1 8.96  20   80       100  100         (75)        (0)  10 4.48 1 8.96  25   80       100  100      (68)         (0)  10 4.48 1 8.96  25   75       99   99      (66)        (0)  10     4.48 1 8.96  90   95       100  100      (5)        (0)  10 4.48 1 8.96     35   75       100   99      (53)        (0)  10 4.48 1 8.96  20   80       100  100      (75)        (0)  10 4.48 1 8.96  50   80       100  100         (37)        (0)  10 4.48 18.96  60   90       100  100      (33)        (0)  10 6.72 1 8.96  20   95       100  100      (78)        (0)  10     6.72 1 8.96  35   80       100  100      (56)        (0)  10 6.72 1 8.96      30   95       100  100      (68)        (0)  10 6.72 1 8.96  30   95        100  100      (68)        (0)  10 6.72 1 8.96  25   85       100  100          (70)        (0)  10 6.72 1 8.96  40   90       100  100      (55)          (0)  10 6.72 1 8.96  15   95       100  100      (84)        (0)     10 6.72 1 8.96  75   70       75  100      (0)        (25)  10 6.72 1     8.96  30   80       100   99      (62)        (0)  10 6.72 1 8.96  75     90       100  100      (16)        (0)  10 8.96 1 8.96  35   90     100  100      (61)        (0)  10 8.96 1 8.96  35   98       100  100       (64)        (0)  10 1.12 3 2.24  10   43      (76)  10 1.12 3 2.24  20       18      (0)  10 1.12 3 8.96  0   18      (100)  10 1.12 3 8.96  15     43      (65)  10 4.48 3 0.56  50   80       100  100      (37)     (0)  10 4.48 3 2.24  25   80       100  100      (68)        (0)  10     4.48 3 2.24  25   58      (56)  10 4.48 3 2.24  25   67      (62)  10     4.48 3 4.48  30   80       100  100      (62)        (0)  10 4.48 3 8.96      0   58      (100)  10 4.48 3 8.96  10   67      (85)  10 1.12 4 2.24     10   13      (23)  10 1.12 4 8.96  15    13      (0)  10 3.36 4 2.24  65       72      (9)  10 3.36 4 8.96  25   72      (65)  10 4.48 4 2.24  20     40      (50)  10 4.48 4 8.96  25   40      (37)  10 6.72 4 2.24  80   95          (15)  10 6.72 4 8.96  60   95      (36)  10 1.12 6 8.96  0   30       99  100      (100)        (1)  10 2.24 6 8.96  0   50       100  100        (100)        (0)  10 4.48 6 8.96  10   80       100  100      (87)         (0)  10 6.72 6 8.96  10   95       100  100      (89)        (0)  10     1.12 7 2.24  15   43      (65)  10 1.12 7 2.24  15   18      (16)  10     1.12 7 8.96  30   43      (30)  10 1.12 78.96  15   18      (16)  10     1.12 78.96  0   30       99  100      (100)        (1)  10 2.24 7 8.96     10   50       100  100      (80)        (0)  10 4.48 7 2.24  40   58      (31)  10 4.48 7 2.24  45   67      (32)  10 4.48 7 8.96  15   58     (74)  10 4.48 7 8.96  25   80       100  100      (68)        (0)  10     4.48 7 8.96  25   67      (62)  10 6.72 7 8.96  60   95       100  100        (36)        (0)  10 1.12 9 2.24  25   43      (41)  10 1.12 9 2.24     20   18      (0)  10 1.12 9 8.96  30   30       80  100      (0)     (20)  10 1.12 9 8.96  35   43      (18)  10 1.12 9 8.96  15   18     (16)  10 2.24 9 8.96  10    50       100  100      (80)        (0)  10     4.48 9 2.24  25   67      (62)  10 4.48 9 2.24  15   58      (74)  10     4.48 9 8.96  25   67      (62)  10 4.48 9 8.96  15   58      (74)  10     4.48 9 8.96  20   80       100  100      (75)        (0)  10 6.72 9 8.96      20   95       100  100      (78)        (0)  10 3.36 10  2.24  45   87         (48)  10 3.36 10  8.96  45   87      (48)  10 6.72 10  2.24  70   90          (22)  10 6.72 10  8.96  45   90      (50)  10 1.12 11  8.96  10     30       100  100      (66)        (0)  10 2.24 11  8.96  40   50     100  100      (20)        (0)  10 4.48 11  8.96  50   80       100  100         (37)        (0)  10 6.72 11  8.96  75   95       100  100      (21)           (0)  10 1.12 12  2.24  5   18      (72)  10 1.12 12  2.24  20   43          (53)  10 1.12 12  8.96  0   30       100  100      (100)        (0)      10 1.12 12  8.96  15   18      (16)  10 1.12 12  8.96  15   43     (65)  10 2.24 12  8.96  0   50       100  100      (100)        (0)  10     4.48 12  2.24  25   58      (56)  10 4.48 12  2.24  10   67      (85)     10 4.48 12  8.96  0   58      (100)  10 4.48 12  8.96  30   80       100      100      (62)        (0)  10 4.48 12  8.96  30   67      (55)  10 6.72     12  8.96  50   95       100  100      (47)        (0)  10 1.12 13  8.96     10   70       70  100      (85)        (30)  10 2.24 13  8.96  20   80         95  100      (75)        (5)  10 4.48 13  8.96  30   80       100     100      (62)        (0)  10 6.72 13  8.96  50   90       100  100     (44)        (0)  10 1.12 14  2.24  10   43      (76)  10 1.12 14  2.24     0   18      (100)  10 1.12 14  8.96  15   70       100  100      (78)         (0)  10 1.12 14  8.96  0   43      (100)  10 1.12 14  8.96  10   18         (44)  10 2.24 14  8.96  40   80       100  100      (50)        (0)     10 4.48 14  2.24  5   58      (91)  10 4.48 14  2.24  30   67      (55)     10 4.48 14  8.96  5   58      (91)  10 4.48 14  8.96  60   80       100     100      (25)        (0)  10 4.48 14  8.96  45   67      (32)  10 6.72     14  8.96  70   90       100  100      (22)        (0)  10 1.12 16  2.24     20   43      (53)  10 1.12 16  2.24  5   18      (72)  10 1.12 16  8.96     25   43      (41)  10 1.12 16  8.96  25   18      (0)  10 1.12 16  8.96     0   70       70  100      (100)        (30)  10 2.24 16  8.96  0   80        90  100      (100)        (10)  10 4.48 16  2.24  55   67      (17)     10 4.48 16  2.24  15    58      (74)  10 4.48 16  8.96  25   58     (56)  10 4.48 16  8.96  30   67      (55)  10 4.48 16  8.96  10   80       100  100      (87)        (0)  10 6.72 16  8.96  30   90       100     100      (66)        (0)  10 1.12 19  2.24  5   13      (61)  10 1.12 19      8.96  10   13      (23)  10 3.36 19  2.24  45   72      (37)  10 3.36     19  8.96  5   72      (93)  10 4.48 19  2.24  15   40      (62)  10 4.48     19   8.96  15   40      (62)  10 6.72 19  2.24  70   95      (26)  10     6.72 19  8.96  20   95      (78)  10 1.12 20 2.24  5   13      (61)  10     1.12 20  8.96  5   13      (61)  10 3.36 20  2.24  80   72      (0)  10     3.36 20  8.96  65   72      (9)  10 4.48 20  2.24  5   40      (87)  10     4.48 20  8.96  40   40      (0)  10 6.72 20  2.24  80   95      (15)  10     6.72 20  8.96  60   95      (36)  10 1.12 21  8.96  0   60       80     100      (100)        (20)  10 2.24 21  8.96  0   70       100   95     (100)        (0)  10 4.48 21  8.96  10  100       90  100      (90)       (10)  10 6.72 21  8.96  0   70       100  100      (100)        (0)     10 1.12 22  2.24  23   30      100  100      (23)        (0)  10 1.12 22      8.96  0   60       90  100      (100)        (10)  10 1.12 22  8.96  20       30       85  100      (33)        (15)  10 2.24 22  8.96  10   70      95   95      (85)        (0)  10 3.36 22  2.24  25   63      (60)  10     3.36 22  8.96  15   63      (76)  10 4.48 22  0.56  55   48      (0)  10     4.48 22  2.24  20   48      (58)  10 4.48 22  2.24  25   53       100     98      (52)        (0)  10 4.48 22  8.96  13   53       100   98     (75)        (0)  10 4.48 22  8.96  0    48      (100)  10 4.48 22  8.96     20  100       100  100      (80)        (0)  10 6.72 22  2.24  70   88        (20)  10 6.72 22  8.96  10   88      (88)  10 6.72 22  8.96  0   70         100  100      (100)        (0)  10 1.12 23  2.24  25   43      (41)     10 1.12 23  2.24  20   18      (0)  10 1.12 23  8.96  25   43      (41)     10 1.12 23  8.96  10   18      (44)  10 4.48 23  2.24  60   67      (10)      10 4.48 23  2.24  35   58      (39)  10 4.48 23  8.96  25   58     (56)  10 4.48 23  8.96  20   67      (70)  10 1.12 24  0.56  20   30       95  100      (33)        (5)  10 1.12 24  0.56  10   35       100  100          (71)        (0)  10 1.12 24  0.56  35   70       100  100      (50)            (0)  10 1.12 24  0.56  5   50       100  100      (90)        (0)      10 1.12 24  0.56  40   50       100   100      (20)        (0)  10 1.12     24  0.56  0   25       95   95      (100)        (0)  10 1.12 24  0.56     5   25       100  100      (80)        (0)  10 1.12 24  0.56  25   10        100  100      (0)       (0)  10 1.12 24  0.56  0   35       95  100        (100)        (5)  10 1.12 24  0.56  5   15       100  100      (66)          (0)  10 1.12 24  0.56  10   40       100  100      (75)        (0)     10 1.12 24  2.24  5   30       95  100      (83)        (5)  10 1.12 24     2.24  13   30       100  100      (56)        (0)  10 1.12 24  2.24  10      35       100  100      (71)        (0)  10 1.12 24  2.24  60   50     100  100      (0)        (0)  10 1.12 24  2.24  0   45       90  100      (100)        (10)  10 1.12 24  2.24  20    35       100  100      (42)           (0)  10 1.12 24  2.24  5   15       100  100      (66)        (0)     10 1.12 24  2.24  20   50       95  100      (60)        (5)  10 1.12 24      2.24  0   10       100  100      (100)        (0)  10 1.12 24  2.24  15       25       100  100      (40)        (0)  10 1.12 24  2.24  20   70      95  100      (71)        (5)  10 1.12 24  2.24  0   43      (100)  10     1.12 24  2.24  20   40       95  100      (50)        (5)  10 1.12 24     2.24  15   25       95   95      (40)        (0)  10 1.12 24  8.96  5     45       90  100      (88)        (10)  10 1.12 24  8.96  25   35     90  100      (28)        (10)  10 1.12 24  8.96  45   30      90  100       (0)        (10)  10 1.12 24  8.96  18   30       100  100      (40)         (0)  10 1.12 24  8.96  30   50       100  100      (40)        (0)     10 1.12 24  8.96  10   10       90  100      (0)        (10)  10 1.12 24      8.96  15   25       40   95      (40)        (57)  10 1.12 24  8.96  35       35       95  100      (0)        (5)  10 1.12 24  8.96  35   40     90  100      (12)        (10)  10 1.12 24  8.96  15   25       90  100        (40)        (10)  10 1.12 24  8.96  15   15       95  100      (0)         (5)  10 1.12 24  8.96  20   50       95  100      (60)        (5)     10 1.12 24  8.96  20   43      (53)  10 1.12 24  8.96  25   70       90     100      (64)        (10)  10 3.36 24  2.24  5   63      (92)  10 3.36     24  2.24  15   72      (79)  10 3.36 24  8.96  0   72      (100)  10     3.36 24  8.96  10   63      (84)  10 4.48 24  0.56  30   80       100     100      (62)        (0)  10 4.48 24  0.56  40   95       100  100     (57)        (0)  10 4.48 24  0.56  10   80       100  100      (87)       (0)  10 4.48 24  0.56  50   90       100  100      (44)        (0)  10     4.48 24  0.56  70   85       100  100      (17)        (0)  10 4.48 24     0.56  40   80       100  100      (50)        (0)  10 4.48 24  0.56  40      95       100  100      (57)        (0)  10 4.48 24  0.56  0   90     100  100      (100)        (0)  10 4.48 24  0.56  35   48      (27)  10     4.48 24  0.56  70   80       100  100      (12)        (0)  10 4.48 24     0.56  60   80       100  100      (25)        (0)  10 4.48 24  0.56  25      65       100  100      (61)        (0)  10 4.48 24   0.56  60   80      100  100      (25)        (0)  10 4.48 24  0.56  25   90       100  100          (72)        (0)  10 4.48 24  0.56  35   60       100  100      (41)            (0)  10 4.48 24  2.24  40   85       100  100      (52)     (0)  10 4.48 24  2.24  40   95      100  100      (57)        (0)  10     4.48 24  2.24  25   80       100  100      (68)        (0)  10 4.48 24     2.24  5   85       100  100      (94)       (0)  10 4.48 24  2.24  30     53       100   98      (43)        (0)  10 4.48 24  2.24  5   80     100  100      (93)        (0)  10 4.48 24  2.24  50   90       100  100         (44)        (0)  10 4.48 24  2.24  10   67      (85)  10 4.48 24     2.24  60   90       100  100      (33)        (0)  10 4.48 24  2.24  15      90       100  100      (83)        (0)  10 4.48 24  2.24  30   80     100  100      (62)        (0)  10 4.48 24  2.24  10   80       100  100         (87)        (0)  10 4.48 24  2.24  20   80       100  100      (75)           (0)  10 4.48 24  2.24  10   48      (79)  10 4.48 24  2.24  5   60           100  100      (91)        (0)  10 4.48 24  2.24  45   80       100      100      (43)        (0)  10 4.48 24  2.24  35   95       100  100     (63)        (0)  10 4.48 24  2.24  25   65       100  100      (61)       (0)  10 4.48 24  4.48  10   80       95  100      (87)        (5)  10     4.48 24  8.96  15   80       100  100      (81)        (0)  10 4.48 24     8.96  45   80       100  100      (43)        (0)  10 4.48 24  8.96  60      85       100  100      (29)        (0)  10 4.48 24  8.96  10   85     100  100      (88)        (0)  10 4.48 24  8.96  30   95       100  100         (68)        (0)  10 4.48 24  8.96  25   53       100   98      (52)          (0)  10 4.48 24  8.96  40   65       100  100      (38)        (0)     10 4.48 24  8.96  10   80       100  100      (87)        (0)  10 4.48     24  8.96  25   90       100   100      (72)        (0)  10 4.48 24  8.96      35   95       95  100      (63)        (5)  10 4.48 24  8.96  30   80         100  100      (62)        (0)  10 4.48 24  8.96  0   60       100     100      (100)        (0)  10 4.48 24  8.96  55   90       100  100     (38)        (0)  10 4.48 24  8.96  30   80       100  100      (62)       (0)  10 4.48 24  8.96  20   48      (58)  10 4.48 24  8.96  35   90        100  100      (61)        (0)  10 4.48 24  8.96  0   67      (100)     10 6.72 24  2.24  30   88      (65)  10 6.72 24  2.24  25   95      (73)      10 6.72 24  8.96  15   95      (84)  10 6.72 24  8.96  5   88      (94)      10 1.12 25  2.24  25   70       100  100      (64)        (0)  10 1.12     25  8.96  10   70       50  100      (85)        (50)  10 4.48 25  2.24     35   90       100  100      (61)        (0)  10 4.48 25  8.96  15   90         100  100      (83)        (0)  10 1.12 26  2.24  5   55       100     100      (90)        (0)  10 1.12 26  8.96  20   55       95  100     (63)        (5)  10 4.48 26  2.24  10   80       100  100      (87)       (0)  10 4.48 26  8.96  10   80       100  100      (87)        (0)  10     1.12 27  2.24  20   55       100  100      (63)        (0)  10 1.12 27     8.96  25   55       85  100      (54)        (15)  10 4.48 27  2.24  20      80       100  100      (75)        (0)  10 4.48 27  8.96  5   80     100  100      (93)        (0)  10 1.12 28  2.24  10   45       100  100         (77)        (0)  10 1.12 28  8.96  15   45       100  100      (66)           (0)  10 3.36 28  2.24  5   63      (92)  10 3.36 28  8.96  5   63         (92)  10 4.48 28  0.56  20   48      (58)  10 4.48 28  2.24  20   95           100  100      (78)       (0)  10 4.48 28  2.24  10   48      (79)     10 4.48 28  8.96  20   48      (58)  10 4.48 28  8.96  25   95       100      100      (73)        (0)  10 6.72 28  2.24  30   88      (65)  10 6.72     28  8.96  15   88      (82)  10 1.12 29  2.24  15   45       100  100       (66)        (0)  10 1.12 29  8.96  75   45       100  100      (0)        (0)  10 4.48 29  2.24  30   95       100  100      (68)        (0)     10 4.48 29  8.96  45   95       100  100      (52)        (0)  10 1.12     30  2.24  25   60       100  100      (58)        (0)  10 1.12 30  8.96     40   60       100  100      (33)        (0)  10 3.36 30  2.24  20   63        (68)  10 3.36 30  8.96  20   63      (68)  10 4.48 30  0.56  25   48         (47)  10 4.48 30  2.24  30   80       100  100      (62)        (0)     10 4.48 30  2.24  20   48      (58)  10 4.48 30  8.96  10   48      (79)      10 4.48 30  8.96  60   80       100  100      (25)        (0)  10 6.72     30  2.24  15   88      (82)  10 6.72 30  8.96  15   88      (82)  10     3.36 31  2.24  5   63      (92)  10 3.36 31  8.96  10    63      (84)     10 4.48 31  0.56  20   48      (58)  10 4.48 31  2.24  20   48      (58)      10 4.48 31  8.96  25   48      (47)  10 6.72 31  2.24  20   88     (77)  10 6.72 31  8.96  10   88      (88)  10 1.1232  2.24  35   60      100  100      (41)        (0)  10 1.12 32  8.96  65   60       100  100          (0)        (0)  10 4.48 32  2.24  40   85       100  100      (52)           (0)  10 4.48 32  8.96  35   85       100  100      (58)        (0)      10 1.12 33  2.24  10   45       100  100      (77)        (0)  10 1.12     33  8.96  5   45       95  100      (88)        (5)  10 3.36 33  2.24     45   87      (48)  10 3.36 33  8.96  20   87      (77)  10 4.48 33  2.24      25   55       100  100      (54)        (0)  10 4.48 33  8.96  60   55          100  100      (0)        (0)  10 6.72 33  2.24  80   90      (11)     10 6.72 33  8.96  55   90      (38)  10 1.12 34  2.24  15   45       100      100      (66)        (0)  10 1.12 34  8.96  10   45       100  100     (77)        (0)  10 3.36 34  2.24  25   87      (71)  10 3.36 34  8.96     10   87      (88)  10 4.48 34  2.24  10   55       100  100      (81)         (0)  10 4.48 34  8.96  20   55       100  100      (63)        (0)     10 6.72 34  2.24  70   90      (22)  10 6.72 34  8.96  5   90      (94)     10 1.12 35  2.24  35   95       100  100      (63)        (0)  10 1.12     35  8.96  15   95       100  100      (84)        (0)  10 4.48 35  2.24     20   95      100  100      (78)        (0)  10 4.48 35  8.96  30   95        100  100      (68)        (0)  10 1.12 36  0.56  5   15       100     100      (66)        (0)  10 1.12 36  0.56  40   50       100  100     (20)        (0)  10 1.12 36  2.24  5   15       100  100      (66)      (0)  10 1.12 36  2.24  90   50       95  100      (0)        (5)  10     1.12 36  8.96  5   15       100  100      (66)        (0)  10 1.12 36     8.96  20   50       95  100      (60)        (5)  10 4.48 36  0.56  30     65       100  100      (53)        (0)  10 4.48 36  0.56  80   85     100  100      (5)        (0)  10 4.48 36  2.24  30   65       100  100        (53)        (0)  10 4.48 36  2.24  85   85       100  100      (0)         (0)  10 4.48 36  8.96  5   65       100  100      (92)        (0)     10 4.48 36  8.96  50   85       100  100      (41)        (0)  11 1.12 1     8.96 0   15         90   85     (100)          (0)  11 2.24 1 8.96 0     20         90   95     (100)          (5)  11 2.24 1 8.96 15   17      97   90     (11)          (0)  11 4.48 1 8.96 10   35         95  100       (71)          (5)  11 4.48 1 8.96 15   45         97  100     (66)          (3)  11 6.72 1 8.96 37   30         99  100     (0)          (1)     11 8.96 1 8.96 47    35         99  100    (0)          (1)  11 1.12 9     8.96 40   15         75   85     (0)          (11)  11 2.24 9 8.96 0     20         85   95     (100)          (10)  11 2.24 9 8.96 13   17       85   90     (23)          (5)  11 4.48 9 8.96 40   45         97  100        (11)          (3)  11 4.48 9 8.96 10   35         80  100     (71)           (20)  11 6.72 9 8.96 20   30         95  100     (33)          (5)      11 8.96 9 8.96 60   35         99  100     (0)          (1)  11 1.12 10      2.24 40   50    80   99   40   50     (20)     (19)    (20)  11 3.36 10      2.24 40   60    90  100   40   75     (33)     (10)    (46)  11 6.72 10      2.24 60   80    95  100   75   95     (25)     (5)    (21)  11 1.12 11     2.24 35   50    85   99   15   50     (30)     (14)    (70)  11 1.12 11     8.96 30   15         90   85     (0)          (0)  11 2.24 11  8.96 80     20         95   95     (0)          (0)  11 3.36 11  2.24 65   60    99     100   70   75     (0)     (1)    (6)  11 4.48 11  8.96 10   35     100  100     (71)          (0)  11 6.72 11  2.24 90   80    100  100     70   95     (0)     (0)    (26)  11 2.24 23  2.24 10   40       10   60     100   95  95   95     (75)        (83)  (0)   (0)  11 2.24 23  8.96 0     40       10   60 100   95  70   95     (100)        (83)  (0)   (26)  11     8.96 23  2.24 15   55       40   75 100  100  100  100     (72)     (46)  (0)   (0)  11 8.96 23  8.96 30   55       20   75 100  100  95     100     (45)        (73)  (0)   (5)  15 0.56 1 2.24      5   10     (50)  15 0.56 1 2.24       95  100 10   55 90   95           (5)  (81)     (5)  15 0.56 1 8.96      35   10          (0)  15 0.56 1 8.96       100     100 0   55 100   95           (0)  (100)  (0)  15 2.24 1 2.24       100     100 30   95 95   95           (0)  (68)  (0)  15 2.24 1 2.24      45     50          (10)  15 2.24 1 8.96       100  100 10   95 95   95      (0)  (89)  (0)  15 2.24 1 8.96      25   50          (50)  15 0.56 3     2.24      15   10          (0)  15 0.56 3 8.96      5   10          (50)      15 2.24 3 2.24      30   50          (40)  15 2.24 3 8.96      55   50             (0)  15 0.56 4 2.24      5   18          (72)  15 0.56 4 8.96       0   18          (100)  15 2.24 4 2.24      30   73          (58)  15     2.24 4 8.96      55   73          (24)  15 0.56 7 2.24      95   10         (0)  15 0.56 7 8.96      5   10          (50)  15 2.24 7 0.56 35     38        100  100     (7)         (0)  15 2.24 7 0.56 40   60     100  100     (33)         (0)  15 2.24 7 2.24 5   38        100  100     (86)         (0)  15 2.24 7 2.24      65   60          (0)  15 2.24 7     2.24 30    60        100  100     (50)         (0)  15 2.24 7 8.96     30   50          (40)  15 2.24 7 8.96 15   60        100  100     (75)           (0)  15 2.24 7 8.96 10   38        100  100     (73)         (0)     15 0.28 8 8.96       99   90 0   30 100   95           (0)  (100)  (0)     15 0.56 8 2.24       95   95 0   85 95   80           (0)  (100)  (0)     15 0.56 8 8.96       99   99 0   45 100  100           (0)  (100)  (0)     15 0.56 8 8.96       100   95 5   85 95   80           (0)  (94)  (0)     15 1.12 8 8.96       100   95 0   60 100  100           (0)  (100)  (0)     15 2.24 8 0.56 55   60        100  100     (8)         (0)  15 2.24 8     0.56 5   38        100  100     (86)         (0)  15 2.24 8 2.24     100  100 90   85 100  100           (0)  (0)  (0)  15 2.24 8 2.24 10     38        100  100     (73)         (0)  15 2.24 8 2.24 35   60     100  100     (41)         (0)  15 2.24 8 8.96       100  100 10   75 100      100           (0)  (86)  (0)  15 2.24 8 8.96 45   60        100  100      (25)         (0)  15 2.24 8 8.96 5   38        100  100     (86)      (0)  15 2.24 8 8.96       100  100 65   85 100  100           (0)  (23)      (0)  15 0.28 9 8.96       99   90 0   30 100   95           (0)  (100)     (0)  15 0.56 9 2.24      5   10          (50)  15 0.56 9 8.96      10     10          (0)  15 0.56 9 8.96       99   99 10   45 100  100     (0)  (77)  (0)  15 1.12 9 8.96       100   95 35   60 100  100     (0)  (41)  (0)  15 2.24 9 2.24      75   50          (0)  15 2.24 9 8.96           100  100 50   75 100  100           (0)  (33)  (0)  15 2.24 9 8.96          60   50          (0)  15 4.48 9 0.56 70   65       100   98     (0)             (0)  15 4.48 9 2.24 75   60        100   98     (0)         (0)     15 4.48 9 8.96 55   65        100   98     (15)         (0)  15 0.28 10     8.96       99   99 0   50 99  100           (0)  (100)  (1)  15 0.56 10     2.24      0   13          (100)  15 0.56 10  8.96       99   99 0   70     100  100           (0)  (100)  (0)  15 0.56 10  8.96      5   13      (61)  15 1.12 10  2.24 30   50    100  100   60   99     (40)     (0)      (39)  15 1.12 10  8.96       100  100 0   90 100  100          (0)     (100)  (0)  15 2.24 10  2.24      25   55          (54)  15 2.24 10     8.96      5   55          (90)  15 2.24 10  8.96       100  100 0   90     100  100           (0)  (100)  (0)  15 3.36 10  2.24 75   60    99  100      95   99     (0)    (1)    (4)  15 6.72 10  2.24 85   80    100  100     99   99     (0)     (90)    (0)  15 0.28 11  8.96       99   99 0   50     99  100           (0)  (100)  (1)  15 0.56 11  8.96       100   99 15     70 100  100           (0)  (78)  (0)  15 1.12 11  2.24 30   50    99     100   50   99     (40)     (1)    (49)  15 1.12 11  8.96       100  100     50   90 100  100           (0)  (44)  (0)  15 2.24 11  8.96       100     100 60   90 100  100           (0)  (33)  (0)  15 3.36 11  2.24 70   60       100  100   95   99     (0)     (0)    (4)  15 6.72 11  2.24 90   80     100  100   95   99     (0)     (0)    (4)  15 0.28 12  8.96       99     99 0   50 100  100           (0)  (100)  (0)  15 0.56 12  2.24      0     10          (100)  15 0.56 12  8.96      0   10          (100)  15 0.56     12 8.96       99   99 30   70 100  100           (0)  (57)  (0)  15 1.12     12  8.96       99  100 10   90 100  100           (1)  (88)  (0)  15     2.24 12  2.24      45   50          (10)  15 2.24 12  8.96      20   50             (60)  15 2.24 12  8.96       100  100 40   90 100  100     (0)  (55)  (0)  15 0.28 14  8.96       99   99 0   40 80   95     (0)  (100)  (15)  15 0.56 14  2.24      10   10          (0)  15 0.56 14      8.96      10   10          (0)  15 0.56 14 8.96       99   99 20   60     90   95           (0)  (66)  (5)  15 1.12 14  8.96       99  100 40   70     99   99           (1)  (42)  (0)  15 2.24 14  2.24      30   50     (40)  15 2.24 14  8.96       100  100 50   90 100  100           (0)     (44)  (0)  15 2.24 14  8.96      15   50          (70)  15 0.28 15  8.96           99   99 0   40 75   95           (0)  (100)  (21)  15 0.56 15     8.96       99   99 10   60 99   95           (0)  (83)  (0)  15 1.12 15     8.96       100  100 30   70 100   99           (0)  (57)  (0)  15 2.24     15  8.96       100   100 60   90 100  100           (0)  (33)  (0)  15     0.28 16  8.96       99   99 0   40 95   95           (0)  (100)  (0)  15     0.56 16  2.24      5   10          (50)  15 0.56 16  8.96      5   10           (50)  15 0.56 16  8.96       100   99 0   60 70   95           (0)      (100)  (26)  15 1.12 16  8.96       99  100 10   70 100   99     (1)  (85)  (0)  15 2.24 16  2.24     30    50          (40)  15 2.24 16     8.96      25   50          (50)  15 2.24 16  8.96       100  100 20   90     100  100           (0)  (77)  (0)  15 0.28 17  8.96       99   90 5   30     75   90           (0)  (83)  (16)  15 0.56 17  8.96       99   95 20     30 95   80           (0)  (33)  (0)  15 1.12 17  8.96       99   99 30     75 80   90           (0)  (60)  (11)  15 2.24 17  8.96       99   99 40      97 95   95           (0)  (58)  (0)  15 0.56 19  2.24      20   18         (0)  15 0.56 19  8.96      5   18          (72)  15 2.24 19  2.24       35   73          (52)  15 2.24 19  8.96      10   73          (86)  15     0.56 20  2.24      15   18          (16)  15 0.56 20  8.96      5   18            (72)  15 2.24 20  2.24      25   73          (65)  15 2.24 20     8.96      45   73          (38)  15 0.56 22  2.24      35   50     (30)  15 0.56 22  8.96      30   50          (40)  15 2.24 22  2.24     45   88          (48)  15 2.24 22  8.96      85   88          (3)  15     0.28 23  8.96       100  100 10   90 95  100           (0)  (88)  (5)     15 0.56 23  2.24      10   10          (0)  15 0.56 23  8.96       100     100 0   85 100  100           (0)  (100)  (0)  15 0.56 23  8.96      10      10          (0)  15 1.12 23  8.96       100  100 35   80 100   95         (0)  (56)  (0)  15 2.24 23  2.24      65   50          (0)  15 2.24     23  8.96       100  100 35   75 100  100           (0)  (53)  (0)  15     2.24 23  8.96      35   50          (30)  15 0.56 24  2.24      30   50             (40)  15 0.56 24  8.96      15   50          (70)  15 2.24 24     2.24      75   88          (14)  15 2.24 24  8.96      45   88     (48)  15 0.56 27  2.24       100  100 40   85 100  100           (0)     (52)  (0)  15 0.56 27  8.96       100  100 10   85 100  100     (0)  (88)  (0)  15 2.24 27  2.24       100  100 80   95 100  100       (0)  (15)  (0)  15 2.24 27  8.96       100  100 60   95 100  100         (0)  (36)  (0)  15 0.56 28  2.24     15   50          (50)  15 0.56     28  8.96      15   50          (70)  15 2.24 28  2.24      60   88        (31)  15 2.24 28  8.96      80   88          (9)  15 0.56 29  2.24        95  100 35   60 95  100           (5)  (41)  (5)  15 0.56 29  8.96        95  100 10   60 100  100           (5)  (83)  (0)  15 2.24 29  2.24     45   75      100  100  100  100     (40)       (0)   (0)  15 2.24 29     2.24       100  100 45   90 100  100           (0)  (50)  (0)  15 2.24     29  8.96 45   75      100  100  100  100     (40)       (0)   (0)  15     2.24 29  8.96       100  100 35   90 100  100           (0)  (61)  (0)     15 6.72 29  2.24 75   80      100  100  100  100     (6)      (0)   (0)     15 6.72 29  8.96 35   80      100  100  100  100     (56)       (0)     (0)  15 0.56 30  2.24      30   50          (40)  15 0.56 30  8.96     15   50          (70)  15 2.24 30  2.24      80   88          (9)  15     2.24 30  8.96      65   88          (26)  15 0.56 31  2.24      45   50             (10)  15 0.56 31  8.96      45   50          (10)  15 2.24 31     2.24      90   88          (0)  15 2.24 31  8.96      80   88     (9)  15 0.56 32  2.24        15   65 100  100            (76)  (0)  15     0.56 32  8.96        10   65 100  100            (84)  (0)  15 1.12 32     2.24 40   55        100   95     (27)         (0)  15 1.12 32  8.96 5     55        95   95     (90)         (0)  15 2.24 32  2.24 50   85     100  100     (41)         (0)  15 2.24 32  2.24        55   75 100  100               (26)  (0)  15 2.24 32  8.96        15   75 100  100     (80)  (0)  15 2.24 32  8.96 35   85        100  100     (58)         (0)      15 0.56 33  0.56      75   50 100  100          (0)  (0)  15 0.56 33     2.24        5   25 95  100            (80)  (5)  15 0.56 33  2.24     40   50 100  100          (20)  (0)  15 0.56 33  2.24      10   13        (23)  15 0.56 33  8.96      30   50 100  100          (40)  (0)  15     0.56 33  8.96        5   25 100  100            (80)  (0)  15 0.56 33     8.96      0   13          (100)  15 2.24 33  0.56      75   75 100  100             (0)  (0)  15 2.24 33  2.24      30   55          (45)  15 2.24     33  2.24        30   95 100  100            (68)  (0)  15 2.24 33  2.24         50   75 100  100          (33)  (0)  15 2.24 33  8.96       100  100     10   95           (0)  (89)  15 2.24 33  8.96      55   75 100  100         (26)  (0)  15 2.24 33  8.96      20   55          (63)  15 0.56 34     2.24      5   13          (61)  15 0.56 34  2.24        5   25 100  100               (80)  (0)  15 0.56 34  8.96        10   25 95  100     (60)  (5)  15 0.56 34  8.96      5   13          (61)  15 2.24 34  2.24     10   35        100  100     (71)         (0)  15 2.24 34  2.24      15     55          (72)  15 2.24 34  2.24        45   95 100  100     (52)  (0)  15 2.24 34  8.96      10   55          (81)  15 2.24 34  8.96            10   95 100  100            (89)  (0)  15 2.24 34  8.96 25   35          100  100     (28)         (0)  15 4.48 34  2.24 20   45        100     100     (55)         (0)  15 4.48 34  8.96 15   45        100  100     (66)         (0)  15 0.56 35  2.24        10   25 100  100     (60)  (0)  15 0.56 35  8.96        0   25 100  100            (100)  (0)      15 2.24 35  2.24        70   95 100  100            (26)  (0)  15 2.24     35  8.96        10    95 100  100            (89)  (0)  15 0.56 36  0.56            5   10 100  100            (50)  (0)  15 0.56 36  2.24        5     10 100  100            (50)  (0)  15 0.56 36  8.96        0   10 100     100            (100)  (0)  15 1.12 36  0.56 60   70        95   95     (14)         (0)  15 1.12 36  2.24 70   70        95   95     (0)      (0)  15 1.12 35  8.96 80   70        95   95     (0)         (0)  15     2.24 36  0.56        55   45 100  100            (0)  (0)  15 2.24 36     2.24        40   45 100  100            (11)  (0)  15 2.24 36  8.96       10   45 100  100            (77)  (0)  15 4.48 36  0.56 55   90     100  100     (38)         (0)  15 4.48 36  2.24 40   90        100  100        (55)         (0)  15 4.48 36  8.96 15   90        100  100     (83)           (0)  18 1.12 10  2.24 10   25    90  100   0   20     (60)     (10)    (100)  18 3.36 10  2.24 10   30    99  100   0   40     (66)     (1)    (100)  18 6.72 10  2.24 20   40    95  100   20   60     (50)     (5)    (66)  18 1.12 11  2.24 20   25    80  100   0   20     (20)     (20)    (100)  18 3.36 11  2.24 20   30    90  100   0   40     (33)      (10)    (100)  18 6.72 11  2.24 30   40    100  100   20   60     (25)        (0)    (66)  33 0.02 1 8.96  40   80   50   40 0   10  60   80     (50)    (0)  (100)   (25)  33 0.07 1 8.96  50   90   45   60 0   10   90       95      (44)    (25)  (100)   (5)  33 0.28 1 8.96  80   98   65   70     10   30  99   99      (18)    (7)  (66)   (0)

EXAMPLE 288

The following procedure was used to determine the interaction between aherbicide and antidote when the herbicide is topically applied to thesoil surface and the antidote is applied to crop seed. Crop plant seedwas treated with the antidote either by contacting the seed withantidote in powder form or by contacting the seed with a solution orsuspension of antidote compound dissolved or suspended in a suitablesolvent, typically methylene chloride or toluene. Relative amounts ofantidote compound and seed were used to provide an antidote-on-seedconcentration, on a percent weight/weight basis, of 0.13 wt. %.Containers were filled and compacted with fumigated silt loam type soilto a depth of about 1.3 cm from the top of the container. A firstcontainer was designated as an untreated control, a second container wasdesignated as a herbicide control, and a third container was designatedas a herbicide + antidote test container. Untreated crop seed was placedin the first and second containers. Antidote-treated crop seed wasplaced in the third container. Then, each of the second and thirdcontainers was filled and leveled with a cover layer of soil havingincorporated therein the selected herbicide at a pre-determinedconcentration. The first container was filled and leveled with soilcontaining no herbicide. All containers were given about 0.6 cm ofoverhead water to simulate an activating rainfall. The containers wereplaced on a greenhouse bench and sub-irrigated as required for theduration of the test. Plant response was observed about three weeksafter initial treatment. Results are set forth in Table V. Herbiciderate is given in kg/ha and antidote rate is given in percentweight/weight of antidote/seed.

                                      TABLE V                                     __________________________________________________________________________    % PLANT INHIBITION AND % SAFENING EFFECT ( )                                  HERBICIDE                                                                              ANTIDOTE                                                                              JOHNSON  GREEN    SORGHUM                                    (kg/ha)  wt. %   GRASS    FOXTAIL  GRAIN                                      NO. RATE NO. RATE                                                                              W     WO W     WO W    WO                                    __________________________________________________________________________     6  0.28 11  0.13                                                                               75    90                                                                               97    97                                                                              23    70                                                       (16)     (0)      (67)                                     6  1.12 11  0.13                                                                               95    99                                                                               99    99                                                                              45    85                                                        (4)     (0)      (47)                                     6  4.48 11  0.13                                                                              100   100                                                                              100   100                                                                              65    97                                                        (0)     (0)      (32)                                    11  0.28 11  0.13                                                                               99    99                                                                              100    99                                                                              60    95                                                        (0)     (0)      (36)                                    11  1.12 11  0.13                                                                              100   100                                                                              100   100                                                                              82    93                                                        (0)     (0)      (11)                                    11  4.48 11  0.13                                                                              100   100                                                                              100   100                                                                              92   100                                                        (0)     (0)      (8)                                     18  0.28 11  0.13                                                                               70    75                                                                               90    99                                                                              28    73                                                        (6)     (9)      (61)                                    18  1.12 11  0.13                                                                              100    99                                                                               99    99                                                                              70    97                                                        (0)     (0)      (27)                                    18  4.48 11  0.13                                                                              100    99                                                                              100    99                                                                              93    99                                                        (0)     (0)      (6)                                     34  0.28 11  0.13                                                                               30    50                                                                               95    60                                                                               0    5                                                        (40)     (0)     (100)                                    34  1.12 11  0.13                                                                               40    60                                                                               99    95                                                                              17    13                                                       (33)     (0)      (0)                                     34  4.48 11  0.13                                                                               80    90                                                                               99    99                                                                              20    30                                                       (11)     (0)      (33)                                    __________________________________________________________________________

EXAMPLE 289

The procedure of Example 285 was followed to determine the interactionbetween herbicide and antidote when both are incorporated in a soilcover layer before emergence of the crop species. In this series oftests, however, all containers were seeded with several weed species inaddition to crop seed. Results are reported in Table VI.

    TABLE VI       % PLANT INHIBITION AND % SAFENING EFFECT ( )    SORGHUM   GREEN DOWNY     WILD BARNYARD  HERBICIDE ANTIDOTE WHEAT GRAIN CORN SOYBEAN FOXTAIL BROME O     ATS GRASS RICE NO. RATE NO. RATE W WO W WO W WO W WO W WO W WO W WO W WO W      WO       12.24 11.12 65   50  99  99  0   0  30   15                      (0)      (0)    (0)    (0) 1 11.20  1 1.12  95   95   99   99  0   0  45   50        (0)    (0)    (0)   (10) 1 2.24 10 1.12  53   50  97   99  0   0  10      15       (0)    (2)    (0)   (33) 1 11.20 10 1.12 100   95  99   99  0      0  15   50       (0)    (0)    (0)   (70) 1 2.24 11 1.12  85   50  99     99  0   0  15   15       (0)    (0)    (0)    (0) 1 11.20 11 1.12  99     95  99   99 10   0  20   50       (0)    (0)    (0)   (60) 5 1.12  1     1.12  35   30  55   73 25   15  33   40       (0)   (24)    (0)   (17) 5     6.72  1 1.12  73   83  75   97 45   75  77   80       (12)   (22)     (40)    (3) 5 1.12 10 1.12  47   30  60   73 15   15  23   40       (0)      (17)    (0)   (42) 5 6.72 10 1.12  77   83  95   97 55   75  95   80        (7)    (2)    (26)    (0) 5 1.12 11 1.12  45   30  30   73 40   15     25   40       (0)   (58)    (0)   (37) 5 6.72 11 1.12  90   83  87   97     50   75  70   80       (0)   (10)    (33)   (12) 6 0.84 23 0.14  95   85              100  100  80   85  90   80       (0)             (0)    (5)     (0) 6 0.84 23 0.14  15   42          100  100  90   90  75   90     (64)             (0)    (0)    (16) 6 0.84 23 0.14  55   78           95       95 100   95 100  100       (29)             (0)    (0)    (0) 6 0.84     23 0.14  18   35          100  100 100   90  90   90       (48)        (0)    (0)    (0) 6 0.84 23 0.14  78   50          100  100 100   95     95  100       (0)             (0)    (0)    (5) 6 0.84 23 0.14  73   75             100  100 100   98  98   95       (2)             (0)    (0)     (0) 6 0.84 23 0.28  65    30           95   95  95   90  80   85     (0)             (0)    (0)    (5) 6 0.84 23 0.56  15   42          100     100 100   90  70   90       (64)             (0)    (0)    (22) 6 0.84     23 0.56  45   78           95   95 100   95 100  100       (42)        (0)    (0)    (0) 6 0.84 23 0.56  65   85          100  100  95   85     95   80       (23)             (0)    (0)    (0) 6 0.84 23 0.56  33   35              100  100 100   90  65   90       (5)             (0)    (0)     (27) 6 0.84 23 0.56  18   50          100  100 100   95  98  100     (64)             (0)    (0)    (2) 6 0.84 23 0.56  85   75          100     100  95   98  95   95       (0)             (0)    (3)    (0) 6 0.84 23     0.84  45   30          100   95  95   90  70   85       (0)     (0)    (0)    (17) 6 0.84 23 2.24  65   85          100  100  90   85     70   80       (23)             (0)    (0)    (12) 6 0.84 23 2.24  42     42          100  100  90   90  50   90       (0)             (0)    (0)       (44) 6 0.84 23 2.24  48   75          100  100  98   98  95   95     (36)             (0)    (0)    (0) 6 0.84 23 2.24  43   50          100     100 100   95  90  100       (14)             (0)    (0)    (10) 6 0.84     23 2.24  35   78           95   95 100   95  95  100       (55)        (0)    (0)    (5) 6 0.84 23 2.24  15   35          100  100  95   90     60   90       (57)             (0)    (0)    (33) 6 0.84 23 2.24  15     30           95   95  95   90  50   85       (50)             (0)    (0)        (41) 6 1.68 23 0.14  90   90          100  100 100  100 100  100      (0)             (0)    (0)    (0) 6 1.68 23 0.14  90   73          100      95 100   95 100  100       (0)             (0)    (0)    (0) 6 1.68 23     0.14  40   75          100  100  95  100  90  100       (46)     (0)    (5)    (10) 6 1.68 23 0.14  55   55          100  100 100   95     90   95       (0)             (0)    (0)    (5) 6 1.68 23 0.14  83   90             100  100  95  100 100  100       (7)             (0)    (5)     (0) 6 1.68 23 0.14  80   85          100  100  95   85  95   90     (5)             (0)    (0)    (0) 6 1.68 23 0.14  92   82           95     100  95   95  90   90       (0)             (5)    (0)    (0) 6 1.68 23     0.56  95   85          100  100  90   85 100   90       (0)     (0)    (0)    (0) 6 1.68 23 0.56  65   73          100   95  95   95  95      100       (10)             (0)    (0)    (5) 6 1.68 23 0.56  88   90           100  100 100  100 100  100       (2)             (0)    (0)    (0)     6 1.68 23 0.56  35   75          100  100 100  100  90  100       (53)               (0)    (0)    (10) 6 1.68 23 0.56  70   55          100  100     95   95  90   95       (0)             (0)    (0)    (5) 6 1.68 23 0.56     80   90          100  100 100  100 100  100       (11)             (0)      (0)    (0) 6 1.68 23 0.84  58   82          100  100  78   95  90   90          (29)             (0)    (17)    (0) 6 1.68 23 2.24  63   90      100  100 100  100  95  100       (30)             (0)    (0)    (5) 6     1.68 23 2.24  80   85          100  100  90   85  95   90       (5)            (0)    (0)    (0) 6 1.68 23 2.24  15   75          100  100 100     100  80  100       (80)             (0)    (0)    (20) 6 1.68 23 2.24     95   90          100  100  98  100 100  100       (0)             (0)     (2)    (0) 6 1.68 23 2.24  15   55          100  100  90   95  80   95         (72)             (0)    (5)    (15) 6 1.68 23 2.24  30   82      95  100  95   95  65   90       (63)             (5)    (0)    (27) 6     1.68 23 2.24  45   73          100   95 100   95 100  100       (38)             (0)    (0)    (0) 6 3.36 23 0.14  88   95          100  100 100     100 100  100       (7)             (0)    (0)    (0) 6 3.36 23 0.14  88      80          100  100 100   95  95   95       (0)             (0)    (0)        (0) 6 3.36 23 0.14  50  100          100  100 100  100  95  100     (50)             (0)    (0)    (5) 6 3.36 23 0.14  95   97          100     100 100  100 100  100       (2)             (0)    (0)    (0) 6 3.36 23     0.14  90  100          100  100  95  100  95  100       (10)     (0)    (5)    (5) 6 3.36 23 0.14  95   90          100  100 100  100  98      100       (0)             (0)    (0)    (2) 6 3.36 23 0.28  90   83          100  100  95   95  90   95       (0)             (0)    (0)    (5)     6 3.36 23 0.56  98   97          100  100 100  100 100  100       (0)              (0)    (0)    (0) 6 3.36 23 0.56  90   95          100  100 100      100 100  100       (5)             (0)    (0)    (0) 6 3.36 23 0.56  80       80          100  100  95   95  95   95       (0)             (0)     (0)    (0) 6 3.36 23 0.56  90  100          100  100  90  100  95  100         (10)             (0)    (10)    (5) 6 3.36 23 0.56  98   90     100  100 100  100 100  100       (0)             (0)    (0)    (0) 6     3.36 23 0.56  75  100          100  100 100  100 100  100       (25)              (0)    (0)    (0) 6 3.36 23 0.84  88   83          100  100  95       95  95   95       (0)             (0)    (0)    (0) 6 3.36 23 2.24  0      90           0  100  0  100  0  100      (100)            (100)   (100)       (100) 6 3.36 23 2.24  82   83           95  100  95   95  95   95      (1)             (5)    (0)    (0) 6 3.36 23 2.24  78   80          100     100 100   95  82   95       (2)             (0)    (0)    (13) 6 3.36 23     2.24  98   97          100  100 100  100 100  100       (0)     (0)    (0)    (0) 6 3.36 23 2.24  50  100          100  100  98  100  98      100       (50)             (0)    (2)    (2) 6 3.36 23 2.24  90   95           100  100 100  100 100  100       (5)             (0)     (0)     (0) 6 3.36 23 2.24  95  100          100  100  95  100  95  100     (5)             (0)    (5)    (5) 6 0.84 25 0.14  75   78           95     95  95   95 100  100       (3)             (0)    (0)    (0) 6 0.84 25     0.56  50   78          100   95 100   95  95  100       (35)     (0)    (0)    (5) 6 0.84 25 2.24  25   78           95    95  95   95     80  100       (67)             (0)    (0)    (20) 6 1.68 25 0.14  80     73          100   95 100   95 100  100       (0)             (0)    (0)       (0) 6 1.68 25 0.56  65   73          100   95 100   95  95  100     (10)             (0)    (0)    (5) 6 1.68 25 2.24  48   73           95      95 100   95  95  100       (34)             (0)    (0)    (5) 6 3.36 25     0.14  90   95           95  100 100  100 100  100       (5)     (5)    (0)    (0) 6 3.36 25 0.56  90   95           95  100 100  100 100      100       (5)             (5)    (0)    (0) 6 3.36 25 2.24  78   95          100  100 100  100  95  100       (17)             (0)    (0)    (5)     7 0.56  1 1.12  25   20  25   77 25   40   95  100       (0)   (67)     (37)    (5) 7 2.24  1 1.12  70   60  35   77 35   40 100  100       (0)      (54)    (12)    (0) 7 0.56 10 1.12  37   20  20   77 15   40 100  100         (0)   (74)    (62)    (0) 7 2.24 10 1.12  68   60  60   77 15   40     100  100       (0)   (22)    (62)    (0) 7 0.56 11 1.12  35   20  17     77  0   40 100  100       (0)   (77)   (100)    (0) 7 2.24 11 1.12  83     60  70   77 13   40 100  100       (0)    (9)    (67)    (0) 8 0.56  1     1.12 100  100 100  100 95   98  10   60       (0)    (0)    (3)   (83) 8     2.24  1 1.12 100  100 100  100 99  100  83   85       (0)    (0)    (1)       (2) 8 0.56 10 1.12  97  100 100  100 55   98  70   60       (3)    (0)        (43)    (0) 8 2.24 10 1.12 100  100 100  100 99  100  95   85     (0)    (0)    (1)    (0) 8 0.56 11 1.12  95  100 100  100 75   98  63     60       (5)     (0)    (23)    (0) 8 2.24 11 1.12 100  100 100  100 99     100  85   85       (0)    (0)    (1)    (0) 10  1.68  1 0.84               98   99 48   80                            (1)   (40) 10  1.68      1 1.68                       85   99 15   80     (14)   (81) 10  1.68  1 3.36                       95   99 20   80                          (4)   (75) 10  3.36  1 0.84     100  100 75   99                            (0)   (24) 10  3.36  1 1.68                         100  100 65   99                            (0)     (34) 10  3.36  1 3.36                      100  100 53   99                   (0)   (46) 10  6.72  1 0.84                      100  100     98  100                            (0)    (2) 10  6.72  1 1.68                100  100 80  100                            (0)   (20) 10     6.72  1 3.36                      100  100 88  100          (0)   (12) 11  1.12  1 1.12  65   45  99   99  5   20  65   43      (0)    (0)    (75)    (0) 11  3.36  1 1.12  55   75 100   95 17   50     45   65       (26)    (0)    (66)   (30) 11  4.48  1 2.24           25     45               (44) 11  4.48  1 8.96           60   45     (0) 11  8.96  1 2.24           30   65               (53) 11  8.96  1     8.96           70   65                (0) 11  1.12 10 1.12  57   45  85      99 12   20       (0)   (14)    (40) 11  3.36 10 1.12  45   75  75   95     5   50       (40)   (21)    (90) 11  4.48 10 2.24           30   45              (33) 11  4.48 10 8.96           40   45               (11) 11     8.96 10 2.24           60   65                (7) 11  8.96 10 8.96         50   65               (23) 11  1.12 11 1.12  40   45  87   99  5     20  50   43       (11)   (12)    (75)    (0) 11  3.36 11 1.12  70   75     99   95 22   50  63   65       (6)    (0)    (56)    (3) 11  4.48 11     2.24           50   45                (0) 11  4.48 11 8.96           45      45                (0) 11  8.96 11 2.24           65   65     (0) 11  8.96 11 8.96           75   65                (0) 35  0.28  1     1.12  87   97 100  100 85   90  53   37       (10)    (0)    (5)    (0)     35  1.12  1 1.12  93  100 100  100 95   95  93   87       (7)    (0)     (0)    (0) 35  0.28 10 1.12  90   97  99  100 70   90  90   37       (7)        (1)    (22)    (0) 35  1.12 10 1.12 100  100 100  100 97   95  90     87       (0)    (0)    (0)    (0) 35  0.28 11 1.12  99   97 100  100 90      90  57   37       (0)    (0)    (0)    (0) 35  1.12 11 1.12 100  100     100  100 97   95  83   87       (0)    (0)    (0)    (4) 35  1.12  1     1.12  50   75  77   87 60   55  55   60       (33)   (11)    (0)    (8)     35  5.60  1 1.12  97   95  99   97 75   83  98   90       (0)    (0)     (9)    (0) 35  1.12 10 1.12  55   75  83   87 55   55  90   60     (26)    (4)    (0)    (0) 35  5.60 10 1.12  97   95  99   97 83   83  95       90       (0)    (0)    (0)    (0) 35  1.12 11 1.12  73   75  93   87     60   55  55   60       (2)    (0)    (0)    (8) 35  5.60 11 1.12  95     95  99   97 83   83  98   90       (0)    (0)    (0)    (0) 35  1.12   1     1.12  40   30  90   70 60   60  53   45       (0)    (0)    (0)    (0)     35  2.24  1 2.24           40   40                (0) 15  2.24  1 8.96             50   40                (0) 15  3.36  1 1.12  55   60  93   99 83       60  57   55       (8)    (6)    (0)    (0) 15  4.48  1 2.24     30   55               (45) 15  4.48  1 8.96           10   55        (81) 15  1.12 10 1.12  43   30  99   70 60   60  57   45       (0)     (0)    (0)    (0) 15  2.24 10 2.24           30   40               (25)     15  2.24 10 8.96           20   40               (50) 15  3.36 10 1.12     65   60  97   99 75   60  60   55       (0)    (2)    (0)    (0) 15     4.48 10 2.24           50   55                (9) 15  4.48 10 8.96         40   55               (27) 15  1.12 11 1.12  43   30  95   70 40     60  83   45       (0)    (0)    (33)    (0) 15  2.24 11 2.24     20   40               (50) 15  2.24 11 8.96           20   40        (50) 15  3.36 11 1.12  30   60  99   99 73   60  55   55       (50)      (0)    (0)    (0) 15  4.48 11 2.24           40   55               (27)     15  4.48 11 8.96           65   55                (0) 18  1.12  1 1.12     63   50  97   99  0   5  73   20       (0)    (2)   (100)    (0) 18     3.36  1 1.12  80   75  95   99 30   23  63   25       (0)    (4)    (0)       (0) 18  1.12 10 1.12  45   50  90   99  0   5  25   20       (10)     (9)   (100)    (0) 18  3.36 10 1.12  50   75  93   99 10   23  70   25         (33)    (6)    (56)    (0) 18  1.12 11 1.12  83   50  97   99 20   5      60   20       (0)    (2)    (0)    (0) 18  3.36 11 1.12  80   75 100     99 53   23  85   25       (0)    (0)    (0)    (0) 28  1.12  1 1.12  60      30  99   97 35   80  65   55       (0)    (0)    (56)    (0) 28  3.36     1 1.12  63   87  99   95 50   95  63   83       (27)    (0)    (47)     (24) 28  1.12 10 1.12  35   30  98   97 45   80  67   55       (0)     (0)    (43)    (0) 28  3.36 10 1.12  83   87 100   95 99   95 100   83         (4)    (0)    (0)    (0) 28  1.12 11 1.12  37   30  83   97 40   80     55   55       (0)   (14)    (50)    (0) 28  3.36 11 1.12  80   87  99     95 99   95  75   83       (8)    (0)    (0)      (9)

EXAMPLE 290

The following procedure shows interaction between herbicide and antidotewhen applied together as a mixture before emergence of the crop and weedspecies. Containers were filled and compacted with fumigated silt loamtop soil to a depth of about 1.3 cm from the top of the container. Afirst container was designated as an untreated control, a secondcontainer was designated as a herbicide control, and a third containerwas designated as a herbicide+antidote test container. Each of thecontainers was seeded with both crop plant and weed species. Theherbicide and the herbicide+antidote test mixture were applied to theseeded containers either by a procedure of topical application to a soillayer placed over the seed bed followed by watering to achieveincorporation, or by a procedure of incorporation into soil and thenplacement of the treated soil into the container over the seed bed. Thecontainers were then placed on a greenhouse bench, and sub-irrigated asrequired for the duration of the test. Plant response was observed aboutthree weeks after initial treatment. Results are reported in Table VII.

    TABLE VII      % PLANT INHIBITION AND % SAFENING EFFECT ( )    DOWNEY SORGHUM GREEN     WILD JOHNSON SHATTER CRAB- PIG- PROSO  BARNYARD   HERBICIDE ANTIDOTE     WHEAT BROME GRAIN FOXTAIL OATS GRASS CANE GRASS WEED MILLET RICE GRASS     SORGHUM SOYBEAN NO. RATE NO. RATE W  WO W  WO W  WO W  WO W WO W  WO W     WO W  WO W  WO W  WO W WO W  WO W  WO W      WO                                 6 2.24  1 1.12 88  95  78  100              (7)   (22)   6 2.24  1 1.12 72   70  70   98     (0)   (28)   6     2.24  1 1.12 55  70  80   98     (21)   (18)   6 2.24  1 2.24 90  95  60      100     (5)   (40)   6 2.24  1 4.48 72  95  55  100     (24)   (45)   6     2.24  1 4.48 60  70  55   98     (14)   (43)   6 2.24  1 8.96 52  70  30       98     (25)   (69)   6 2.24  1 8.96 82  95  20  100     (13)   (80)     6 2.24  2 1.12 70  62  90  100     (0)   (10)   6 2.24  2 2.24 58  70     92   98     (17)   (6)   6 2.24  2 2.24 68  62  80  100     (0)   (20)     6 2.24  2 4.48 52  62  80  100     (16)   (20)   6 2.24  2 8.96 60  62     70  100     (3)   (30)   6 2.24  3 1.12 45  62  68  100     (27)   (32)      6 2.24  3 1.12 65  80  65   92     (18)   (29)   6 2.24  3 2.24 62  80     50   92     (22)   (45)   6 2.24  3 2.24 60  62  55  100     (3)   (45)      6 2.24  3 4.48 70  80  20   92     (12)   (78)   6 2.24  3 4.48 70  62     35  100     (0)   (65)   6 2.24   3 8.96 62  62  20  100     (0)   (80)      6 2.24  3 8.96 48  80  30   92     (40)   (67)   6 0.14  4 0.14 20  33     40   55  40   25 15 35     (39)  (27)   (57)  (0)   6 0.14  4 0.56 15     33 50   55  33   25 30 35     (54)  (9)   (14)  (0)   6 0.14  4 2.24 25     33 35   55  35   25 25 35     (24)  (36)   (28)  (0)   6 0.56  4 0.14 30      43 40   65  93   50 43 45     (30)  (38)   (4)  (0)   6 0.56  4 0.56 57      43 70   65  55   50 70 45     (0)  (0)    (0)  (0)   6 0.56  4 2.24 50     43 65   65  65   50 60 45     (0)  (0)   (0)  (0)   6 2.24  4 0.14 83     80 90   75  99   90 85 85     (0)  (0)   (0)  (0)   6 2.24  4 0.56 57     80 83   75  95   90 50 85     (28)  (0)   (0)  (41)   6 2.24  4 1.12 80     95  62  100     (15)   (38)   6 2.24  4 2.24 75  95  45  100     (21)     (55)   6 2.24  4 2.24 75  80 93   75  95   90 70 85     (6)  (0)   (0)     (17)   6 2.24  4 4.48 70  95  28  100     (26)    (72)   6 2.24  4 8.96     65  95  10  100     (31)   (90)   6 2.24  5 1.12 75  95  62  100     (21)   (38)   6 2.24  5 2.24 75  95  40  100     (21)   (60)   6 2.24  5     4.48 45  95  30  100     (52)   (70)   6 2.24  5 8.96 35  95  40  100      (63)   (60)   6 0.03  6 0.03   0   13 80   85  0   5 0   5 78  83 68     83 100 100       (100)  (5)   (100)  (100)  (6)  (18)  (0)   6 0.03  6     0.14   0   13 80   85  0   5 0   5 75  83 70  83 100  100       (100)     (5)   (100)  (100)  (9)  (15)  (0)   6 0.03  6 0.56   0   13 80   85  5      5 0   5 85  83 85  83 100 100       (100)  (5)   (0)  (100)  (0)  (0)     (0)   6 0.03  6 2.24   0   13 78   85  0   5 0   5 80  83 80  83 100 100           (100)  (8)   (100)  (100)  (3)  (3)  (0)   6 0.14  6 0.03   0   25     90   93  10   45 15   55 90  93 70  90 100 100       (100)  (3)   (77)     (72)  (3)  (22)  (0)   6 0.14  6 0.14   17   45 87   95    65  45    85      99       (62)  (8)     (0)     (14)   6 0.14  6 0.14   0   25 93   93     8   45 5   55 93  93 90  90 100 100       (100)  (0)   (82)  (90)  (0)     (0)  (0)   6 0.14  6 0.56   5   45 95   95    73  45    75   99     (88)  (0)     (0)     (24)   6 0.14  6 0.56   0   25 93   93  15   45 13       55 93  93 100  90 100 100       (100)  (0)   (66)  (76)  (0)  (0)  (0)       6 0.14  6 2.24   5    25 95   93  13   45 10   55 97  93 100  90 100     100       (80)  (0)   (71)  (81)  (0)  (0)  (0)   6 0.14  6 2.24   0     45 85   95    57  45    50   99       (100)  (10)     (0)     (49)   6     0.56  6 0.03   50   55 98   98  99   98 93   92 99  98 99 100 100 100        (9)  (0)   (0)  (0)  (0)  (1)  (0)   6 0.56  6 0.14   55   50 93   95        70  90    85   99       (0)  (2)     (22)     (14)   6 0.56  6 0.14     40   55 97   98  80   98 93   92 98  98 100 100 100 100       (27)  (1)      (18)  (0)  (0)  (0)  (0)   6 0.56  6 0.56   10   50 95   95    85  90      87   99       (80)  (0)     (5)     (12)   6 0.56  6 0.56   15   55 98      98  75   98 70   92 98  98 95 100 100 100       (72)  (0)   (23)  (23)     (0)  (5)  (0)   6 0.56  6 2.24   20   50 99   95    87  90    90   99        (60)  (0)     (3)     (9)    6 0.56  6 2.24   50   55 97   98  85     98 75   92 99  98 100 100 100 100       (9)  (1)   (13)  (18)  (0)  (0)     (0)   6 2.24  6 0.03   75   80 100  100  99   99 98   98 100 100 100 100     100 100       (6)  (0)   (0)  (0)  (0)  (0)  (0)   6 2.24  6 0.14   83     80 100  100  99   99 98   98 100 100 100 100 100 100       (0)  (0)     (0)  (0)  (0)  (0)  (0)   6 2.24  6 0.14   90   96 99   99    97  97     100  100       (6)  (0)     (0)     (0)    6 2.24  6 0.56   65   96 95     99    83  97    100  100       (32)  (4)     (14)     (0)   6 2.24  6     0.56   78   80 99  100  99   99 97   98 100 100 100 100 100 100     (2)  (1)   (0)  (1)  (0)  (0)  (0)   6 2.24  6 2.24   63   80 98  100     100   99 90   98 100 100 100 100 100 100       (21)  (2)   (0)  (8)  (0)      (0)  (0)   6 2.24  6 2.24   40   96 99   99    99  97    100  100     (58)  (0)     (0)     (0)    6 4.48  6 0.03   94   99 100  100  100  100     100   99 100 100 100 100 100 100       (5)  (0)   (0)  (0)  (0)  (0)     (0)   6 4.48  6 0.14   90   99 100  100  95  100 100   99 100 100 100     100 100 100       (9)  (0)   (5)  (0)  (0)  (0)  (0)   6 4.48  6 0.56     78   99 100  100  99  100 99   99 100 100 100 100 100 100       (21)     (0)   (1)  (0)  (0)  (0)  (0)   6 4.48  6 2.24   83   99 99   100  100     100 99   99 100 100 100 100 100 100       (16)  (1)   (0)  (0)  (0)  (0)      (0)   6 0.03  7 0.03   0   5 90   93  3   5 5   8 93  93 48  45     (100)  (3)   (40)  (37)  (0)  (0)   6 0.03  7 0.14   5   5 90   93  3     5 3   8 93  93 40  45       (0)  (3)   (40)  (62)  (0)  (11)   6 0.03  7     0.56   5   5 93   93  5   5 0   8 93  93 40  45       (0)  (0)   (0)     (100)  (0)  (11)   6 0.03  7 2.24   0   5 95   93  0   5 3   8 93  93 40      45       (100)  (0)   (100)  (62)  (0)  (11)   6 0.14  7 0.03   43   55     97   95  63   45 60   50 98  95 40  58       (21)  (0)   (0)  (0)  (0)     (31)   6 0.14  7 0.14   45   55 95   95  40   45 53   50 97  95 45  58         (18)  (0)   (11)  (0)  (0)  (22)   6 0.14  7 0.14   0   45 65   95      45  45    80   99       (100)  (31)     (0)     (19)   6 0.14  7 0.56     10   45 87   95    67  45    85   99       (77)  (8)     (0)     (14)     6 0.14  7 0.56   40   55 95   95  40   45 30   50 97  95 40  58     (27)  (0)   (11)  (40)  (0)  (31)   6 0.14  7 2.24   25   45 95   95     55  45    57   99       (44)  (0)     (0)     (42)   6 0.14  7 2.24   20       55 93   95  15   45 20   50 97  95 43  58       (63)  (2)   (66)  (60)      (0)  (25)   6 0.56  7 0.03   65   73 94   97  85   93 97   83 98  97 65      60       (10)  (3)   (8)  (0)  (0)  (0)   6 0.56  7 0.14   70   73 97     97  84   93 78   83 97  97 65  60       (4)  (0)   (9)  (6)  (0)  (0)     6 0.56  7 0.14   30   50 90   95    70  90    99   99       (40)  (5)      (22)     (0)   6 0.56  7 0.56   25   50 95   95    80  90    99   99        (50)  (0)     (11)     (0)   6 0.56  7 0.56   65   73 97   97  83     93 75   83 97  97 65  60       (10)  (0)   (10)  (9)  (0)  (0)   6 0.56     7 2.24   25   50 99   95    85  90    99   99       (50)  (0)     (5)      (0)   6 0.56  7 2.24   50   73 95   97  65   93 65   83 94  97 55  60         (31)  (2)   (30)  (21)  (3)  (8)   6 2.24  7 0.03   97   90 97   98     95   98 99   95 98 100 95  95       (0)  (1)   (3)  (0)  (2)  (0)   6     2.24  7 0.14   98   90 98   98  99   98 99   95 99 100 98  95       (0)     (0)   (0)  (0)  (0)  (0)   6 2.24  7 0.14   45   96 99   99    99  97     100  100       (53)  (0)     (0)     (0)   6 2.24  7 0.56   88   90 98     98  94   98 97   95 99 100 93  95       (2)  (0)   (4)  (0)  (1)  (2)     6 2.24  7 0.56   77   96 100   99    100  97    99  100       (19)  (0)        (0)     (0)   6 2.24  7 2.24   83   90 98   98  99   98 88   95 97     100 85  95       (7)  (0)   (0)  (7)  (3)  (10)   6 2.24  7 2.24   53     96 99    99    97  97    97  100       (44)  (0)     (0)   6 4.48  7     0.03   99   99 99   99  98   99 99   99 99  99 98  98       (0)  (0)     (1)  (0)  (0)  (0)   6 4.48  7 0.14   99   99 99   99  99   99 99   99     100  99 97  98       (0)  (0)   (0)  (0)  (0)  (1)   6 4.48  7 0.56   98       99 98   99  99   99 99   99 100  99 94  98       (1)  (1)   (0)  (0)     (0)  (4)   6 4.48  7 2.24   97   99 99   99  99   99 99   99 99  99 93     98       (2)  (0)   (0)  (0)  (0)  (5)   6 0.14  8 0.14   5   45 77   95        47  45    77   99       (88)  (18)     (0)     (22)   6 0.14  8 0.56      0   45 93   95    47  45    50   99       (100)  (2)     (0)     (49)     6 0.14  8 2.24   7   45 85   95    70  45    75   99       (84)  (10)      (0)     (24)   6 0.56  8 0.14   37   50 95   95    80  90    97   99        (26)  (0)     (11)     (2)   6 0.56  8 0.56   20   50 93   95    80     90    85   99       (60)  (2)     (11)     (14)   6 0.56  8 2.24   43     50 99   95    95  90    97   99       (14)  (0)     (0)     (2)   6 2.24      8 0.14   65   96 99   99    99  97    99  100       (32)  (0)     (0)       (1)   6 2.24  8 0.56   80   96 99   99    99  97    100  100     (16)  (0)     (0)     (0)   6 2.24  8 1.12 62  80  75   92     (22)     (18)   6 2.24  8 2.24   40   96 99   99    99  97    99  100       (58)     (0)     (0)     (1)   6 2.24  8 2.24 58  80  70   92     (27)   (23)   6     2.24  8 4.48 55  80  60   92     (31)   (34)   6 2.24  8 8.96 45  80  40       92     (43)   (56)   6 0.03  9 0.03   10   5 90   93  5   5 8   8 90     93 45  45       (0)  (3)   (0)  (0)  (3)  (0)   6 0.03  9 0.14   0   5     93   93  5   5 5   8 93  93 40  45       (100)  (0)   (0)  (37)  (0)     (11)   6 0.03  9 0.56   0   5 90   93  0   5 3   8 90  93 35  45     (100)  (3)   (100)  (62)  (3)  (22)   6 0.03  9 2.24   0   5 90   93  0      5 0   8 90  93 45  45       (100)  (3)   (100)  (100)  (3)  (0)   6     0.14  9 0.03   45   55 93   95  33   45 50   50 95  95 65  58       (18)      (2)   (26)  (0)  (0)  (0)   6 0.14  9 0.14   5   45 95   95    50  45      95   99       (88)  (0)     (0)     (4)   6 0.14  9 0.14   30   55 97     95  25   45 40   50 97  95 45  58       (45)  (0)   (44)  (20)  (0)     (22)   6 0.14  9 0.56   10   55 97   95  15   45 18   50 98  95 60  58         (81)  (0)   (66)  (64)  (0)  (0)   6 0.14  9 0.56   7   45 87   95      77  45       (84)  (8)     (0)   6 0.14  9 2.24   20   55 93   95  25     45 18   50 97  95 65  58       (63)  (2)   (44)  (64)  (0)  (0)   6 0.14      9 2.24   10   45 75   95    40  45    63   99       (77)  (21)     (11)         (36)   6 0.56  9 0.03   55   73 95   97  58   93 68   83 97  97 75     60       (24)  (2)   (37)  (18)  (0)  (0)   6 0.56  9 0.14   45   73 97      97  50   93 65   83 97  97 80  60       (38)  (0)   (46)  (21)  (0)     (0)   6 0.56  9 0.14   23   50 95   95    73  90    97   99       (54)     (0)     (18)     (2)   6 0.56  9 0.56   17   50 95   95    95  90    99      99       (66)  (0)     (90)     (0)   6 0.56  9 0.56   30   73 98   97     83   93 55   83 97  97 65  60       (58)  (0)   (24)  (0)  (0)  (0)   6     0.56  9 2.24   10   50 95   95    67  90    95   99       (80)  (0)     (25)     (4)   6 2.24  9 0.03   93    90 97   98  95   98 98   95 98 100     94  95       (0)  (1)   (3)  (0)  (2)  (1)   6 2.24  9 0.14   83   96 99       99    99  97    99  100       (13)  (0)     (0)     (1)   6 2.24  9     0.14   93   90 98   98  94   98 98   95 98 100 90  95       (0)  (0)     (4)  (0)  (2)  (5)   6 2.24  9 0.56   90   90 99   98  99   98 98   95     98 100 80  95       (0)  (0)   (0)  (0)  (2)  (15)   6 2.24  9 0.56   35       96 99    99    93  97    97  100       (63)  (0)     (4)     (3)   6     2.24  9 2.24   83   90 99   98  97   98 97   95 99 100 85  95       (7)     (0)   (1)  (0)  (1)  (10)   6 2.24  9 2.24   43   96 100   99    97  97       100  100       (55)  (0)     (0)     (0)   6 4.48  9 0.03   99   99 97       99  99   99 99   99 99  99 98  98       (0)  (2)   (0)  (0)  (0)  (0)      6 4.48  9 0.14   93   99 99   99  98    99 98   99 99  99 97  98     (6)  (0)   (1)  (1)  (0)  (1)   6 4.48  9 0.56   97   99 99   99  100     99 99   99 99  99 95  98       (2)  (0)   (0)  (0)  (0)  (3)   6 4.48  9     2.24   94   99 100   99  98   99 97   99 99  99 100  98       (5)  (0)     (1)  (2)  (0)  (0)   6 0.14 10 0.14   10   45 90   95    65  45    95     99       (77)  (5)     (0)     (14)   6 0.14 10 0.56   13   45 90   95      50  45    50   99       (71)  (5)     (0)     (49)   6 0.14 10 2.24     10   45 98   95    55  45    57   99       (77)  (5)     (0)     (42)     6 0.56 10 0.14   25   50 99   95    77  90    95   99       (50)  (0)      (14)     (4)   6 0.56 10 0.56   33   50 97   95    75  90    99   99        (34)  (0)     (16)     (0)   6 0.56 10 2.24   13   50 90   95    93     90    83   99       (74)  (5)     (0)     (16)   6 2.24 10 0.14   77     96 100   99    100  97    97  100       (19)  (0)     (0)     (3)  10     1.12  1 0.56           10 15 85   80               (33)  (0)  10 1.12  1     0.56           25 50 90   80               (50)  (0)  10 1.12  1 1.12            0 15 95   80               (100)  (0)  10 1.12  1 1.12     30 50 90   80               (40)  (0)  10 1.12  1 2.24           35 50     90   80               (30)  (0)  10 1.12  1 2.24           15 15 75   80                   (0)  (6)  10 1.12  1 3.36           10 15 85   80          (33)  (0)  10 1.12  1 3.36           20 50 90   80     (60)  (0)  10 1.68  1 0.14           20 45 100  100               (55)     (0)  10 1.68  1 0.56           15 45 100  100               (66)  (0)     10 1.68  1 0.84           10 45 100  100               (77)  (0)  10     1.68  1 0.84           10 17 100  100               (41)  (0)  10 1.68     1 0.84           10  5 85   81               (0)  (0)  10 1.68  1 0.84             58 72 100  100               (19)  (0)  10 1.68  1 0.84      0  0 75   60               (0)  (0)  10 1.68  1 0.84           0 30 100       97               (100)  (0)  10 1.68  1 0.84           45 78 98  100                 (42)  (2)  10 1.68  1 0.84           35 75 100  100          (53)  (0)  10 1.68  1 0.84           13 55 87  100     (76)  (13)   10 1.68  1 1.68           8 17 95  100               (52)     (5)  10 1.68  1 1.68           15 45 100  100               (66)  (0)     10 1.68  1 1.68           15 30 90   97               (50)  (7)  10 1.68      1 1.68           0  0 65   60               (0)  (0)  10 1.68  1 1.68             38 78 100  100               (51)  (0)  10 1.68  1 1.68      23 55 85  100               (58)  (15)  10 1.68  1 1.68           50 72     100  100               (30)  (0)  10 1.68  1 1.68           47 75 100     100               (37)  (0)  10 1.68  1 1.68           17  5 95   81               (0)  (0)  10 1.68  1 2.24           10 45 100  100       (77)  (0)  10 1.68  1 3.36           0 17 100  100               (100)      (0)  10 1.68  1 3.36           8 45 100  100               (82)  (0)     10 1.68  1 3.36           25 78 100  100               (67)  (0)  10     1.68  1 3.36           50 72 100  100               (30)  (0)  10 1.68     1 3.36           35 75 99  100               (53)  (1)  10 1.68  1 3.36              45  5 70   81               (0)  (13)  10 1.68  1 3.36      30 55 88  100               (45)  (12)  10 1.68  1 3.36           20 30     95   97               (33)  (2)  10 1.68  1 3.36           0  0 35   60                  (0)  (41)  10 2.24  1 0.56           10 25 95  100          (60)  (5)  10 2.24  1 0.56           45 65 100   90     (30)  (0)  10 2.24  1 1.12           15 25 80  100               (40)     (20)  10 2.24  1 1.12           35 65 100   90               (46)  (0)     10 2.24  1 2.24           30 65 100   90               (53)  (0)  10     2.24  1 2.24           10 25 90  100               (60)  (10)  10 2.24     1 3.36           5 25               (80)  10 2.24   1 3.36           25     65               (61)  10 2.24  1 0.14           35 63     (44)  10 3.36  1 0.56           40 63 100  100               (36)  (0)     10 3.36  1 0.84           5 60 100  100               (91)  (0)  10 3.36      1 0.84           25 72 100  100               (65)  (0)  10 3.36  1     0.84           15 20 90  100               (25)  (10)  10 3.36  1 0.84             80 88 100  100               (9)  (0)  10 3.36  1 0.84     48 90 99  100               (46)  (1)  10 3.36  1 0.84           78 86     100  100               (9)  (0)  10 3.36  1 0.84           68 60 100     100               (0)  (0)  10 3.36  1 0.84           5 25 99   95             (80)  (0)  10 3.36  1 0.84           18 55 97   99     (67)  (2)  10 3.36  1 1.68           10 60 100  100               (83)     (0)  10 3.36  1 1.68           23 72 100  100               (68)  (0)     10 3.36  1 1.68           30 90 87  100               (66)  (13)  10     3.36  1 1.68           20 20 80  100               (0)  (20)  10 3.36     1 1.68           25 25 98   95               (0)  (0)  10 3.36  1 1.68             68 88 100  100               (22)  (0)  10 3.36  1 1.68      17 55 99   99               (69)  (0)  10 3.36  1 1.68           48 86     100  100               (44)  (0)  10 3.36  1 1.68           25 60 97     100               (58)  (3)  10 3.36  1 2.24           8 63 100  100               (87)  (0)  10 3.36  1 3.36           10 60 100  100        (83)  (0)  10 3.36  1 3.36           8 72 100  100               (88)      (0)  10 3.36  1 3.36           0 20 60  100               (100)  (40)     10 3.36  1 3.36           23 60 99  100               (61)  (1)  10 3.36      1 3.36           30 55 97   99               (45)  (2)  10 3.36  1 3.36               15 90 85  100               (83)  (15)  10 3.36  1 3.36        23 25 98   95               (8)  (0)  10 3.36  1 3.36           38 86     100  100               (55)  (0)  10 3.36  1 3.36           58 88 100     100               (34)  (0)  10 3.36  1 0.56           30 45 90  100               (33)  (10)  10 3.36  1 0.56           70 80 100  100         (12)  (0)  10 3.36  1 1.12           60 80 90  100     (25)  (10)  10 4.48  1 1.12           48 82               (41)  10 4.48     1 1.12           95 98               (3)  10 4.48  1 1.12           25     45 100  100               (44)  (0)  10 4.48  1 2.24           20 45 100      100               (55)  (0)  10 4.48  1 2.24           45 82        (45)  10 4.48  1 2.24           55 80 100  100               (31)     (0)  10 4.48  1 2.24           55 98               (43)  10 4.48  1 3.36               50 80 100  100               (37)  (0)  10 4.48  1 3.36        15 45 100  100               (66)  (0)  10 4.48  1 4.48           40     82               (51)  10 4.48  1 4.48           68 98     (30)  10 4.48  1 8.96           50 98               (48)  10 4.48  1     8.96           38 82               (53)  10 6.72  1 0.14           88 88     100  100               (0) (0)  10 6.72  1 0.56           68 88 100  100                   (22)  (0)  10 6.72  1 0.56           40 70 100  100            (42)  (0)  10 6.72  1 0.56           70 90 100  100     (22)  (0)  10 6.72  1 0.84           28 88 100  100               (68)     (0)  10 6.72  1 0.84           55 85 100  100               (35)  (0)     10 6.72  1 0.84           25 67 97   97               (62)  (0)  10 6.72      1 0.84           90 98 100  100               (8)  (0)  10 6.72  1 0.84               40 27 99   97               (0) (0)  10 6.72  1 0.84     70 77 100  100               (9)  (0)  10 6.72  1 0.84           27 93     100  100               (70)  (0)  10 6.72  1 0.84           88 95 100     100               (7)  (0)  10 6.72  1 0.84           25 55 90  100              (54)  (10)  10 6.72  1 1.12           65 90 100  100        (27)  (0)  10 6.72  1 1.12           20 70 100  100     (71)  (0)  10 6.72  1 1.68           25 85 100  100               (70)     (0)  10 6.72  1 1.68           38 88 100  100               (56)  (0)     10 6.72  1 1.68           37 27 95   97               (0)  (2)  10 6.72     1 1.68           78 95 100  100               (17)  (0)  10 6.72  1 1.68               37 67 97   97               (44)  (0)  10 6.72  1 1.68       45 93 95  100               (51)  (5)  10 6.72  1 1.68           88 98     100  100               (10)  (0)  10 6.72  1 1.68           30 55 95     100               (45)  (5)  10 6.72  1 1.68           45 77 100  100                (41)  (0)  10 6.72  1 2.24           15 88 100   100          (82)  (0)  10 6.72  1 2.24           45 90 100  100     (50)  (0)  10 6.72  1 2.24           45 70 100  100               (35)     (0)  10 6.72  1 3.36           10 88 100  100               (88)  (0)     10 6.72  1 3.36           10 85 100  100               (88)  (0)  10     6.72  1 3.36           75 98 100  100               (23)  (0)  10 6.72     1 3.36           33 27 99   97               (0) (0)  10 6.72  1 3.36            20 55 85  100               (63)  (15)  10 6.72  1 3.36     55 77 99  100               (28)  (1)  10 6.72  1 3.36           68 93     93  100               (26)  (7)  10 6.72  1 3.36           13 67 99   97                   (80)  (0)  10 6.72  1 3.36           85 95 100  100            (10)  (0)  10 6.72  1 3.36           60 90 100  100     (33)  (0)  10 6.72  1 3.36           15 70 100  100               (78)     (0)  10 4.48  2 1.12           78 82               (4)  10 4.48  2 1.12              78 55               (0)  10 4.48  2 2.24           82 55            (0)  10 4.48  2 2.24           68 82               (17)  10 4.48     2 4.48           45 55               (18)  10 4.48  2 4.48           50     82               (39)  10 4.48  2 8.96           45 82     (45)  10 4.48  2 8.96           70 55               (0)  10 4.48  3 1.12               38 82               (53)  10 4.48  3 1.12           50 82              (39)  10 4.48  3 1.12           78 55               (0)  10     4.48  3 2.24           20 55               (63)  10 4.48  3 2.24       35 82               (57)  10 4.48  3 2.24           52 82      (36)  10 4.48  3 4.48           40 55               (27)  10 4.48  3     4.48           48 82               (41)  10 4.48  3 4.48           25 82                   (69)  10 4.48  3 8.96           25 82               (69)     10 4.48  3 8.96           20 82               (75)  10 4.48  3 8.96          18 55               (67)  10 4.48  4 1.12           95 98         (3)  10 4.48  4 2.24           85 98               (13)  10 4.48  4     4.48           75 98               (23)  10 4.48  4 8.96           80 98                   (18)  10 4.48  5 1.12           45 98               (54)     10 4.48  5 2.24           50 98               (48)  10 4.48  5 4.48          52 98               (46)  10 4.48  5 8.96           60 98         (38)  10 1.68  6 0.84           5 30 90   97               (83)  (7)      10 1.68  6 1.68           13 30 92   97               (56)  (5)  10     1.68  6 3.36           17 30 97   97               (43)  (0)  10 3.36  6     0.84           23 55 95   99               (58)  (4)  10 3.36  6 1.68            15 55 97   99               (72)  (2)  10 3.36  6 3.36     40 55 97   99               (27)  (2)  10 6.72  6 0.84           33 67     100   97               (50)  (0)  10 6.72  6 1.68           25  67 99     97               (62)  (0)  10 6.72  6 3.36           10 67 100   97               (85)  (0)  10 4.48  8 1.12           48 82               (41)     10 4.48  8 2.24           30 82               (63)  10 4.48  8 4.48          35 82               (57)  10 4.48  8 8.96           30 82         (63)  10 4.48 10 1.12           50 82               (39)  10 4.48 10     1.12           70 55               (0)  10 4.48 10 2.24           45 82                  (45)  10 4.48 10 2.24           52 55               (5)  10     4.48 10 4.48           35 82               (57)  10 4.48 10 4.48       78 55               (0)  10 4.48 10 8.96           45 55     (18)  10 4.48 10 8.96           40 82               (51)  10 4.48 12     1.12           50 82               (39)  10 4.48 12 2.24           40 82                   (51)  10 4.48 12 4.48           18 82               (78)     10 4.48 12 8.96           10 82               (87)  10 4.48 13 1.12          55 82               (32)  10 4.48 13 1.12           62 82         (24)  10 4.48 13 2.24           80 82               (2)  10 4.48 13     2.24           45 82               (45)  10 4.48 13 4.48           12 82                   (85)  10 4.48 13 4.48           68 82               (17)     10 4.48 13 8.96           75 82               (8)  10 4.48 13 8.96         35 82               (57)  10 4.48 14 1.12           50 82        (39)  10 4.48 14 2.24           30 82               (63)  10 4.48 14     4.48           32 82               (60)  10 4.48 14 8.96           30 82                   (63)  10 4.48 15 1.12           95 98               (3)     10 4.48 15 2.24           92 98               (6)  10 4.48 15 4.48         85 98               (13)  10 4.48 15 8.96           85 98        (13)  10 1.12 16 0.56           10 15 90   80               (33)  (0)      10 1.12 16 1.12           15 15 80   80               (0)  (0)  10 1.12     16 2.24           15 15 90   80               (0)  (0)  10 1.12 16 3.36              20 15 85   80               (0)  (0)  10 1.68 16 0.84     10 30 95   97               (66)  (2)  10 1.68 16 1.68           8 30 94       97               (73)  (3)  10 1.68 16 3.36           20 30 86   97                (33)  (11)  10 2.24 16 0.56           10 25 90  100         (60)  (10)  10 2.24 16 1.12           15 25 100  100     (40)  (0)  10 2.24 16 2.24           20 25 90  100               (20)     (10)  10 2.24 16 3.36           15 25 95  100               (40)  (5)     10 3.36 16 0.84           15 55 99   99               (72)  (0)  10 3.36     16 1.68           13 55 95   99               (76)  (4)  10 3.36 16 3.36               18 55 96   99               (67)  (3)  10 4.48 16 0.56       35 45 94  100               (22)  (5)  10 4.48 16 1.12           20 45     100  100               (55)  (0)  10 4.48 16 1.12           28 82            (65)  10 4.48 16 2.24           30 82               (63)  10 4.48     16 2.24           35 45 100  100               (22)  (0)  10 4.48 16     3.36           30 45 100  100               (33)  (0)  10 4.48 16 4.48             30 82               (63)  10 4.48 16 8.96           15 82            (81)  10 6.72 16 0.56           30 70 90  100               (57)     (10)  10 6.72 16 0.84           17 67 90   97               (74)  (7)     10 6.72 16 1.12           30 70 100  100               (57)  (0)  10     6.72 16 1.68           20 67 99   97               (70)  (0)  10 6.72 16     2.24           35 70 100  100               (50)  (0)  10 6.72 16 3.36             40 70 90  100               (42)  (10)  10 6.72 16 3.36      20 67 97   97               (70)  (0)  10 4.48 18 1.12           62 98                  (36)  10 4.48 18 2.24           60 98               (38)     10 4.48 18 4.48           50 98               (48)  10 4.48 18 8.96          52 98               (46)  10 4.48 19 1.12           62 82         (24)  10 4.48 19 2.24           48 82               (41)  10 4.48 19     4.48           45 82               (45)  10 4.48 19 8.96           28 82                   (65)  10 4.48 20 1.12           65 82               (20)     10 4.48 20 2.24           55 82               (32)  10 4.48 20 4.48          60 82               (26)  10 4.48 20 8.96           55 82         (32)  10 1.68 21 0.84           0  0 85   60               (0)  (0)     10 1.68 21 1.68           0  0 95   60               (0)  (0)  10 3.36     21 0.84           10 20 100  100               (50)  (0)  10 3.36 21     1.68           10 20 100  100               (50)  (0)  10 3.36 21 3.36             10 20 90  100               (50)  (10)  10 6.72 21 0.84      20 55 80  100               (63)  (20)  10 6.72 21 1.68           10 55     100  100               (81)   (0)  10 6.72 21 3.36           25 55 100     100               (54)  (0)  10 1.12 22 0.56           35 50 100   80                (30)  (0)  10 1.12 22 1.12           20 50 95   80        (60)  (0)  10 1.12 22 2.24           35 50 95   80               (30)      (0)  10 1.12 22 3.36           25 50 100   80               (50)  (0)     10 1.68 22 0.84           0  0 95   60               (0)  (0)  10 1.68     22 1.68           0  0 90   60               (0)  (0)  10 1.68 22 3.36             0  0 90   60               (0)  (0)  10 2.24 22 0.56     40 65 100   90               (38)  (0)  10 2.24 22 1.12           30 65     95   90               (53)  (0)  10 2.24 22 2.24           30  65 95     90               (53)  (0)  10 2.24 22 3.36           20 65 100   90               (69)  (0)  10 3.36 22 0.84           0 20 100  100       (100)  (0)  10 3.36 22 1.68           0 20 95  100               (100)      (5)  10 3.36 22 3.36           15 20 75  100               (25)  (25)     10 4.48 22 0.56           55 80 100  100               (31)  (0)  10     4.48 22 1.12           50 80 95  100               (37)  (5)  10 4.48 22     1.12           20 55               (63)  10 4.48 22 2.24           48 55                   (12)  10 4.48 22 2.24           60 80 100  100       (25)  (0)  10 4.48 22 3.36           50 80 100  100               (37)      (0)  10 4.48 22 4.48           32 55               (41)  10 4.48 22     8.96           32 55               (41)  10 6.72 22 0.56           70 90     100  100               (22)  (0)  10 6.72 22 0.84           0 55 95  100                   (100)  (5)  10 6.72 22 1.12           65 90 100  100             (27)  (0)  10 6.72 22 1.68           0 55 90  100     (100)  (10)  10 6.72 22 2.24           60 90 100  100               (33)      (0)  10 6.72 22 3.36           0 55 75  100               (100)  (25)     10 6.72 22 3.36           55 90 100  100               (38)  (0)  10     1.68 24 0.14           13 45 100  100               (71)  (0)  10 1.68     24 0.43           5 35 100  100               (85)  (0)  10 1.68 24 0.56               5 45 100  100               (88)  (0)  10 1.68 24 0.56       38 37 100  100               (0)  (0)  10 1.68 24 0.84           0 45     100  100               (100)  (0)  10 1.68 24 0.84           20 17 100     100               (0)  (0)  10 1.68 24 0.84           8 23 98  100             (65)  (2)  10 1.68 24 0.84           0 35 100  100     (100)   (0)  10 1.68 24 0.84           5 78 100  100               (93)     (0)  10 1.68 24 0.84           0  8 100  100               (100)  (0)     10 1.68 24 0.84           0  0 100  100               (0)  (0)  10 1.68     24 0.84           28 23 100  100               (0)  (0)  10 1.68 24 0.84               8 50 100  100               (84)  (0)  10 1.68 24 0.84       0  8 100  100               (100)  (0)  10 1.68 24 0.84           10     35 100  100               (71)  (0)  10 1.68 24 1.12           8 37 98     100               (78)  (2)  10 1.68 24 1.68           8 17 100  100               (52)  (0)  10 1.68 24 1.68           0 35 100  100       (100)  (0)  10 1.68 24 1.68           5 23 100  100               (78)      (0)  10 1.68 24 1.68           10 45 100  100               (77)  (0)     10 1.68 24 1.68           13 23 98  100               (43)  (2)  10 1.68     24 1.68           23 50 100  100               (54)  (0)  10 1.68 24     1.68           10 78 100  100               (87)  (0)  10 1.68 24 1.68             0  8 100  100               (100)  (0)  10 1.68 24 1.68      5 35 100  100               (85)  (0)  10 1.68 24 1.68           0  0     100  100               (0)  (0)  10 1.68 24 1.68           13  8 100     100               (0)  (0)  10 1.68 24 2.24           13 45 98  100              (71)  (2)  10 1.68 24 2.24           55 37 100  100       (0)  (0)  10 1.68 24 3.36           0 35 100  100               (100)     (0)  10 1.68 24 3.36           0 23 100  100               (100)  (0)     10 1.68 24 3.36           5 45 100  100               (88)  (0)  10 1.68     24 3.36           0 17 100  100               (100)  (0)  10 1.68 24     3.36           0  0 100  100               (0)  (0)  10 1.68 24 3.36           5  8 100  100               (37)  (0)  10 1.68 24 3.36           0     23 100  100               (100)  (0)  10 1.68 24 3.36           5  8 100      100               (37)  (0)  10 1.68 24 3.36           5 78 100  100                (93)  (0)  10 1.68 24 3.36           5 35 100  100        (85)  (0)  10 1.68 24 3.36           20 50 100  100     (60)  (0)  10 3.36 24 0.14           18 63 100  100               (71)     (0)  10 3.36 24 0.43           55 63 100  100               (12)  (0)     10 3.36 24 0.56           13 63 100  100               (79)  (0)  10     3.36 24 0.56           25 68 98  100               (63)  (2)  10 3.36 24     0.84           8 63 100  100               (87)  (0)  10 3.36 24 0.84            23 78 100  100               (70)  (0)  10 3.36 24 0.84     18 72 100  100               (75)  (0)  10 3.36 24 0.84           30 60     100  100               (50)  (0)  10 3.36 24 0.84           10 50 100     100               (80)  (0)  10 3.36 24 0.84           0 23 100  100               (100)  (0)  10 3.36 24 0.84           25 86 100  100         (70)   (0)  10 3.36 24 0.84           10  8 100  100     (0)  (0)  10 3.36 24 0.84           25 70 100  100               (64)     (0)  10 3.36 24 0.84           20 67 95  100               (70)  (5)  10     3.36 24 0.84           5 35 100  100               (85)  (0)  10 3.36 24     1.12           23 68 100  100               (66)  (0)  10 3.36 24 1.68             10 78 95  100               (87)  (5)  10 3.36 24 1.68     5 63 100  100               (92)  (0)  10 3.36 24 1.68           0 60     100  100               (100)  (0)  10 3.36 24 1.68           13 72 100     100               (81)  (0)  10 3.36 24 1.68           10 70 100  100                (85)  (0)  10 3.36 24 1.68           13 86 100  100         (84)  (0)  10 3.36 24 1.68           0 35 100  100     (100)  (0)  10 3.36 24 1.68           5 67 100  100               (92)     (0)  10 3.36 24 1.68           10 50 100  100               (80)  (0)     10 3.36 24 1.68           10  8 100  100               (0)  (0)  10 3.36     24 1.68           5 23 100  100               (78)  (0)  10 3.36 24 2.24               10 63 100  100               (84)  (0)  10 3.36 24 2.24        15 68 100  100               (77)  (0)  10 3.36 24 3.36           15     63 95  100               (76)  (5)  10 3.36 24 3.36           25 78 100     100               (67)  (0)  10 3.36 24 3.36           5 72 100  100               (93)  (0)  10 3.36 24 3.36           15 60 100   100         (75)  (0)  10 3.36 24 3.36           0  8 100  100     (100)  (0)  10 3.36 24 3.36           20 50 100  100               (60)     (0)  10 3.36 24 3.36           5 35 100  100               (85)  (0)  10     3.36 24 3.36           10 23 100  100               (56)  (0)  10 3.36     24 3.36           35 67 100  100               (47)  (0)  10 3.36 24     3.36           20 86 100  100               (76)  (0)  10 3.36 24 3.36             38 70 100  100               (45)  (0)  10 4.48 24 1.12      50 82               (39)  10 4.48 24 1.12           50 82     (39)  10 4.48 24 1.12           35 83               (57)  10 4.48 24     1.12           52 98               (46)  10 4.48 24 1.12           28 55                   (49)  10 4.48 24 2.24           45 83               (45)     10 4.48 24 2.24           8 55               (85)  10 4.48 24 2.24         48 98               (51)  10 4.48 24 2.24           35 82        (57)  10 4.48 24 2.24           28 82               (65)  10 4.48 24     4.48           25 82               (69)  10 4.48 24 4.48           22 83                   (73)  10 4.48 24 4.48           20 82               (75)     10 4.48 24 4.48           18 55               (67)  10 4.48 24 4.48          58 98               (40)  10 4.48 24 8.96           20 55         (63)  10 4.48 24 8.96           10 83               (87)  10 4.48 24     8.96           55 98               (43)  10 4.48 24 8.96           22 82                   (73)  10 4.48 24 8.96           15 82               (81)     10 6.72 24 0.14           45 88 100  100               (48)  (0)  10     6.72 24 0.43           68 88 100  100               (22)  (0)  10 6.72     24 0.56           25 88 100  100               (71)  (0)  10 6.72 24     0.56           30 82 100  100               (63)  (0)  10 6.72 24 0.84             33 85 100  100               (61)  (0)  10 6.72 24 0.84      55 88 100  100               (37)  (0)  10 6.72 24 0.84           13 88     100  100               (85)  (0)  10 6.72 24 0.84           35 93 100     100               (62)  (0)  10 6.72 24 0.84           35 67 100  100                (47)  (0)  10 6.72 24 0.84           33 87 100  100         (62)  (0)  10 6.72 24 0.84           25 45 100  100     (44)  (0)  10 6.72 24 0.84           73 98 100  100               (25)     (0)  10 6.72 24 0.84           8 58 100  100               (86)  (0)  10     6.72 24 0.84           23 88 12  100               (73)  (88)  10 6.72     24 0.84           5 70 100  100               (92)  (0)  10 6.72 24 1.12               15 82 100  100               (81)  (0)  10 6.72 24 1.68        40 93 95  100               (56)  (5)  10 6.72 24 1.68           18     85 100  100               (78)  (0)  10 6.72 24 1.68           8  88 100      100               (90)  (0)  10 6.72 24 1.68           20 88 100  100                 (77)  (0)  10 6.72 24 1.68           35 87 100  100          (59)  (0)  10 6.72 24 1.68           45 98 100  100     (54)  (0)  10 6.72 24 1.68           10 45 100  100               (77)     (0)  10 6.72 24 1.68           15 70 100  100               (78)  (0)     10 6.72 24 1.68           25 88 100  100               (71)  (0)  10     6.72 24 1.68           28 67 100  100               (58)  (0)  10 6.72     24 1.68           5 58 100  100               (91)  (0)  10 6.72 24 2.24               5 88 100  100               (94)  (0)  10 6.72 24 2.24       58 82 100  100               (29)  (0)  10 6.72 24 3.36           8 93     100  100               (91)  (0)  10 6.72 24 3.36           0 88 100     100               (100)  (0)  10 6.72 24 3.36           8 85 100  100                (90)  (0)  10 6.72 24 3.36           10 88 100  100         (88)  (0)  10 6.72 24 3.36           5 58 100  100     (91)  (0)  10 6.72 24 3.36           33 98 100  100               (66)     (0)  10 6.72 24 3.36           8 67 100  100               (88)  (0)  10     6.72 24 3.36           8 70 100  100               (88)  (0)  10 6.72 24     3.36           30 88 100  100               (65)  (0)  10 6.72 24 3.36             25 87 100  100               (71)  (0)  10 6.72 24 3.36      13 45 100  100               (71)  (0)  10 1.68 25 0.84           25 78     100  100               (67)  (0)  10 1.68 25 1.68           13 78 100     100               (83)  (0)  10 1.68 25 3.36           28 78 100  100                (64)  (0)  10 3.36 25 0.84           58 86 100  100         (32)  (0)  10 3.36 25 1.68           18 86 0  100               (79)      (0)  10 3.36 25 3.36           5 86 100  100               (94)  (0)     10 6.72 25 0.84           95 98 100  100               (3)  (0)  10 6.72     25 1.68           58 98 100  100               (40)  (0)  10 6.72 25     3.36           25 98 100  100               (74)  (0)  10 1.68 26 0.56             28 37 100  100               (0)  (24)  10 1.68 26 0.84      45 78 100  100               (42)  (0)  10 1.68 26 1.12           0 37     100  100               (100)  (0)  10 1.68 26 1.68           38 78 100     100               (51)  (0)  10 1.68 26 2.24           8 37 100  100               (78)  (0)  10 1.68 26 3.36           55 78 100  100        (29)  (0)  10 3.36 26 0.56           28 68 100  100     (58)  (0)  10 3.36 26 0.84           53 90 100  100               (41)     (0)  10 3.36 26 1.12           10 68 100  100               (85)  (0)     10 3.36 26 1.68           35 90 100  100               (61)  (0)  10     3.36 26 2.24           30 68 100  100               (55)  (0)  10 3.36     26 3.36           48 90 98  100               (46)  (2)  10 6.72 26 0.56               63 82 95  100               (23)  (5)  10 6.72 26 0.84       43 95 100  100               (54)  (0)  10 6.72 26 1.12           28     82 100  100               (65)  (5)  10 6.72 26 1.68           38 95 100      100               (60) (0)  10 6.72 26 2.24           23 82 100  100                (71)  (0)  10 6.72 26 3.36           53 95 100  100         (44)  (0)  10 1.68 27 0.14           8 45 100  100     (82)  (0)  10 1.68 27 0.56           13 45 100  100               (71)     (0)  10 1.68 27 0.56           10 37 100  100               (72)  (0)     10 1.68 27 0.84           43 78 100  100               (44)  (0)  10     1.68 27 1.12          23 37 100  100               (37)  (0)  10 1.68 27     1.68           40 78 100  100               (48)  (0)  10 1.68 27 2.24             8 45 100  100               (82)  (0)  10 1.68 27 2.24     8 37 98  100               (78)  (2)  10 1.68 27 3.36           53 78     100  100               (32)  (0)  10 3.36 27 0.14           30 63 100     100               (52)  (0)  10 3.36 27 0.56           18 63 100  100                (71)   (0)  10 3.36 27 0.56           8 68 100  100         (88)  (0)  10 3.36 27 0.84           35 90 100  100     (61)  (0)  10 3.36 27 1.12           10 68 100  100               (85)     (0)  10 3.36 27 1.68           30 90 100  100               (66)  (0)     10 3.36 27 2.24           10 63 100  100               (84)  (0)  10     3.36 27 2.24           23 68 100  100               (66)  (0)  10 3.36     27 3.36           45 90 100  100               (50)  (0)  10 6.72 27     0.14           75 88 100  100               (14)  (0)  10 6.72 27 0.56             30 88 100  100               (65)  (0)  10 6.72 27 0.56      43 82 100  100               (47)  (0)  10 6.72 27 0.84           45 95     100  100               (52)  (0)  10 6.72 27 1.12           5 82 100     100               (93)  (0)  10 6.72 27 1.68           53 95 100  100                (44)  (0)  10 6.72 27 2.24           18 88 100  100         (79)  (0)  10 6.72 27 2.24           18 82 100  100     (78)  (0)  10 6.72 27 3.36           40 95 98  100               (57)     (2)  10 1.68 28 0.56           25 37 98  100               (32)  (2)  10     1.68 28 1.12           0 37 100  100               (100)  (0)  10 1.68     28 2.24           5 37 100  100               (86)  (0)  10 3.36 28 0.56               65 68 100  100               (4)  (0)  10 3.36 28 1.12       20 68 100  100               (70)  (0)  10 3.36 28 2.24           50     68 98  100               (26)  (2)  10 4.48 28 1.12           38 82              (53)  10 4.48 28 2.24           22 82               (73)  10     4.48 28 4.48           42 82               (48)  10 4.48 28 8.96       15 82               (81)  10 6.72 28 0.56           50 82 100  100               (39)  (0)  10 6.72 28 1.12           43 82 100   100         (47)  (0)  10 6.72 28 2.24           20 82 100  100     (75)  (0)  10 1.68 29 0.84           45 78 100  100               (42)     (0)  10 1.68 29 0.84           30 27 100  100               (0)  (0)  10     1.68 29 1.68           15 27 100  100               (44)  (0)  10 1.68     29 1.68           33 78 100  100               (57)  (0)  10 1.68 29     3.36           40 78 100  100               (48)  (0)  10 1.68 29 3.36             23 27 100  100               (14)  (0)  10 3.36 29 0.84      15 33 100  100               (54)  (0)  10 3.36 29 0.84           13 90     100  100               (85)  (0)  10 3.36 29 1.68           8 33 100     100               (75)  (0)  10 3.36 29 1.68           38 90 100  100                (57)  (0)  10 3.36 29 3.36           13 33 100  100         (60)  (0)  10 3.36 29 3.36           33 90 100  100     (63)  (0)  10 6.72 29 0.84           58 95 100  100               (38)     (0)  10 6.72 29 0.84           38 53 100  100               (28)  (0)     10 6.72 29 1.68           48 53 100  100               (9)  (0)  10 6.72     29 1.68           45 95 100  100               (52)  (0)  10 6.72 29     3.36           38 53 100  100               (28)  (0)  10 6.72 29 3.36             68 95 100  100               (28)  (0)  10 1.68 30 0.14      8 45 100  100               (82)  (0)  10 1.68 30 0.56           5 45     100  100               (88)  (0)  10 1.68 30 0.84           35 38 100     100               (7)  (0)  10 1.68 30 0.84           5 23 100  100              (78)  (0)  10 1.68 30 1.68           13 38 100  100       (65)  (0)  10 1.68 30 1.68           8 23 100  100               (65)     (0)  10 1.68 30 2.24           8 45 100  100               (82)  (0)  10     1.68 30 3.36           30 38 100  100               (21)  (0)  10 1.68     30 3.36           15 23 100  100               (34)  (0)  10 3.36 30     0.14           5 63 100  100               (92)  (0)  10 3.36 30 0.56            8 63 100  100               (87)  (0)  10 3.36 30 0.84     15 67 100  100               (77)  (0)  10 3.36 30 0.84           15 68     100  100               (77)   (0)  10 3.36 30 1.68           23 67 100     100               (65)  (0)  10 3.36 30 1.68           28 68 100  100                (58)  (0)  10 3.36 30 2.24           10 63 100  100         (84)  (0)  10 3.36 30 3.36           13 67 100  100     (80)  (0)  10 3.36 30 3.36           0 68 100  100               (100)     (0)  10 6.72 30 0.14           48 88 100  100               (45)  (0)     10 6.72 30 0.56           18 88 100  100               (79)  (0)  10     6.72 30 0.84           73 92 100  100               (20)  (0)  10 6.72     30 0.84           33 88 100  100               (62)  (0)  10 6.72 30     1.68           40 88 100  100               (54)  (0)  10 6.72 30 1.68             40 92 100  100               (56)  (0)  10 6.72 30 2.24      18 88 100  100               (79)  (0)  10 6.72 30 3.36           30 92     100  100               (67)  (0)  10 6.72 30 3.36           30 88 100     100               (65)  (0)  10 1.68 31 0.84           10 23 100  100                (56)  (0)  10 1.68 31 1.68           8 23 100  100        (65)  (0)  10 1.68 31 3.36           5 23 100  100               (78)      (0)  10 3.36 31 0.84           38 67 100  100               (43)  (0)     10 3.36 31 1.68           13 67 100  100               (80)  (0)  10     3.36 31 3.36           10 67 100  100               (85)  (0)  10 6.72     31 0.84           30 88 100  100               (65)  (0)  10 6.72 31     1.68           25 88 100  100               (71)  (0)  10 6.72 31 3.36             30 88 100  100               (65)  (0)  10 1.68 32 0.84      18 28 100  100               (35)  (0)  10 1.68 32 1.68           23 28     100  100               (17)  (0)  10 1.68 32 3.36           0 28 100     100               (100)  (0)  10 3.36 32 0.84           30 53 100  100                 (43)  (0)  10 3.36 32 1.68           15 53 100  100          (71)  (0)  10 3.36 32 3.36           15 53 100  100     (71)  (0)  10 6.72 32 0.84           45 90 100  100               (50)     (0)  10 6.72 32 1.68           33 90 100  100               (63)  (0)     10 6.72 32 3.36           33 90 100  100               (63)  (0)  10     1.68 33 0.14           23 45 100  100               (48)  (0)  10 1.68     33 0.56           18 45 100  100               (60)  (0)  10 1.68 33     0.84           8 42 100  100               (80)  (0)  10 1.68 33 1.68            15 42 100  100               (64)  (0)  10 1.68 33 2.24     5 45 100  100               (88)  (0)  10 1.68 33 3.36           5 42     100  100               (88)  (0)  10 3.36 33 0.14           45 63 100     100               (28)  (0)  10 3.36 33 0.56           28 63 100  100                (55)  (0)  10 3.36 33 0.84           13 70 100  100         (81)  (0)  10 3.36 33 1.68           13 70 100  100     (81)  (0)  10 3.36 33 2.24           8 63 100  100               (87)     (0)  10 3.36 33 3.36           18 70 100  100               (74)  (0)     10 6.72 33 0.14           80 88 100  100               (9)  (0)  10 6.72     33 0.56           60 88 100  100               (31)  (0)  10 6.72 33     0.84           40 72 100  100               (44)  (0)  10 6.72 33 1.68             28 72 100  100               (61)  (0)  10 6.72 33 2.24      18 88 100  100               (79)  (0)  10 6.72 33 3.36           13 72     100  100               (81)  (0)  10 1.68 34 0.14           13 45 100     100               (71)  (0)  10 1.68 34 0.56           10 45 100  100                (77)  (0)  10 1.68 34 0.84           10 42 100  100         (76)  (0)  10 1.68 34 1.68           8 42 100  100     (80)  (0)   10 1.68 34 2.24           10 45 100  100               (77)     (0)  10 1.68 34 3.36           8 42 100  100               (80)  (0)  10     3.36 34 0.14           50 63 100  100               (20)  (0)  10 3.36     34 0.56           18 63 100  100               (71)  (0)  10 3.36 34     0.84           28 70 100  100               (60)  (0)  10 3.36 34 1.68             8 70 100  100               (88)  (0)  10 3.36 34 2.24     10 63 100  100               (84)  (0)  10 3.36 34 3.36           8 70     100  100               (88)  (0)  10 6.72 34 0.14           50 88 100     100               (43)  (0)  10 6.72 34 0.56           40 88 100  100                (54)  (0)  10 6.72 34 0.84           30 72 100  100         (58)  (0)  10 6.72 34 1.68           33 72 100  100     (54)  (0)  10 6.72 34 2.24           20 88 100  100               (77)     (0)  10 6.72 34 3.36           13 72 100  100               (81)  (0)     10 1.68 35 0.14           10 45 100  100               (77)  (0)  10     1.68 35 0.56           8 45 100  100               (82)  (0)  10 1.68 35     0.84           15 55 100  100               (72)  (0)  10 1.68 35 1.68             25 55 100  100               (54)  (0)  10 1.68 35 2.24      0 45 98  100               (100)  (0)  10 1.68 35 3.36           8 55     100  100               (85)  (0)  10 3.36 35 0.14           45 63 100     100               (28)  (0)  10 3.36 35 0.56           20 63 100  100                (68)  (0)  10 3.36 35 0.84           40 93 98  100        (56)  (2)  10 3.36 35 1.68           23 93 100  100     (75)  (0)  10 3.36 35 2.24           8 63 100  100               (87)     (0)  10 3.36 35 3.36           23 93 100  100               (75)  (0)     10 6.72 35 0.14           65 88 100  100               (26)  (0)  10     6.72 35 0.56           13 88 100  100               (85)  (0)  10 6.72     35 0.84           40 98 100  100               (59)  (0)  10 6.72 35     1.68           38 98 100  100               (61)  (0)  10 6.72 35 2.24             13 88 100  100               (85)  (0)  10 6.72 35 3.36      18 98 100  100               (81)  (0)  10 1.68 36 0.84           0   0     100  100               (0)  (0)  10 1.68 36 1.68           0  0 100  100                   (0)  (0)  10 1.68 36 3.36           0  0 100  100          (0)  (0)  10 3.36 36 0.84           15 8 100  100               (0)      (0)  10 3.36 36 1.68           15 8 100  100               (0)  (0)  10     3.36 36 3.36           13  8 100  100               (0)  (0)  10 6.72 36     0.84           30 70 100  100               (57)  (0)  10 6.72 36 1.68             35 70 100  100               (50)  (0)  10 6.72 36 3.36      18 70 100  100               (74)  (0)  11 1.12  1 1.12   80   99     (19)  11 1.12  1 2.24   72  99       (27)  11 1.12  1 4.48   60   99       (39)  11 1.12  1 8.96   52   99       (47)  11 1.12   4 1.12   80   99           (19)  11 1.12  4 2.24   58   99       (41)  11 1.12  4 4.48   45     99       (54)  11 1.12  4 8.96   35   99       (64)  11 1.12  5 1.12     68   99       (31)  11 1.12  5 2.24   42   99       (57)  11 1.12  5     4.48   48   99       (51)  11 1.12  5 8.96             42   99           (57)  11 1.12 15 1.12             55   99                 (44)  11     1.12 15 2.24             60   99                 (39)  11 1.12 15 4.48               58   99                 (41)  11 1.12 15 8.96             55     99                 (44)  11 1.12 18 1.12             50   99         (49)  11 1.12 18 2.24             70   99                 (29)  11     1.12 18 4.48             50   99                 (49)  11 1.12 18 8.96               62   99                 (37)  11 1.12 23 0.14      85   85 98      98       20   37          (0)  (0)        (45)  11 1.12 23 0.56      95       85 90   98       20   37          (0)  (8)        (45)  11 1.12 23     2.24      95   85 90   98       50   37          (0)  (8)        (0)  11     2.24 23 0.14      85   95 98   98       53   53          (10)  (0)      (0)  11 2.24 23 0.56      95   95 90   98       43   53          (0)     (8)        (0)  11 2.24 23 2.24      95   95 85   98       55   53        (0)  (13)        (0)  11 4.48 23 0.14      95   95 98  100       63     70          (0)  (2)        (10)  11 4.48 23 0.56      98   95 98  100         50   70          (0)  (2)        (28)  11 4.48 23 2.24      98   95     100  100       40   70          (0)  (0)        (42)  11 1.12 29 0.14       95   95 98   90       20   50          (0)  (0)        (60)  11 1.12     29 0.56      95   95 90   90       20   50          (0)  (0)        (60)      11 1.12 29 2.24      95   98 60   90       35   50          (10)  (33)           (30)  11 2.24 29 0.14      95   98 90   98       30   52     (3)  (8)        (42)  11 2.24 29 0.56      95   98 95   98       33   52              (3)  (3)        (36)  11 2.24 29 2.24      95   98 90   98      43   52          (3)  (8)        (17)  11 4.48 29 0.14      95    98 95       98       48   60          (3)  (3)        (20)  11 4.48 29 0.56     95   98 95   98       53   60          (3)  (3)        (11)  11 4.48 29     2.24      100   98 95   98       53   60          (0)  (3)        (11)     6 2.24 10 0.56   35   96 99   99    97  97    99  100       (63)  (0)      (0)     (1)   6 2.24 10 1.12 50  80  30   92     (37)   (67)   6 2.24     10 1.12 62  62  62  100     (0)   (38)   6 2.24 10 2.24 35  80  40   92        (56)   (56)   6 2.24 10 2.24 45  62  58  100     (27)   (42)   6 2.24     10 2.24   65   96 100   99    99  97    99  100       (32)  (0)     (0)      6 2.24 10 4.48 48  62  35  100     922)   (65)   6 2.24 10 4.48 35  80     25   92     (56)   (72)   6 2.24 10 8.96 35  62  20  100     (43)   (80)       6 2.24 10 8.96 30  80  22   92     (62)   (76)   6 0.03 11 0.03   5     35 80   78  48   40 45   43 85  78 88  90 100 100       (85)  (0)   (0)     (0)  (0)  (0)  (0)   6 0.03 11 0.14   5   35 85   78  40   40 38   43 85      78 85  90 100 100       (85)  (0)   (0)  (11)  (0)  (5)  (0)   6 0.03     11 0.56   0   35 80   78  30   40 33   43 78  78 93  90 100 100     (100)  (0)   (25)  (23)  (0)  (0)  (0)   6 0.14 11 0.03   55   83 95     90  80   80 65   83 95  93 98  99 100 100       (33)  (0)   (0)  (21)     (0)  (1)  (0)   6 0.14 11 0.14   50   42 90   90    97  78    97   80        (0)  (0)     (0)     (0)   6 0.14 11 0.14   38   83 95   90  80   80     80   83 93  93 97  99 100 100       (54)  (0)   (0)  (3)  (0)  (2)  (0)      6 0.14 11 0.56   35   42 93   90    90  78    93   80       (16)  (0)       (0)     (0)   6 0.14 11 0.56   15   83 94   90  60   80 55   83 94  93     99  99 100 100       (81)  (0)   (25)   (33)  (0)  (0)  (0)   6 0.14 11     2.24   17   42 95   90    99  78    97   80       (59)  (0)     (0)     (0)   6 0.14 11 2.24   28   83 93   90  50   80 48   83 93  93 99  99     100 100       (66)  (0)   (37)  (42)  (0)  (0)  (0)   6 0.56 11 0.03     95   98 98   98  93   97 90   94 97  98 100 100 100 100       (3)  (1)     (4)  (4)  (1)  (0)  (0)   6 0.56 11 0.14   73   70 92   97    90  93     99   99       (0)  (5)     93)     (0)   6 0.56 11 0.14   85   98 98     98  97   97 97   94 98  98 99 100 100 100       (13)  (0)   (0)  (0)     (0)  (1)  (0)   6 0.56 11 0.56   70   98 98   98  98   97 88   94 98  98     100 100 100 100       (28)  (0)   (0)  (6)  (0)  (0)  (0)   6 0.56 11     0.56   70   70 92   97    99  93    97   99       (0)  (5)     (0)     (2)   6 0.56 11 2.24   52   98 98   98  98   97 70   94 98  98 100 100     100 100       (46)   (0)   (0)  (25)  (0)  (0)  (0)   6 0.56 11 2.24     40   70 99   97    99  93    87   99       (42)  (0)     (0)     (12)     6 2.24 11 0.03   98   99 98   99  97   99 92   99 99  99 100 100 100 100           (1)  (1)   (2)  (7)  (0)  (0)  (0)   6 2.24 11 0.14   99   99 99     99  99   99 99   99 99  99 100 100 100 100       (0)  (0)   (0)  (0)     (0)  (0)  (0)   6 2.24 11 0.14   80   88 99   99    99  99    97   99        (9)  (0)     (0)     (2)   6 2.24 11 0.56   94   99 100   99  99   99     99   99 99  99 100 100 100 100       (5)  (0)   (0)  (0)  (0)  (0)  (0)      6 2.24 11 0.56   75   88 99   99    99  99    99   99       (14)  (0)       (0)     (0)   6 2.24 11 2.24   68   88 99   99    99  99    92   99        (22)  (0)     (0)     (7)   6 2.24 11 2.24   60   99 99   99  98   99     94   99 99  99 100 100 100 100       (39)   (0)   (1)  (5)  (0)  (0)     (0)   6 4.48 11 0.03   97  100 100  100  99  100 99  100 100 100 100 100     100 100       (3)  (0)   (1)  (1)  (0)  (0)  (0)   6 4.48 11 0.14   97     100 100  100  99  100 100  100 100 100 100 100 100 100       (3)  (0)     (1)  (0)  (0)  (0)  (0)   6 4.48 11 0.56   98  100 99  100  99  100 99     100 99 100 100 100 100 100       (2)  (1)   (1)  (1)  (1)  (0)  (0)   6     4.48 11 2.24   80  100 99  100  99  100 99  100 99 100 100 100 100 100         (20)  (1)   (1)  (1)  (1)  (0)  (0)   6 2.24 12 1.12 62  80  55   92         (22)   (40)   6 2.24 12 2.24 55  80  40   92     (31)   (56)   6     2.24 12 4.48 52  80  35   92     (35)   (61)   6 2.24 12 8.96 35  80  30       92     (56)   (67)   6 2.24 13 1.12 65  80  85   92     (18)   (7)   6     2.24 13 1.12 68  70  100   98     (2)   (0)   6 2.24 13 2.24 60  80  75      92     (25)   (18)   6 2.24 13 2.24 68  70  100   98     (2)   (0)   6     2.24 13 4.48 58  80  60   92     (27)   (34)   6 2.24 13 4.48 65  70  98       98     (7)   (0)   6 2.24 13 8.96 58  80  55   92     (27)   (40)   6     2.24 13 8.96 60  70  100   98     (14)   (0)   6 2.24 14 1.12 55  80  90       92     (31)   (2)   6 2.24 14 2.24 42  80  60   92     (47)   (34)   6     2.24 14 4.48 48  80  55   92     (40)   (40)   6 2.24 14 8.9645  80  30      92     (43)   (67)   6 2.24 15 1.12 85  95  60  100     (10)   (40)   6     2.24 15 2.24 75  95  45  100     (21)   (55)   6 2.24 15 4.48 68  95  35      100     (28)   (65)   6 2.24 15 8.96 50  95  55  100     (47)   (45)     6 2.24 16 1.12 62  80  55   92     (22)   (40)   6 2.24 16 2.24 50  80     45   92     (37)   (51)   6 2.24 16 4.48 42  80  30   92     (47)   (67)       6 2.24 16 8.96 32  80  30   92     (60)   (67)   6 0.14 17 0.14 30  65      88   93 67   80     (53)   (5)  (16)   6 0.14 17 0.5625  65  95   93 80       80     (61)   (0)  (0)   6 0.14 17 2.24 15  65  80   93 95   80     (76)   (13)  (0)   6 0.56 17 0.14   73   90 97   99        99   97     (18)  (2)         (0)   6 0.56 17 0.56   73   90 97   99        100   97           (18)  (2)         (0)   6 0.56 17 2.24   50   90 93   99        95       97       (44)  (6)         (2)   6 2.24 17 0.14   90   97 99  100       100   99       (7)  (1)         (0)   6 2.24 17 0.56   85   97 100     100        99   99       (12)  (0)         (0)   6 2.24 17 2.24   85     97 100  100        100   99       (12)  (0)         (0)   6 2.24 18 1.12     50  95  45  100     (47)   (55)   6 2.24 18 2.24 70  95  45  100     (26)   (55)   6 2.24 18 4.48 65  95  40  100     (31)   (60)   6 2.24 18     8.96 45  95  35  100     (52)   (65)   6 2.24 19 1.12 60  80 65   92     (25)  (29)   6 2.24 19 2.24 55  80  50   92     (31)   (45)    6 2.24 19     4.48 52  80  25   92     (35)   (72)   6 2.24 19 8.96 58  80  20   92      (27)   (78)   6 2.24 20 1.12 35  80  48   92     (56)   (47)   6 2.24     20 2.24 60  80  55   92     (25)   (40)   6 2.24 20 4.48 58  80  35   92         (27)   (61)   6 2.24 20 8.96 48  80  10   92     (40)   (89)   6     2.24 22 1.12 35  62  95  100     (43)   (5)   6 2.24 22 2.24 70  62  95     100     (0)   (5)   6 2.24 22 4.48 65  62  80  100     (0)   (20)   6     2.24 22 8.96 72  62  60  100     (0)   (40)   6 0.14 23 0.14 10  30 0     35  30 60     (66)  (100)   (50)   6 0.14 23 0.14 65  70 90   73  100     90 98 98     (7)  (0)   (0)  (0)   6 0.14 23 0.14 58  37 60   70  90     85 85 98     (0)  (14)   (0)  (13)   6 0.14 23 0.14 20  20 40   60  90     85 0 45     (0)  (33)   (0)  (100)   6 0.14 23 0.56 10  30 30   35   30     60     (66)  (14)    (50)   6 0.14 23 0.56 13  20 35   60  90   85 70 45         (35)  (41)   (0)  (0)    6 0.14 23 0.56 60  70 90   73  80   90 40     98     (14)  (0)   (11)  (59)   6 0.14 23 0.56 40  37 80   70  90   85     80 98     (0)  (0)   (0)  (18)   6 0.14 23 2.24 10  30 0   35   20 60      (66)  (100)    (66)   6 0.14 23 2.24 43  37 80   70  90   85 60 98     (0)  (0)   (0)  (38)   6 0.14 23 2.24 5  20 35   60  85   85 0 45     (75)  (41)   (0)  (100)   6 0.14 23 2.24 45  70 73   73  80   90 0 98      (35)  (0)   (11)  (100)   6 0.56 23 0.14 85  70 85   90  98   85 95 100         (0)  (5)   (0)  (5)   6 0.56 23 0.14 15  45 60   90   80 83     (66)      (33)    (3)   6 0.56 23 0.14 70  82    100 100     (14)    (0)   6 0.56     23 0.14 53  50 85   75  98   90 80 75     (0)  (0)   (0)  (0)   6 0.56     23 0.14 98  83 98   95  98   90 98 100     (0)  (0)   (0)  (2)   6 0.56     23 0.14 100  78 100   95  100  100 100 98     (0)  (0)   (0)  (0)   6     0.56 23 0.28 30  15 75   90   30 78     (0)  (16)    (61)   6 0.56 23     0.56 60   70 100   90  98   85 88 100     (14)  (0)   (0)  (12)   6 0.56     23 0.56 63  78 90   95  100  100 95 98     (19)  (5)   (0)  (3)   6 0.56     23 0.56 85  82    95 100     (0)     (5)   6 0.56 23 0.56 20  45 40   90       60 83     (55)  (55)    (27)   6 0.56 23 0.56 38  50 90   75  95   90     60 75     (24)  (0)   (0)  (20)   6 0.56 23 0.56 90  83 95   95  95   90     100 100     (0)  (0)   (0)  (0)   6 0.56 23 2.24 78  78 90   95  100     100 90 98     (0)  (5)   (0)   (8)   6 0.56 23 2.24 73  70 85   90  100      85 75 100     (0)  (5)   (0)  (25)   6 0.56 23 2.24 43  50 50   75  95      90 78 75     (14)  (33)   (0)  (0)   6 0.56 23 2.24 0  15 70   90   0     78     (100)  (22)    (100)   6 0.56 23 2.24 65  82    95 100     (20)       (5)   6 0.56 23 2.24 88  83 95   95  100   90 95 100     (0)  (0)     (0)  (5)   6 0.56 23 2.24 15  45 80   90   40 83     (66)  (11)    (51)      6 0.84 23 0.14 45  70 90   95  100  100     (35)   (5)   (0)   6 0.84     23 0.14 30  42 90   90  100  100     (28)  (0)   (0)   6 0.84 23 0.14 15      41 90   90  100  100     (63)  (0)   (0)   6 0.84 23 0.14 45  53 75     60  100  100     (15)  (0)   (0)   6 0.84 23 0.14 98  82 100   98  100     100 100 100     (0)  (0)   (0)  (0)   6 0.84 23 0.14 45  35 70   85  100      100     (0)  (17)   (0)   6 0.84 23 0.14 85  70 85  100  100  100     (0)  (15)   (0)   6 0.84 23 0.14 30  58 95   95  100  100     (48)  (0)      (0)   6 0.84 23 0.14 43  15 85   60  100  100     (0)  (0)   (0)   6     0.84 23 0.14 15  43 80   73  95   95 50 63     (65)  (0)   (0)  (20)   6     0.84 23 0.14 10  20 95   60  100  100     (50)  (0)   (0)   6 0.84 23     0.14 50  48 90   90  100  100     (0)  (0)   (0)   6 0.84 23 0.14 23  27     100  100  100  100     (14)  (0)   (0)   6 0.84 23 0.14 30  83 0   98     100  100 90 100     (63)  (100)   (0)  (10)   6 0.84 23 0.56 48  58 95     95  100  100     (17)  (0)   (0)   6 0.84 23 0.56 25  42 60   90  100     100     (40)  (33)   (0)

EXAMPLE 291

The procedure of Example 285 was followed to determine the interactionbetween various combinations of herbicide and antidotes whenincorporated in a soil cover layer before emergence of rice andbarnyardgrass. The tested combinations included mixtures of twodifferent antidotes in combination against various herbicides. Thecombinations of antidotes included an antidote of the invention, i.e.,benzhydryl compound ™1 or υ24, and a commercially-known antidote,namely, the compound 4,6-dichloro-2'-phenylpyrimidine (commonly known as"CGA-123407" and designated as "CGA" in Tables VIII-A and VIII-B), whichis sold in combination with the herbicide pretilachlor by Ciba-GeigyCorporation, Ardsley, N.Y. The herbicide a compounds tested werebutachlor (herbicide ™10), metolachlor (herbicide ™14), benthiocarb(herbicide ™36) and pretilachlor (herbicide ™37). Results are reportedin Tables VIII-A and VIII-B.

                  TABLE VIII-A                                                    ______________________________________                                                              % Inhibition                                            Herbicide                                                                             Rate    Antidote* Rate         Barnyard-                              No.     kg/ha   No.       kg/ha   Rice grass                                  ______________________________________                                        37      0.83    --        0       35   100                                    37      0.83     1 + CGA  0.28 + 0.28                                                                            5    90                                    37      0.83    24 + CGA  0.28 + 0.28                                                                           10   100                                    37      0.83     1 + CGA  1.12 + 1.12                                                                            5   100                                    37      0.83    24 + CGA  1.12 + 1.12                                                                           10   100                                    37      0.83     1 + CGA  4.48 + 4.48                                                                           10   100                                    37      0.83    24 + CGA  4.48 + 4.48                                                                           10   100                                    37      3.36    --        0       65   100                                    37      3.36     1 + CGA  0.28 + 0.28                                                                           10   100                                    37      3.36    24 + CGA  0.28 + 0.28                                                                           20   100                                    37      3.36     1 + CGA  1.12 + 1.12                                                                            5   100                                    27      3.36    24 + CGA  1.12 + 1.12                                                                           10   100                                    37      3.36     1 + CGA  4.48 + 4.48                                                                           10   100                                    37      3.36    24 + CGA  4.48 + 4.48                                                                           30   100                                    10      1.68    --        0       58   100                                    10      1.68     1 + CGA  0.28 + 0.28                                                                           15   100                                    10      1.68    24 + CGA  0.28 + 0.28                                                                           10   100                                    10      1.68     1 + CGA  1.12 + 1.12                                                                           30   100                                    10      1.68    24 + CGA  1.12 + 1.12                                                                           10   100                                    10      1.68     1 + CGA  4.48 + 4.48                                                                           35   100                                    10      1.68     1 + CGA  4.48 + 4.48                                                                           35   100                                    10      6.72    --        0       95   100                                    10      6.72     1 + CGA  0.28 + 0.28                                                                           40   100                                    10      6.72    24 + CGA  0.28 + 0.28                                                                           35   100                                    10      6.72     1 + CGA  1.12 + 1.12                                                                           30   100                                    10      6.72    24 + CGA  1.12 + 1.12                                                                           45   100                                    10      6.72     1 + CGA  4.48 + 4.48                                                                           60   100                                    10      6.72    24 + CGA  4.48 + 4.48                                                                           35   100                                    14      0.43    --        0       58    95                                    14      0.43     1        0.56    30    95                                    14      0.43    24        0.56    10    95                                    14      0.43     1        2.24    45    90                                    14      0.43    24        2.24    25   100                                    14      0.43     1        8.96    50   100                                    14      0.43    24        8.96    35    80                                    14      1.68    --        0       85   100                                    14      1.68     1        0.56    65   100                                    14      1.68    24        0.56    75   100                                    14      1.68     1        2.24    65   100                                    14      1.68    24        2.24    65   100                                    14      1.68     1        8.96    60   100                                    14      1.68    24        8.96    45   100                                    36      4.48    --        0       85   100                                    36      4.48     1        0.56    75   100                                    36      4.48    24        0.56    95   100                                    36      4.48     1        2.24    70   100                                    36      4.48    24        2.24    85   100                                    36      4.48     1        8.96    85   100                                    36      4.48    24        8.96    80   100                                    36      8.96    --        0       97   100                                    36      8.96     1        0.56    95   100                                    36      8.96    24        0.56    80   100                                    36      8.96     1        2.24    95   100                                    36      8.96    24        2.24    95   100                                    36      8.96     1        8.96    90   100                                    36      8.96    24        8.96    90   100                                    ______________________________________                                         *CGA = CGA123407 antidote compound                                       

                  TABLE VIII-B                                                    ______________________________________                                                                       %                                                                Herb-        Rice Inhibition by Rate                        Antidote*                                                                             Rate      icide        of Herbicide (kg/ha)                           No.     kg/ha     No.     0.28 0.56 1.68 3.36 6.72                            ______________________________________                                        --      0         37      25   52   90   92   98                              1 + CGA 0.28 + 0.28                                                                             37       0    5    0   30   70                              1 + CGA 1.12 + 1.12                                                                             37       5   15   15   10   10                              1 + CGA 4.48 + 4.48                                                                             37       5   35    5   25   45                              --      0         14      78   95   95   98   100                             1 + CGA 0.28 + 0.28                                                                             14      30   60   65   95   100                             1 + CGA 1.12 + 1.12                                                                             14      25   25   95   90   100                             1 + CGA 4.48 + 4.48                                                                             14      15   20   55   95   95                              --      0         10      55   35   83   87   95                              1 + CGA 0.28 + 0.28                                                                             10       0   35   10   10   60                              1 + CGA 1.12 + 1.12                                                                             10      35     5   5   50   50                              1 + CGA 4.48 + 4.48                                                                             10      45   30    5   75   80                              ______________________________________                                         *CGA = CGA123407 Antidote Compound                                       

EXAMPLE 292

The following procedure shows interaction between herbicide and antidotewhen applied together as a mixture in puddle seeded rice conditionscharacteristic of Asian rice-growing methods. This test included a tankmixture of butachlor (herbicide ™10) plus DPX-5384 (herbicide ™38) plusbenzhydryl antidote compound ™1. The combination of butachlor plusDPX-5384 provides broad spectrum control of the most troublesome weedsfound in rice. An untreated control pan, a herbicide control pan and aherbicide antidote test pan were filled with 5 cm of Ray silt loam soilsaturated with water and were placed in a greenhouse. Pre-germinatedrice seed, previously soaked in water for 24 hours followed by a 24-hourmoist incubation period, was sown on to the wet soil surface. Labelle, along-grain Indica type seed, and S-201, a short-grain Japonica typeseed, were used for the test. The rice seed was pressed lightly into thesoil to cover the seeds. Two weed species, barnyardgrass (an annualgrass) and Sagittaria pygmaea (a perennial broadleaf weed) were alsoseeded into the pans seeded with rice. Barnyardgrass was sown onto thesoil in a manner similar to rice seed. Sagittaria pygmaea was pressedabout 1-2 cm below the soil surface. The tank mixtures were applied tothe soil by a track sprayer. The pans were placed in watering trays andthe water level was maintained to assure saturated soil conditionsthroughout the duration of the test. Greenhouse temperature was 27° C.at night and 29° C. in daytime. A tank mix ratio of 2:1butachlor:antidote ™1 (1.68/kg/ha:0.84 kg/ha) showed complete ricesafening. The tank mixtures containing butachlor+ DPX-5384 were alsosafened with antidote ™1 to a degree equivalent to butachlor+antidote ™1mixtures, along with excellent control of barnyardgrass and Sagittariapygmaea weeds. Results are reported in Table IX.

                                      TABLE IX                                    __________________________________________________________________________                       % Plant Inhibition                                         *Herbicide                                                                              Rate                                                                             *Antidote                                                                           Labelle                                                                            S-201                                                                             Barnyard-                                                                           Sagittaria                                  #10     & #38                                                                              #1    Rice Rice                                                                              grass pygmaea                                     __________________________________________________________________________    --        -- --     0    0  --     0                                          0.56      -- --    30   10  70     30                                         1.68      -- --    95   90  98     80                                         4.48      -- --    100  95  100    90                                         --        -- 0.28   0    0   0     0                                          --        -- 0.84   0    0   0     0                                          --        -- 2.24   0    0   0     0                                          0.56      -- 0.28  10   10  80     40                                         1.68      -- 0.84   0    0  90     40                                         4.48      -- 2.24  60   40  99     90                                         --        0.025                                                                            --    10    0  10    100                                         --        0.050                                                                            --    20    0  10    100                                         --        0.025                                                                            2.24   0    0  10    100                                         --        0.050                                                                            2.24  10    0  10    100                                         0.56      0.025                                                                            --    20    0  60    100                                         1.68      0.025                                                                            --    95   90  90    100                                         4.48      0.025                                                                            --    98   95  99    100                                         0.56      0.025                                                                            0.28   0    0  70    100                                         1.68      0.025                                                                            0.84  20    0  80    100                                         4.48      0.025                                                                            2.24  50   20  95    100                                         0.56      0.050                                                                            --    30   10  80    100                                         1.68      0.050                                                                            --    80   70  90    100                                         4.48      0.050                                                                            --    100  95  99    100                                         0.56      0.050                                                                            0.28  20    0  60    100                                         1.68      0.050                                                                            0.84  20   10  80    100                                         4.48      0.050                                                                            2.24  20   10  90    100                                         __________________________________________________________________________     *In kg/ha                                                                

The foregoing examples illustrate that the benzhydryl-type antidotecompounds of this invention are useful in reducing herbicidal injury tocrop plants under greenhouse test conditions.

In field applications, the herbicide, antidote, or a mixture thereof,may be applied to the plant locus without any adjuvants other than asolvent. Usually, the herbicide, antidote, or a mixture thereof, isapplied in conjunction with one or more adjuvants in liquid or solidform. Compositions or formulations containing mixtures of an appropriateherbicide and antidote usually are prepared by admixing the herbicideand antidote with one or more adjuvants such as diluents, solvents,extenders, carriers, conditioning agents, water, wetting agents,dispersing agents, or emulsifying agents, or any suitable combination ofthese adjuvants. These mixtures may be in the form of particulatesolids, granules, pellets, wettable powders, dusts, solutions, aqueousdispersions, or emulsions.

Examples of suitable adjuvants are finely-divided solid carriers andextenders including talcs, clays, pumice, silica, diatomaceous earth,quartz, Fuller's earth, sulfur, powdered cork, powdered wood, walnutflour, chalk, tobacco dust, charcoal, and the like. Typical liquiddiluents include Stoddard's solvent, acetone, methylene chloride,alcohols, glycols, ethyl acetate, benzene, and the like. Liquids andwettable powders usually contain as a conditioning agent one or moresurface-active agents in amounts sufficient to make a compositionreadily dispersible in water or in oil. The term "surface-active agent"includes wetting agents, dispersing agents, suspending agents, andemulsifying agents. Typical surface-active agents are mentioned in U.S.Pat. No. 2,547,724.

Compositions of this invention generally contain from about 5 to 95parts herbicide-and-antidote, about 1 to 50 parts surface-active agent,and about 4 to 94 parts solvent, all parts being by weight based on thetotal weight of the composition.

Application of the herbicide, antidote, or mixture thereof, can becarried out by conventional techniques utilizing, for example,hand-carried or tractor-mounted spreaders, power dusters, boom and handsprayers, spray dusters, and granular applicators. If desired,application of the compositions of the invention to plants can beaccomplished by incorporating the compositions in the soil or othermedia.

The crop may be protected by treating the crop seed with an effectiveamount of antidote prior to planting. Generally, smaller amounts ofantidote are required to treat such seeds. A weight ratio of as littleas 0.6 parts of antidote per 1000 parts of seed may be effective. Theamount of antidote utilized in treating the seed may be increased ifdesired. Generally, however, a weight ratio of antidote-to-seed weightmay range from 0.1 to 10.0 parts of antidote per 1000 parts of seed.Since only a very small amount of active antidote is usually requiredfor the seed treatment, the compound preferably is formulated as anorganic solution, powder, emulsifiable concentrate, water solution, orflowable formulation, which can be diluted with water by the seedtreater for use in seed treating apparatus. Under certain conditions, itmay be desirable to dissolve the antidote in an organic solvent orcarrier for use as a seed treatment or the pure compound alone may beused under properly controlled conditions.

For antidote seed-coating or for antidotes applied to soil in granularor liquid formulations, suitable carriers may be either solids, such astalc, sand, clay, diatomaceous earth, sawdust, calcium carbonate, andthe like, or liquids, such as water, kerosene, acetone, benzene,toluene, xylene, and the like, in which the active antidote may beeither dissolved or dispersed. Emulsifying agents are used to achieve asuitable emulsion if two immiscible liquids are used as a carrier.Wetting agents may also be used to aid in dispersing the active antidotein liquids used as a carrier in which the antidote is not completelysoluble. Emulsifying agents and wetting agents are sold under numeroustradenames and trademarks and may be either pure compounds, mixtures ofcompounds of the same general groups, or they may be mixtures ofcompounds of different classes. Typical satisfactory surface activeagents which may be used are alkali metal higher-alkylarylsulfonatessuch as sodium dodecylbenzenesulfonate, and the sodium salts ofalkylnaphthalenesulfonic acids, fatty alcohol sulfates such as thesodium salts of monoesters of sulfuric acid with n-aliphatic alcoholscontaining 8-18 carbon atoms, long-chain quaternary ammonium compounds,sodium salts of petroleum-derived alkylsulfonic acids, polyethylenesorbitan monooleate, alkylaryl polyether alcohols, water-soluble ligninsulfonate salts, alkali casein compositions, longchain alcohols usuallycontaining 10-18 carbon atoms, and condensation products of ethyleneoxide with fatty acids, alkylphenols, and mercaptans.

The following examples describe preparation of herbicide formulations,antidote formulations, and herbicide+antidote formulations, and use ofthese formulations, under field test conditions.

EXAMPLE 293

A commercially-available formulation of alachor (herbicide ™6) inemulsifiable concentrate form (LASSO® herbicide, Monsanto Co., St.Louis, Mo.) was used for the field tests. The formulation contained 45.1% by wt alachlor (480 g/1 or 4 lbs/gal) and 54.9 % by wt inertingredients.

EXAMPLE 294

An emulsifiable concentrate formulation containing herbicide compound™10 was prepared with the following components:

    ______________________________________                                                                % by wt.                                              ______________________________________                                        Herbicide #10: butachlor (92% tech)                                                                     65.95                                               Atlox 3404F emulsifier; ICI Specialty                                                                   2.25                                                Chemicals, Wilmington, Del.                                                   Atlox 3409F emulsifier; ICI Specialty                                                                   2.75                                                Chemicals, Wilmington, Del.                                                   T-500-100 solvent (mixture of C.sub.9 aromatic                                                          29.02                                               compounds); Tenneco Chemical Co., Atlanta, Ga.                                GE AG-78 antifoaming agent (polysiloxane);                                                              0.01                                                General Electric Co., Waterford, N.Y.                                         Methyl violet (30% solution as the oleate);                                                             0.02                                                Dye specialties Co., Jersey City, N.J.                                        ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.0008observed at 25° C. calculated against water at 15.6° C., and a flashpoint of 41° C. The formulation showed good to perfect emulsion bloom atwater-hardness concentrations of 114 ppm and 1000 ppm and was 100percent stable after one hour at each water-hardness test concentration.The formulation contained 600 g/1 (5 lb/gal) of herbicide compound ™10.

EXAMPLE 295

An emulsifiable concentrate formulation containing acetochlor (herbicidecompound ™11) was prepared with the following components:

    ______________________________________                                                                % by wt.                                              ______________________________________                                        Herbicide #11: acetochlor (93.5% tech)                                                                  92.00                                               Witco C-5438 emulsifier (blend of                                                                       7.96                                                aionic/non-ionic emulsifiers in ethylene                                      glycol); Witco Chemical Co.,                                                  New York, N.Y.                                                                GE AG-78 antifoaming agent (polysiloxane);                                                              0.02                                                General Electric Co., Waterford, N.Y.                                         Methyl violet dye; Dye Specialities Co.,                                                                0.017                                               Jersey City, N.J.                                                             ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.1167observed at 25° C. and calculated against water at 15.6° C., and had aflash point above 100° C. (tag closed-cup method). The formulationshowed perfect emulsion bloom at water-hardness concentrations of 114ppm, 342 ppm and 1000 ppm, and was 100 percent stable after one hour ateach water-hardness concentration. The formulation was blue andcontained 960 g/1 (8 lb/gal) of acetochlor compound.

EXAMPLE 296

An emulsifiable concentrate formulation containing herbicide compound™15 was prepared with the following components:

    ______________________________________                                                               % by wt.                                               ______________________________________                                        Herbicide #15: 2-chloro-2'-methyl-                                                                     41.16                                                6'-methoxy-N-(isopropoxymethyl)-                                              acetanilide (78% tech.)                                                       FLOMO 50H emulsifier (50% solution                                                                     1.79                                                 of calcium dodecylbenzene sulfonate                                           in mineral spirits); De Soto Chemical                                         Co., Chicago, Ill.                                                            FLOMO 14D emulsifier (reaction product                                                                 1.91                                                 of dodecyl phenol and 14 mols ethylene                                        oxide); De Soto Chemical Co., Chicago,                                        Ill.                                                                          FLOMO XH emulsifier (block copolymer                                                                   0.93                                                 of propylene oxide and ethylene oxide);                                       De Soto Chemical Co., Chicago, Ill.                                           FLOMO 54C emulsifier (castor oil                                                                       0.17                                                 ethoxylated with 54 moles ethylene oxide);                                    De Soto Chemical Co., Chicago, Ill.                                           Naphtha Solvent          0.20                                                 Monochlorobenzene Solvent                                                                              53.84                                                ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.1213observed at 25° C. and calculated against water at 15.6° C., a solutionpoint at 2° C., and a flash point less than 38° C. The formulationshowed perfect emulsion bloom at water-hardness concentrations of 114ppm and 342 ppm, and very good bloom at 1000 ppm, and was 100 percentstable after one hour at each test concentration. The formulationcontained 360 g/1 (3 lb/gal) of herbicide compound ™15.

EXAMPLE 297

Other, non-commercially available herbicide formulations used in thefield tests were prepared in emulsifiable-concentrate form in accordancewith procedures such as described in Examples 294-296. These herbicidesand their concentrations of active ingredient were as follows:

    ______________________________________                                        Herbicide    Concentration of                                                 Cpd. #       Active Ingredient                                                ______________________________________                                         9           600 g/l; 5 lb/gal                                                18           480 g/l; 4 lb/gal                                                31           480 g/l; 4 lb/gal                                                39           480 g/l; 4 lb/gal                                                ______________________________________                                    

EXAMPLE 298

An emulsifiable concentrate formulation containing antidote compound ™1was prepared with the following components:

    ______________________________________                                                               % by wt.                                               ______________________________________                                        Antidote #1: methyl diphenylmethoxy-                                                                   47.04                                                acetate (100% tech.)                                                          Atlox 3437F emulsifier; ICI Specialty                                                                  4.67                                                 Chemicals, Wilmington, Del.                                                   Atlox 3438F emulsifier; ICI Specialty                                                                  0.33                                                 Chemicals, Wilmington, Del.                                                   T-400 solvent (mixture of C.sub.9 aromatic                                                             33.57                                                compounds); Tenneco Chemical Co.,                                             Atlanta, Ga.                                                                  Monochlorobenzene solvent                                                                              14.39                                                ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.0195observed at 25° C. calculated against water at 15.6° C., and a solutionpoint less than 0° C. The formulation showed perfect emulsion bloom atwater-hardness concentrations of 114 ppm and 1000 ppm and was 100percent stable after one hour at each water-hardness test concentration.The formulation contained 480 g/1 (4 lb/gal) of antidote compound ™1.

EXAMPLE 299

An emulsifiable concentrate formulation containing antidote compound ™1was prepared with the following components:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #1: methyl diphenylmethoxy-                                                                 13.00                                                  acetate (95% tech.)                                                           Stepan Agent 45 emulsifier; Stepan                                                                   5.00                                                   Chemical Co., Northfield, Ill.                                                T-400 solvent (mixture of C.sub.9 aromatic                                                           57.40                                                  compounds); Tenneco Chemical Co.,                                             Atlanta, Ga.                                                                  Monochlorobenzene solvent                                                                            24.60                                                  ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 0.9724observed at 25° C. calculated against water at 15.6° C., a solutionpoint of 0° C., and a flash point of 38° C. The formulation showed nobloom because it floated on water. The emulsion was observed as 100percent stable after one hour at each water-hardness test concentration.The formulation contained 120 g/1 (1 lb/gal) of antidote compound ™1.

EXAMPLE 300

An emulsifiable concentrate formulation containing antidote compound ™9was prepared with the following components:

    ______________________________________                                                                by wt.                                                ______________________________________                                        Antidote #9: 2,2,2-trifluoroethyl                                                                       45.06                                               diphenylmethoxyacetate (99% tech.)                                            FLOMO 50H emulsifier (50% solution                                                                      0.40                                                of calcium dodecylbenzene sulfonate                                           in mineral spirits); De Soto Chemical                                         Co., Chicago, Ill.                                                            FLOMO 14D emulsifier (reaction product                                                                  2.74                                                of dodecyl phenol and 14 mols ethylene                                        oxide); De Soto Chemical Co., Chicago,                                        Ill.                                                                          FLOMO XH emulsifier (block copolymer                                                                    1.33                                                of propylene oxide and ethylene oxide);                                       De Soto Chemical Co., Chicago, Ill.                                           FLOMO 54C emulsifier (castor oil                                                                        0.24                                                ethoxylated with 54 moles ethylene oxide);                                    De Soto Chemical Co., Chicago, Ill.                                           Naphtha Solvent           0.29                                                T-400 solvent (mixture of C.sub.9 aromatic                                                              24.97                                               compounds); Tenneco Chemical Co.,                                             Atlanta, Ga.                                                                  Monochlorobenzene Solvent 24.97                                               ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.0759observed at 25° C. and calculated against water at 15.6° C., and a flashpoint above 38° C. The formulation showed very good emulsion bloom at awater-hardness concentration of 114 ppm, and perfect bloom at 342 ppmand 1000 ppm, and was 100 percent stable after one hour at each testconcentration. The formulation contained 480 g/1 (4 lb/gal) of antidotecompound ™9.

EXAMPLE 301

An emulsifiable concentrate formulation containing antidote compound ™11was prepared with the following components:

    ______________________________________                                                                % by wt.                                              ______________________________________                                        Antidote #11: 1,1-dimethylethyl-                                                                        32.10                                               ammonium phenyl[3-(trifluoromethyl)-                                          phenyl]methoxyacetate                                                         FLOMO 50H emulsifier (50% solution                                                                      1.79                                                of calcium dodecylbenzene sulfonate                                           in mineral spirits); De Soto Chemical                                         Co., Chicago, Ill.                                                            FLOMO 14D emulsifier (reaction product                                                                  1.91                                                of dodecyl phenol and 14 mols ethylene                                        oxide); De Soto Chemical Co., Chicago,                                        Ill.                                                                          FLOMO XH emulsifier (block copolymer                                                                    0.93                                                of propylene oxide and ethylene oxide);                                       De Soto Chemical Co., Chicago, Ill.                                           FLOMO 54C emulsifier (caster oil                                                                        0.17                                                ethoxylated with 54 moles ethylene oxide);                                    De Soto Chemical Co., Chicago, Ill.                                           Naphtha Solvent           0.20                                                Monochlorobenzene Solvent 62.90                                               ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.1215observed at 25° C. and calculated against water at 15.6° C., and a flashpoint less than 38° C. The formulation showed good emulsion bloom atwater-hardness concentrations of 114 ppm, 342 ppm and 1000 ppm, and hada cream layer 1 cm in thickness at each test concentration. Theformulation contained 360 g/1 (3 lb/gal) of antidote compound ™11.

EXAMPLE 302

Antidote compound ™11 in crystalline form was converted to a 20% powderfor use in field tests. The powder was prepared with the followingcomponents:

    ______________________________________                                                            % by wt.                                                  ______________________________________                                        Antidote #11: 1,1-dimethylethyl-                                                                    20.00                                                   ammonium phenyl[3-(trifluoromethyl)-                                          phenyl]methoxyacetate                                                         Barden clay carrier; J. M. Huber Co.,                                                               80.00                                                   Havre de Grace, Md.                                                           ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50.microns to about 100 microns in diameter.

EXAMPLE 303

An emulsifiable concentrate formulation containing antidote compound ™16was prepared with the following components:

    ______________________________________                                                              % by wt.                                                ______________________________________                                        Antidote #16: S-ethyl 2-(diphenyl-                                                                    22.72                                                 methoxy)ethanethioate                                                         FLOMO 50H emulsifier (50% solution of                                                                 3.75                                                  calcium dodecylbenzene sulfonate in                                           mineral spirits); De Soto Chemical Co.,                                       Chicago, Ill.                                                                 FLOMO 54C emulsifier (castor oil                                                                      3.75                                                  ethoxylated with 54 moles ethylene oxide);                                    De Soto Chemical Co., Chicago, Ill.                                           Monochlorobenzene solvent                                                                             69.78                                                 ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a solution point of 0° C., and aflash point less than 38° C. The formulation showed perfect emulsionbloom at water-hardness concentrations of 4 ppm, 342 ppm and 1000 ppm,and was 100 percent stable after one hour at each test concentration.The formulation was dark brown and contained 240 g/1 (2 lb/gal) ofantidote compound ™16.

EXAMPLE 304

Antidote compound ™16 in crystalline form was converted to a 50% stickypowder for use in field tests. The powder was prepared the followingcomponents:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #16: S-ethyl 2-(diphenyl-                                                                   50.00                                                  methoxyethanethioate                                                          Micro-Cel E diatomaceous earth;                                                                      25.00                                                  Johns-Manville Co., Los Angeles, Ca.                                          Dipropylene Glycol     25.00                                                  ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50 microns to about 100 microns in diameter.

EXAMPLE 305

Antidote compound ™22 in crystalline form was converted to a 25%wettable powder for use in formulation field tests. The wettable powderwas prepared with the following components.

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #22: bis(2,6-dimethylphenyl)-                                                               25.00                                                  methoxyacetic acid                                                            Reax 45-A dispersant (modified sodium                                                                4.00                                                   salts of sulfonated lignin); Westvaco                                         Chem. Div., Winder, Ga.                                                       Aerosol OTB dispersant (dioctyl ester                                                                4.00                                                   of sodium sulfosuccinic acid), American                                       Cyanamid Co., Stamford, Conn.                                                 Barden clay carrier; J. M. Huber Co.,                                                                67.00                                                  Havre de Grace, Md.                                                           ______________________________________                                    

These components were mixed together until uniform and then furtherblended and ground in a hammer mill to a fine powder of particle sizefrom about 50 microns to about 100 microns in diameter.

EXAMPLE 306

Antidote compound ™22 in crystalline form was converted to a 50% powderfor use in field tests. The powder was prepared with the followingcomponents:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #22: bis(2,6-dimethylphenyl)-                                                               50.0                                                   methoxyacetic acid                                                            Micro-Cel E diatomaceous earth;                                                                      25.0                                                   Johns-Manville Co., Los Angeles, Ca.                                          Barden Clay carrier; J. M. Huber Co.,                                                                25.0                                                   Havre de Grace, Md.                                                           ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50 microns to about 100 microns in diameter.

EXAMPLE 307

An emulsifiable concentrate formulation containing antidote compound ™23was prepared with the following components:

    ______________________________________                                                                % by wt.                                              ______________________________________                                        Antidote #23: 3-nitrophenyl                                                                             10.96                                               diphenylmethoxyacetate (98% tech)                                             FLOMO 54C emulsifier (castor oil                                                                        5.90                                                ethoxylated with 54 moles ethylene oxide);                                    De Soto Chemical Co., Chicago, Ill.                                           FLOMO 50H emulsifier (50% solution of                                                                   3.90                                                calcium dodecylbenzene sulfonate in                                           mineral spirits); De Soto Chemical Co.,                                       Chicago, Ill.                                                                 FLOMO XD emulsifier (block copolymer of                                                                 0.20                                                ethyleneoxide and propylene oxide); De Soto                                   Chemical Co., Chicago, Ill.                                                   Monochlorobenzene solvent 79.03                                               ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.1173observed at 25° C. calculated against water at 15.6° C., and a solutionpoint of 0° C. and a flash point of less than 38° C. The formulationshowed perfect emulsion bloom at water-hardness concentrations of 114ppm, 342 ppm and 1000 ppm and was 100 percent stable after one hour ateach test concentration. The formulation was amber and contained 120 g/1(1 lb/gal) of antidote compound ™23.

EXAMPLE 308

Antidote compound ™23 in crystalline form was converted to a 50% powderfor use in field tests. The powder was prepared with the followingcomponents:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #23: 3-nitrophenyl                                                                          50.00                                                  diphenylmethoxyacetate                                                        Barden clay carrier; J. M. Huber Co.,                                                                25.00                                                  Havre de Grace, Md.                                                           Micro-Cel E diatomaceous earth;                                                                      25.00                                                  Johns-Manville Co., Los Angeles, Ca.                                          ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50 microns to about 100 microns in diameter.

EXAMPLE 309

An emulsifiable concentrate formulation containing antidote compound ™24was prepared with the following components:

    ______________________________________                                                                 % by wt.                                             ______________________________________                                        Antidote #24: ethyl bis(2,6-dimethylphenyl)                                                              25.02                                              methoxyacetate (95% tech.)                                                    FLOMO 50H emulsifier (50% solution of                                                                     5.56                                              calcium dodecylbenzene sulfonate in                                           mineral spirits); De Soto Chemical Co.,                                       Chicago, Ill.                                                                 FLOMO 54C emulsifier (castor oil ethoxylated                                                              4.44                                              with 54 moles ethylene oxide); De Soto                                        Chemical Co., Chicago, Ill.                                                   T-400 solvent (mixture of C.sub.9 aromatic                                                               32.49                                              compounds); Tenneco Chemical Co., Atlanta, Ga.                                Monochlorobenzene solvent  32.49                                              ______________________________________                                    

These components were mixed together at room temperature until a uniformblend was obtained. The formulation had a specific gravity of 1.10145observed at 25° C. calculated against water at 15.6° C., a solutionpoint less than 0° C., and a flash point of 38° C. The formulationshowed very good emulsion bloom at waterhardness concentrations of 114ppm, 342 ppm, and 1000 ppm, and was 100 percent stable after one hour ateach test concentration. The formulation was brown in color andcontained 240 g/1 (2 lb/gal) of antidote compound ™24.

EXAMPLE 310

Antidote compound ™24 in crystalline form was converted to a 50% stickypowder for use in field tests. The wettable powder was prepared with thefollowing components:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #24: ethyl bis(2,6-dimethyl-                                                                50.00                                                  phenyl)methoxyacetate                                                         Micro-Cel E diatomaceous earth;                                                                      25.00                                                  Johns-Manville Co., Los Angeles, Ca.                                          Dipropylene Glycol     25.00                                                  ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50 microns to about 100 microns in diameter.

EXAMPLE 311

Antidote compound ™27 in crystalline form was converted to a 25% stickypowder for use in field tests. The powder was prepared with thefollowing components:

    ______________________________________                                                             % by wt.                                                 ______________________________________                                        Antidote #27: 1-cyano-1-methylethyl                                                                  25.0                                                   diphenylmethoxyacetate                                                        Micro-Cel E diatomaceous earth;                                                                       50.00                                                 Johns-Manville Co., Los Angeles, Ca.                                          Dipropylene Glycol     25.0                                                   ______________________________________                                    

These components were mixed together until uniformly dispersed and thenfurther blended and ground in a hammer mill to a fine powder of particlesize from about 50 microns to about 100 microns in diameter.

EXAMPLE 312

Antidote-coated crop seed was prepared by placing a measured quantity ofseed in a plastic container along with a measured quantity of the powderformulation containing antidote compound The powder formulation wasprepared by procedures of Examples 302, 304, 305, 306, 308, 310 or 311.The crop seed was previously treated with the fungicide captan (ChevronChemical Co., San Francisco, Calif.) and with the insecticidemethoxychlor (E.I. duPont de Nemours & Co. Wilmington, Del.). Theplastic container containing seed and powder formulation was shakenuntil all seed was thoroughly coated with the formulation.Antidote-coated crop seed was prepared having antidote at concentrationsin a range typically from 1/32% to 1/8%, wt./wt., antidote-on-seed.

EXAMPLE 313

Formulations were prepared for field testing to determine thecomparative effects of herbicide alone, herbicide-and-antidote incombination, and antidote alone. The herbicide and/or antidoteformulations were applied by tank-mix spraying. Also, theherbicide-antidote interactions were evaluated with the antidote as aseed coating. For each formulation, a tractor-mounted 20-liter spraytank was filled about half-full with water. For the herbicideformulations containing no antidote, an appropriate amount ofemulsifiable concentrate (as described in Examples 293-297) was addeddirectly to a tank. For the antidote-containing tank-mix formulations,the antidote in wettable powder form or in emulsifiable form was addedto a tank. Then for the herbicide + antidote formulation, antidotewettable powder or emulsifiable concentrate was added to a tankcontaining herbicide. Each tank-mix formulation was agitatedsufficiently to ensure a uniform suspension. The relative amounts ofwater, herbicide emulsifiable concentrate, and antidote, added to thetank were calculated for each formulation based upon a formulationspraying rate of 280 l/ha (30 gal/acre) in order to achieve variousfield application rates of herbicide and antidote, as appropriate, forthe rates shown in the following tests. Each formulation was sprayed onthree replicate plots, with a small-plot tractor-mounted sprayer with a3 meter (10 ft) boom delivering 280 l/ha (30 gal/ac) at 2 atm pressure(30 psi), unless otherwise specified. The treatments were made to siltloam topsoil containing approximately one percent organic matter andwere selected in a random manner in order to normalize variations inplot soil conditions. Three control plots were established which werenot treated with herbicide or with antidote formulations. Whereappropriate, crop seed used in the field tests was treated prior toplanting with Vitavax fungicide, or captan fungicide, or the insecticidemethoxychlor.

EXAMPLE 314

Formulations of butachlor (herbicide cpd. ™10) and tank-mix safenedbutachlor (with antidote cpd. ™1) were pre-emergent surface-applied inside-by-side field plots to determine their relative inhibition ofgrassy weeds and injury to direct-seeded upland rice in easternMissouri. Eight rows of Brazos rice seed, treated with Vitavaxfungicide, and four rows of barnyardgrass seed were planted 3 cm deep ata heavy seeding rate in Ray silt loam topsoil using a 12-row Planet Jr.planter. The test formulations of butachlor, safened butachlor, and acontrol formulation of antidote without herbicide, were prepared asdescribed in the foregoing Examples. The plots (2×5 m; 7×15 ft) weresprayed with a CO₂ -pressurized small-plot back-pack sprayer at a rateof 280 l/ha (30 gal/ac). Test observations, taken at 24 days aftertreatment by three observers, are reported in Table X.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed: 8-15 Km/hr (5-9 mph)                                              Air temperature:                                                                          33° C. (92° F.)                                     Soil temperature:                                                                         30° C. (86° F.)                                     Relative humidity:                                                                        44%                                                               Soil moisture:                                                                            slightly cloddy, dry surface;                                                 adequate subsurface moisture.                                     Climatic Conditions First-Three Weeks:                                        Average air temp.:                                                                        Hi/Lo 31° C. (87° F.)/19° C. (67°                 F.)                                                               Extreme air temp.:                                                                        Hi/Lo 36° C. (97° F.)/13° C. (55°                 F.)                                                               Rainfall:   8.9 cm (3.5 in) total                                             Irrigation: 1 cm (0.5") overhead 4 days after treatment.                      ______________________________________                                    

                  TABLE X                                                         ______________________________________                                        Formulation (kg/ha)     % Inhibition                                          Herbicide Antidote             Barnyard-                                      #10       #1            Rice   Grass                                          ______________________________________                                        0         0              0      0                                             2.24      0             20     85                                             4.48      0             23     97                                             8.96      0             32     99                                             0         1.12           0      0                                             2.24      1.12           7     92                                             4.48      1.12          10     96                                             8.96      1.12          20     97                                             0         2.24           0      0                                             2.24      2.24          10     82                                             4.48      2.24          15     88                                             8.96      2.24          13     97                                             0         4.48           0      0                                             2.24      4.48          10     87                                             4.48      4.48          23     97                                             8.96      4.48          15     98                                             ______________________________________                                    

EXAMPLE 315

Formulations of alachlor (herbicide cpd. ™4) and tank-mix safenedalachlor (separately with antidote cpd. ™9 and ™11) were pre-emergentsurface-applied in side-by-side field plots to determine their relativeinhibition of grassy and broadleaf weeds in the presence of grainsorghum in eastern Missouri. Four rows of DeKalb E59⁺ grain sorghum seedwere planted 2-3 cm (3/4-1 in) deep in Ray silt loam topsoil at aseeding rate of at least 22 Kg/ha (20 lb/ac). Test formulations ofalachlor, safened alachlor and a control formulation of antidote withoutherbicide, were prepared as described in the foregoing Examples. Theplots (2×8 m; 7×25 ft) were sprayed with a CO₂ -pressurized small-plotback-pack sprayer at a rate of 280 l/ha (30 gal/ac). Test observationsare reported in Table XI.

    ______________________________________                                        Field Conditions at Treatment:                                                ______________________________________                                        Wind speed:    8-14 Km/hr (5-9 mph)                                           Air temperature:                                                                             24° C. (75° F.)                                  Soil moisture: surface dry, moist @ seed depth                                ______________________________________                                    

                  TABLE XI                                                        ______________________________________                                        Formulation    % Inhibition                                                   Herbicide                                                                              Antidote  Grain     Giant   Pig-                                     #6       #9/#11    Sorghum   Foxtail weed                                     (kg/ha)  (kg/ha)   a/b       a/b     a/b                                      ______________________________________                                        0               0      0/0     0/0     0/0                                    1.12            0      22/3    100/97  100/100                                2.24            0      62/32   100/100 100/100                                4.48            0      88/70   100/100 100/100                                0                      0/0     0/0     0/0                                    1.12     #9     1.12   14/0    100/100 100/100                                2.24     #9     1.12   27/8    100/95  100/100                                4.48     #9     1.12   62/33   100/100 100/100                                0        #9     2.24   0/0     0/0     0/0                                    1.12     #9     2.24   15/7    100/98  100/100                                2.24     #9     2.24   30/10   100/100 100/100                                4.48     #9     2.24   41/8    100/98  100/100                                0        #9     4.48   0/0     0/0     0/0                                    1.12     #9     4.48   8/0      99/100  99/100                                2.24     #9     4.48   24/3    100/100 100/100                                4.48     #9     4.48   37/12   100/100 100/100                                0                      0/0     0/0     0/0                                    1.12     #11    1.12   18/10   100/100 100/100                                2.24     #11    1.12   37/18   100/100 100/100                                4.48     #11    1.12   65/45   100/100 100/100                                0        # 11   2.24   0/0     0/0     0/0                                    1.12     #11    2.24   7/0     100/100 100/100                                2.24     #11    2.24   18/3    100/100 100/100                                4.48     #11    2.24   46/32   100/100 100/100                                0        #11    4.48   2/0     0/0     0/0                                    1.12     #11    4.48   9/0     100/100 100/100                                2.24     #11    4.48   12/3    100/100 100/100                                4.48     #11    4.48   42/18   100/100 100/100                                ______________________________________                                         a = Observations taken at 21 days after treatment.                            b = Observations taken at 58 days after treatment.                       

EXAMPLE 316

Formulations of four acetanilide herbicides a (cpds ™6, ™11, ™15 and™18) were individually surface-applied pre-emergent to side-by-sidefield plots to determine their relative injury to grain sorghum and corngrown from seed treated with antidote compound ™11. DeKalb E59⁺ hybridgrain sorghum seed and DeKalb corn seed were treated with antidote ™11in an 80% powder formulation (prepared as described in the foregoingExamples) at a rate of 1/8% antidote-on-seed (wt/wt). Six rows of eachseed were planted in Ray silt loam soil to a depth of 1.9-2.5 cm (3/4-1in) using a 12-row Planet Jr. planter at a seeding rate of at least 22kg/ha (20 lb/ac) for the sorghum seed and at a rate of 147,000 seed/ha(64,000 seed/ac) for the corn seed. The herbicide test and controlformulations were prepared and surface-applied to the field plots (3×12m; 11×15 ft) as described in Example 313. Test observations are reportedin Table XII.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed:    0-5 Km/hr (0-3 mph)                                            Air temperature:                                                                             27° C. (80° F.)                                  Soil moisture: surface dry, moist @ seed depth                                Climatic Conditions First-Three Weeks:                                        Average air temp.:                                                                           Hi/Lo 32° C. (90° F.)/20° C.                             (68° F.)                                                Extreme air temp.:                                                                           Hi/Lo 35° C. (95° F.)/16° C.                             (61° F.)                                                Rainfall:      3.3 cm (1.31 in) total                                         Irrigation:    2.5 cm (1.0 in) 2 days after treatment                         ______________________________________                                    

                  TABLE XII                                                       ______________________________________                                                 % Injury                                                                      Seed Without Antidote #11                                                     Antidote     on Seed (1/8%)                                          Herbicide  Sorghum   Corn     Sorghum Corn                                    # .sub.--  (kg/ha)                                                                       a/b       a/b      a/b     a/b                                     ______________________________________                                              0        0/0       0/0    0/0     0/0                                   #6    4.48     94/80     11/0   40/16   3/7                                         6.72     99/99     9/5    57/29   23/7                                  #11   2.24     96/80     13/3   72/67   5/4                                         6.72     100/100   28/15  87/63   13/5                                  #15   2.24     94/86     48/20  61/71   14/18                                       6.72     100/100   89/90  100/90  42/46                                 #18   2.24     99/13      8/13  56/49   8/3                                         6.72     100/29    37/29  92/99   17/13                                 ______________________________________                                         a = Observations taken at 29 days after treatment.                            b = Observations taken at 64 days after treatment.                       

EXAMPLE 317

Formulations of alachlor (herbicide cpd. ™6) and tank-mix safenedalachlor (with antidote cpd. ™23) were pre-plant-incorporated inside-by-side field plots to determine their relative injury to winterwheat in eastern Missouri. Test formulations of alachlor, safenedalachlor, and a control formulation of antidote without herbicide, wereprepared as described in the foregoing Examples. The plots (3×8 m; 11×25ft) were sprayed with a CO₂ -pressurized small-plot back-pack sprayer ata rate of 280 l/ha (30 gal/ac). A Ferguson Tilrovator was used toincorporate the formulations to a depth of about 2.5 cm (1 in). A JohnDeere drill planter was used to plant Pike winter wheat seed to a depthof about 4 cm (11/2 in) at a seeding rate of about 99 kg/ha (90 lb/ac).Test observations taken 28 days after treatment, are reported in TableXIII.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed:   0-5 Km/hr (0-3 mph)                                             Air temperature:                                                                            29° C. (85° F.)                                   Soil moisture:                                                                              surface dry, moist @ seed depth                                 Climatic Conditions First-Three Weeks:                                        Rainfall:     12.6 cm (4.97 in) total                                         Irrigation:   2.5 cm (1.0 in) 4 days after treatment                          ______________________________________                                    

                  TABLE XIII                                                      ______________________________________                                        Herbicide     Antidote   % Inhibition                                         #6 (kg/ha)    #23 (kg/ha)                                                                              Wheat                                                ______________________________________                                        0             0           0                                                   1.12          0          70                                                   2.24          0          81                                                   4.48          0          92                                                   0             1.12        0                                                   1.12          1.12       58                                                   2.24          1.12       83                                                   4.48          1.12       90                                                   0             2.24        0                                                   1.12          2.24       56                                                   2.24          2.24       85                                                   4.48          2.24       90                                                   0             4.48        0                                                   1.12          4.48       45                                                   2.24          4.48       72                                                   4.48          4.48       85                                                   ______________________________________                                    

EXAMPLE 318

Formulations of butachlor (herbicide cpd. ™10) and tank-mix safenedbutachlor (separately with antidote cpd. ™16, ™22 and ™24) werepre-plantincorporated in side-by-side field plots to determine theirrelative injury to direct-seeded rice in eastern Missouri. Testformulations of butachlor, safened butachlor, and a control formulationof antidote without herbicide, were prepared as described in theforegoing Examples. The plots (3×8 m; 10×25 ft) were sprayed with a CO₂-pressurized small-plot back-pack sprayer at a rate of 280 1/ha (30gal/ac). A Ferguson Tilrovator was used to incorporate the formulationsinto Black Stick soil. A John Deere drill planter was used to plantBellbonnete rice at a seeding rate of 108 kg/ha (98 lb/ac). Testobservations are reported in Table XIV.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed:   calm                                                            Air temperature:                                                                            32° C. (90° F.)                                   Soil temperature:                                                                           32° C. (90° F.)                                   Soil moisture:                                                                              surface dry, dry @ seed depth                                   Climatic Conditions First-Four Weeks:                                         Rainfall:     6.5 cm (2.56 in) total                                          Irrigation:   1.8 cm (3/4 in) one day after treatment                         ______________________________________                                    

                  TABLE XIV                                                       ______________________________________                                        Formulation                                                                               Antidote        % Inhibition                                      Herbicide   Tank Mix Ratio  Rice                                              #10 (kg/ha) Herbicide:Antidote                                                                            a       b                                         ______________________________________                                        0           --               0       0                                        1.12        --              23      23                                        3.36        --              37      47                                        6.72        --              53      58                                        1.12        #16 8:1         23      18                                        3.36        #16 8:1         30      35                                        6.72        #16 8:1         47      47                                        1.12        #16 4:1         23      28                                        3.36        #16 4:1         37      35                                        6.72        #16 4:1         43      47                                        0           --               0       0                                        1.12        #16 2:1         25      22                                        3.36        #16 2:1         28      32                                        6.72        #16 2:1         25      35                                        1.12        #22 8:1         20      22                                        3.36        #22 8:1         28      30                                        6.72        #22 8:1         32      41                                        1.12        #22 4:1         23      18                                        3.36        #22 4:1         28      25                                        6.72        #22 4:1         30      30                                        0           --               0       0                                        1.12        #22 2:1         25      12                                        3.36        #22 2:1         30      17                                        6.72        #22 2:1         30      17                                        1.12        #24 8:1         15      12                                        3.36        #24 8:1         20      18                                        6.72        #24 8:1         27      30                                        1.12        #24 4:1         12      18                                        3.36        #24 4:1         28      25                                        6.72        #24 4:1         33      25                                        0           0                0       0                                        1.12        #24 2:1         18      13                                        3.36        #24 2:1         28      17                                        6.72        #24 2:1         27      17                                        ______________________________________                                         a = Observations taken at 24 days after treatment.                            b = Observations taken at 37 days after treatment.                       

EXAMPLE 319

Formulations of four acetanilide herbicides (cpds. ™6, ™10, ™31 and ™39)were individually pre-plant-incorporated in side-by-side field plots todetermine their relative inhibition of barnyardgrass and injury to riceplants grown from direct-seeded rice seeds treated separately withantidote compounds ™16, ™22 and ™24. LaBelle rice seed was treatedseparately with the three antidotes in 50% sticky powder formulations(prepared as described in the foregoing Examples) at antidote-on-seedrates of 1/32%, 1/16% or 1/8%. The formulations were sprayed andincorporated into silty loam soil plots (3×5 m; 11×15 ft), and the riceseed was drilled into the soil at a seeding rate of 110 kg/ha (100lb/ac). Test observations are reported in Table XV.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed: calm                                                              Air temperature:                                                                          34° C. (94° F.)                                     Soil temperature:                                                                         28° C. (83° F.)                                     Soil moisture:                                                                            surface dry, slight moisture @ seed depth                         Climatic Conditions First-Three Weeks:                                        Rainfall:   4.72 cm (1.86 in) total                                           Irrigation: 1.9 cm (3/4 in) one day after treatment                           ______________________________________                                    

                  TABLE XV                                                        ______________________________________                                        Antidote # .sub.--                                                                     Herbicide # (kg/ha)                                                  wt/wt % on                                                                             #10    #10     #6   #6    #39  #39   #31                             Rice Seed                                                                              1.12   3.36    1.12 3.36  1.12 3.36  1.12                            ______________________________________                                        % RICE INHIBITION                                                             --   0       27     47    98   99    83   98    99                                 #16                                                                      1/32 0       12     23    85   99    53   99    99                            1/16 0       12     18    63   95    37   95    99                            1/8  0        7     18    45   95    28   96    98                                 #22                                                                      1/32 0        8     18    80   99    42   99    99                            1/16 0       13     20    80   97    43   98    98                            1/8  0        7     15    80   99    23   98    99                                 #24                                                                      1/32 0       10     20    78   99    45   99    99                            1/16 0       10     15    70   95    35   97    99                            1/8  0        0     13    70   98    23   95    99                            % BARNYARDGRASS INHIBITION                                                    --   0       100    100   100  100   100  100   100                                #16                                                                      1/32 0       98     100   100  100   100  100   100                           1/16 0       100    100   100  100   100  100   100                           1/8  0       100    100   100  100   100  100   100                                #22                                                                      1/32 0       100    100   100  100   100  100   100                           1/16 0       100    100   100  100   100  100   100                           1/8  0       100    100   100  100   100  100   100                                #24                                                                      1/32 0       100    100   100  100   100  100   100                           1/16 0       100    100   100  100   100  100   100                           1/8  0       100    100   100  100   100  100   100                           ______________________________________                                    

EXAMPLE 320

Formulations of butachlor (herbicide cpd ™10) and tank-mix safenedbutachlor (separately with antidote cpd. ™1, ™16, ™22, ™24 and ™27) werepre-plant-incorporated in side-by-side field plots to determine theirrelative injury to direct seeded rice in eastern Missouri. Testformulations of butachlor, safened butachlor and a control formulationof antidote without herbicide, were prepared as described in theforegoing Examples. The plots (5×5 m; 15×15 ft) were sprayed with asmall-plot tractor sprayer at a rate of 280 l/ha (30 gal/ac). Arototiller was used to incorporate the formulations into silty clay loamsoil to a depth of about 2 to 5 cm (1 to 2 in). A John Deere drillplanter was used to plant Labelle (Indica-type) rice at a seeding rateof 121 kg/ha (110 lb/ac). Test observations are reported in Table XVI.

    ______________________________________                                        Field Conditions at Treatment:                                                Wind speed:   calm                                                            Air temperature:                                                                            32° C. (90° F.)                                   Soil temperature:                                                                           29° C. (85° F.)                                   Soil moisture:                                                                              surface dry, dry @ seed depth                                   Climatic Conditions First-Four Weeks:                                         Rainfall:     0.5 cm (0.20 in.) 18 days after treatment;                      Irrigation:   1.8 cm (3/4 in) @ 1, 6 and 12 days after                                      treatment                                                       ______________________________________                                    

                  TABLE XVI                                                       ______________________________________                                        Herbicide                                                                             Antidote                 Rice                                         #10     # .sub.--  Tank Mix Ratio                                                                              Inhibition (%)                               (kg/ha) (kg/ha)    Herbicide:Antidote                                                                          a     b                                      ______________________________________                                        0       --         --             0     0                                     3.36    --         --            82    57                                     6.72    --         --            92    70                                     --      #1     6.72    --           0     0                                   --      #16    6.72    --           0     0                                   --      #22    6.72    --           0     0                                   --      #24    6.72    --           0     0                                   3.36    #1     0.84    4:1         40    22                                   6.72    #1     1.68    4:1         48    28                                   3.36    #1     1.68    2:1         37    18                                   6.72    #1     3.36    2:1         35    22                                   3.36    #1     3.36    1:1         22    17                                   6.72    #1     6.72    1:1         25    18                                   3.36    #16    0.84    4:1         30    22                                   6.72    #16    1.68    4:1         45    33                                   3.36    #16    1.68    2:1         27    13                                   6.72    #16    3.36    2:1         37    25                                   3.36    #16    3.36    1:1         27    12                                   6.72    #16    6.72    1:1         33    18                                   3.36    #22    0.84    4:1         27    17                                   6.72    #22    1.68    4:1         37    25                                   3.36    #22    1.68    2:1         27    18                                   6.72    #22    3.36    2:1         40    27                                   3.36    #22    3.36    1:1         27    17                                   6.72    #22    6.72    1:1         35    22                                   3.36    #24    0.84    4:1         25    13                                   6.72    #24    1.68    4:1         32    22                                   3.36    #24    1.68    2:1         18    10                                   6.72    #24    3.36    2:1         28    20                                   3.36    #24    3.36    1:1         22     7                                   6.72    #24    6.72    1:1         30    17                                   3.36    #27    0.84    4:1         --    --                                   6.72    #27    1.68    4:1         45    28                                   3.36    #27    1.68    2:1         40    32                                   6.72    #27    3.36    2:1         32    22                                   3.36    #27    3.36    1:1         23    13                                   6.72    #27    6.72    1:1         28    22                                   ______________________________________                                         a = Observations taken at 12 days after treatment.                            b = Observations taken at 22 days after treatment.                       

Although this invention has been described with respect to specificembodiments, the details of these embodiments are not to be construed aslimitations. Various equivalents, changes, and modifications may be madewithout departing from the spirit and scope of this invention, and it isunderstood that such equivalent embodiments are part of this invention.

What is claimed is:
 1. Compound of the formula ##STR28## wherein R₁ andR₂ are H; R₄ is H, alkyl, alkenyl, alkynyl, haloalkyl, cycloalkyl,alkoxyalkyl, alkoxycarbonylalkyl, alkylthioalkyl, hydroxyalkyl, phenylor benzyl and, when not self-inclusive, said R₄ members substituted withalkyl, cycloalkyl, alkoxy, haloalkyl, phenyl, halophenyl, alkoxyphenylor nitro groups andR₈ and R₉ are independently H, alkyl, alkoxy, halo orhaloalkyl; provided that:(a) when R₄ is H, R₈ and/or R₉ cannot be H,methyl, ethyl or halogen and (b) when R₈ and/or R₉ are H, halogen orCF₃, R₄ cannot be methyl, ethyl, n-propyl, 2-ethoxyethyl ordiphenylmethyl.
 2. Compound according to claim 1 wherein R₄ is selectedfrom the group consisting of H, lower alkyl, C₂₋₅ alkenyl or alkynyl,benzyl, phenyl, pyridylmethyl and when not self-inclusive said R₄members substituted with halo, haloloweralkyl, nitro or cyano groups. 3.Compound of claim 2 which is 1,1-dimethylethyl diphenylmethoxyacetate.4. Compound of claim 2 which is benzyl diphenylmethoxyacetate. 5.Compound of claim 2 which is 1-methylethyl diphenylmethoxyacetate. 6.Compound of claim 2 which is 2,2,2-trifluoroethyldiphenylmethoxyacetate.
 7. Compound of claim 2 which is phenyldiphenylmethoxyacetate.
 8. Compound of claim 2 which is2,2,3,3-tetrafluoropropyl diphenylmethoxyacetate.
 9. Compound of claim 2which is 1-methyl-2,2,2-trifluoroethylphenyl]3-(trifluoromethyl)phenyl]methoxyacetate.
 10. Compound of claim 2which is 4-chlorobenzyl diphenylmethoxyacetate.
 11. Compound of claim 2which is bis(2,6-dimethylphenyl)methoxyacetic acid.
 12. Compound ofclaim 2 which is 3-nitrophenyl diphenylmethoxyacetate.
 13. Compound ofclaim 2 which is ethyl bis(2,6-dimethylphenyl)methoxyacetate. 14.Compound of claim 2 which is 3-pyridinylmethyl diphenylmethoxyacetate.15. Compound of claim 2 which is 1-cyano-1-methylethyldiphenylmethoxyacetate.
 16. Compound of claim 2 which is 2-cyanoethyldiphenylmethoxyacetate.
 17. Compound of claim 2 which is1-cyano-1-methylethyl bis(2,6-dimethylphenyl)methoxyacetate. 18.Compound of claim 2 which is 1-methyl-2-propynyl diphenylmethoxyacetate.19. Compound of claim 2 which is 3-nitrophenyl(4-chlorophenyl)phenylmethoxyacetate.
 20. Compound of claim 2 which is1-cyano-1-methylethyl (4-chlorophenyl)phenylmethoxyacetate.
 21. Compoundof claim 2 which is 1-ethyl-2-propynyl diphenylmethoxyacetate. 22.Compound of claim 2 which is 2-propenyl(4-chlorophenyl)phenylmethoxyacetate.